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Thiazyl radicals: old materials for new molecular devices
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In this paper, a review describes recent advances in the development of thiazyl radicals, particularly dithiadiazolyl (RCNSSN), as molecule-based materials.Abstract:
This review describes recent advances in the development of thiazyl radicals, particularly dithiadiazolyl (RCNSSN) and dithiazolyl (RCSNSCR) as molecule-based materials. Particular emphasis is placed on their potential applications as molecular conductors, magnets and switchable materials and incorporates an overview of the structure–property relationships required in these molecular systems.read more
Citations
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Playing with organic radicals as building blocks for functional molecular materials
Imma Ratera,Jaume Veciana +1 more
TL;DR: This critical review provides an up-to-date survey to this new generation of multifunctional magnetic materials showing promise for applications in spintronics as well as bistable memory devices and sensing materials.
Journal ArticleDOI
What's new in stable radical chemistry?
TL;DR: This review provides a survey of the major classes of stable or persistent organic/organomain group radicals with a view to presenting a unified description of the interdependencies between radical molecular structure and properties.
Journal ArticleDOI
Pancake Bonding: An Unusual Pi-Stacking Interaction.
TL;DR: The role of van der Waals interactions in pancake bonded dimers, chains, and other aggregates is different from closed shell vdW aggregates: here the Pauli repulsions reduce the attractive dispersion interaction significantly.
Journal ArticleDOI
Pancake bonds: π-Stacked dimers of organic and light-atom radicals
TL;DR: In this paper, a survey of the more common organic and light-atom neutral radicals, radical cations and radical anions that are known to form π-dimers in the solid state is presented.
Journal ArticleDOI
Enhanced conductivity and magnetic ordering in isostructural heavy atom radicals.
Craig M. Robertson,Alicea A. Leitch,Kristina Cvrkalj,Robert W. Reed,Daniel J. T. Myles,Paul A. Dube,Richard T. Oakley +6 more
TL;DR: Variable temperature magnetic susceptibility measurements indicate that all four radicals exhibit S = 1/2 Curie-Weiss behavior over the temperature range 20-300 K, and at lower temperatures, the three selenium-based radicals display magnetic ordering.
References
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Journal ArticleDOI
Metal-insulator transitions
TL;DR: A review of the metal-insulator transition can be found in this article, where a pedagogical introduction to the subject is given, as well as a comparison between experimental results and theoretical achievements.
Journal ArticleDOI
Electron correlations in narrow energy bands
TL;DR: In this paper, the Hartree-Fock approximation of the correlation problem for the d-and f-bands was applied to a simple, approximate model for the interaction of electrons in narrow energy bands.
Journal ArticleDOI
Quantum theory of solids
Rudolf Peierls,Louis D. Roberts +1 more
TL;DR: In this article, the interaction of light with non-conducting crystals has been studied in the context of crystal lattices and its applications in general theory and applications, such as semi-conductivity and superconductivity.
Book
Handbook of organic conductive molecules and polymers
TL;DR: In this article, the properties of conjugated polymers and their properties were investigated at submicron scale with a scanning force microscope magnetic properties of conducting polymers Optically Detected Magnetic Resonance (ODMR).
Journal ArticleDOI
Organic molecular soft ferromagnetism in a fullerene c60.
Pierre-Marc Allemand,K. C. Khemani,A. Koch,Fred Wudl,Karoly Holczer,Steven Donovan,George Grüner,Joe D. Thompson +7 more
TL;DR: The properties of an organic molecular ferromagnet with a Curie temperature of 16.1 kelvin are described, where the ferromagnetic state shows no remanence, and the temperature dependence of the magnetization below ;Tc does not follow the behavior expected of a conventional ferromaagnet.
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