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Thermodynamic assessment of the Co-Ta system

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TLDR
In this paper, the phase equilibria and thermodynamic properties of the binary Co-Ta system were analyzed and a complete thermodynamic description was obtained with the CALPHAD technique using a computerized optimization procedure.
Abstract
The phase equilibria and thermodynamic properties of the binary Co-Ta system were analyzed and a complete thermodynamic description of the binary system was obtained with the CALPHAD technique using a computerized optimization procedure. The thermodynamic descriptions of pure Co and Ta elements were taken from the SGTE database. Based on the experimental data, six binary intermetallic compounds were considered. They are three Laves phases, μ phase, θ phase and Co 7 Ta 2 phase. The last two compounds are treated as stoichiometric compounds. Good agreement was obtained between calculated results and experimental data in the binary system.

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Structure and stability of Laves phases part II—structure type variations in binary and ternary systems

TL;DR: In this article, various models for the prediction of the occurrence and stability of Laves phases have been discussed and the need for careful experimental investigations of phase equilibria is demonstrated, and some general rules for the occurrence of different Laves phase polytypes are derived from a study of the results of experimental phase diagram investigations of various binary and ternary systems.
Journal ArticleDOI

Laves phases: a review of their functional and structural applications and an improved fundamental understanding of stability and properties

TL;DR: There is a broad range of successful utilization of Laves phases in functional applications including hydrogen storage material (Hydraloy), as magneto-mechanical sensors and actuators (Terfenol), or for wear and corrosion-resistant coatings in corrosive atmospheres and at high temperatures (Tribaloy).
Journal ArticleDOI

CSUTDCC1—A thermodynamic database for multicomponent cemented carbides

TL;DR: In this paper, a self-consistent thermodynamic database for multicomponent cemented carbides has been developed, with the thermodynamic descriptions for all of the binary systems and some of the ternary systems taken from the literature with slight modifications for some reported parameters.
Journal ArticleDOI

Experimental and thermodynamic study of the microstructure evolution in cobalt-base superalloys at high temperature

TL;DR: In this article, experiments and thermodynamic calculations were performed on five cobalt-base superalloys containing tantalum carbide and chromium carbides in order to evaluate the accuracy of thermodynamics calculations for this alloy family.
Journal ArticleDOI

Phase equilibria and thermodynamic calculation of the Co–Ta binary system

TL;DR: In this article, an experimental investigation and thermodynamic evaluation of the Co-Ta binary phase diagram was carried out and the equilibrium compositions obtained in two-phase alloys and diffusion couples were measured by electron probe microanalyzer (EPMA).
References
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Journal ArticleDOI

SGTE data for pure elements

TL;DR: In this article, the authors present the data for the condensed phases of 78 elements as currently used by SGTE (Scientific Group Thermodata Europe) as a sound basis for the critical assessment of thermodynamic data, thereby, perhaps, limiting unnecessary duplication of effort.
Journal ArticleDOI

The Thermo-Calc databank system☆

TL;DR: Using the facilities of Thermo-Calc one can tabulate thermodynamic data, calculate the heat change of chemical reactions and their driving force, evaluate equilibria for chemical systems and phase transformations and calculate various types of multicomponent phase diagrams by an automatic mapping procedure.
Journal ArticleDOI

Model predictions for the enthalpy of formation of transition metal alloys II

TL;DR: In this article, the authors present a computer program in Algol 60 by means of which enthalpy effects can be calculated for binary alloys in which at least one transition metal is involved.
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A model for alloying in ferromagnetic metals

TL;DR: In this paper, a mathematical representation of the magnetic specific heat, recently suggested by Inden, was applied to iron in an evaluation of the difference in Gibbs energy between the fcc and bcc states.
Journal ArticleDOI

Compounds and pseudo-binary alloys with the CuAl2(C16)-type structure I. Preparation and X-ray results

TL;DR: A total of 46 binary compounds with the CuAl2(C16)-type structure have been prepared and their crystallographic properties (unit cell dimensions a and c and the atomic coordinate x) have been measured as discussed by the authors.
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