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Three-dimensional micro-XRF investigations of paint layers with a tabletop setup

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TLDR
The feasibility of 3D micro-XRF spectroscopy with a tabletop setup is demonstrated and its sensitivity in comparison to the synchrotron-based setup is discussed.
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This article is published in Spectrochimica Acta Part B: Atomic Spectroscopy.The article was published on 2005-01-10. It has received 126 citations till now.

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Development of confocal X-ray fluorescence (XRF) microscopy at the Cornell high energy synchrotron source

TL;DR: A confocal X-ray fluorescence microscope was built at the Cornell High Energy Synchrotron Source (CHESS) to obtain compositional depth profiles of historic paintings as discussed by the authors.
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Photon-based techniques for nondestructive subsurface analysis of painted cultural heritage artifacts.

TL;DR: A number of fundamentally new approaches for fully imaging the buildup of hidden paint layers and other complex three-dimensional (3D) substructures have been put into practice, and these developments and their recent practical application with CH artifacts are discussed.
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Recent developments in spectroscopic imaging techniques for historical paintings - A review

TL;DR: In this article, an overview of the application of scanning macro-XRF with mobile instruments for the investigation of historical paintings is presented, compared to synchrotron-based macro XRF imaging and Neutron Activation Auto-Radiography.
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A model for the confocal volume of 3D micro X-ray fluorescence spectrometer

TL;DR: In this article, the primary fluorescence intensity of 3D micro-XRF experiments is derived based on the fundamental parameter approach, where the confocal volume is defined by the X-ray optics used.
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High-definition X-ray fluorescence elemental mapping of paintings.

TL;DR: A corrective procedure was devised to enhance the visualization of the elemental maps by using the elastic X-ray scatter as a proxy for the lead white overpaint, and foresee the technique applied to the most demanding of culturally significant artworks where conventional analytical methods are inadequate.
References
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A new 3D micro X-ray fluorescence analysis set-up - First archaeometric applications

TL;DR: A 3D micro X-ray fluorescence (micro-XRF) analysis method based on a confocal Xray set-up is presented in this article, which is evaluated and illustrated with depth sensitive investigations of paint layers in ancient Indian Mughal miniatures.
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Three-dimensional trace element analysis by confocal X-ray microfluorescence imaging.

TL;DR: A three-dimensional variant of scanning micro X-ray fluorescence (XRF) is described and evaluated at the ID18F instrument of the European Synchrotron Radiation Facility (ESRF), based on confocal excitation/detection using a polycapillary half-lens in front of the energy-dispersive detector.
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ArtTAX--a new mobile spectrometer for energy-dispersive micro X-ray fluorescence spectrometry on art and archaeological objects.

TL;DR: A selection of qualitative and quantitative results on pigment, metal, glass, and enamel analyses are presented to show the potential of ArtTAX in the field of art and archaeology.
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Capillary optics and their use in x-ray analysis†

TL;DR: In this paper, the use of polycapillary lenses in X-ray microanalysis and Xray diffractometry is considered, and a new type of tube for obtaining a high photon flux with low divergence has been developed.
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Nondestructive three-dimensional elemental microanalysis by combined helical x-ray microtomographies

TL;DR: In this article, a non-destructive x-ray technique combining simultaneous transmission, fluorescence, and Compton microtomography has been developed for the microanalysis of rare and fragile samples from several research fields.
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