Journal ArticleDOI
Trivacant heteropolytungstate derivatives. 3. Rational syntheses, characterization, two-dimensional tungsten-183 NMR, and properties of tungstometallophosphates P2W18M4(H2O)2O6810- and P4W30M4(H2O)2O11216- (M = cobalt, copper, zinc)
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This article is published in Inorganic Chemistry.The article was published on 1987-11-01. It has received 368 citations till now. The article focuses on the topics: Cobalt & Zinc.read more
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Polyoxometalates: Very large clusters - Nanoscale magnets
Journal ArticleDOI
Layered double hydroxides (LDH) intercalated with metal coordination compounds and oxometalates
TL;DR: In this paper, the synthesis, properties and applications of layered double hydroxides (LDHs) are reviewed, also known as anionic clays or hydrotalcite-like materials containing intercalated anions constituted by metal complexes or oxometalates.
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Epoxidation of olefins with hydrogen peroxide catalyzed by polyoxometalates
TL;DR: In this article, a review of recent developments for the epoxidation of olefins with hydrogen peroxide catalyzed by polyoxometalates is presented, which can be classified into two groups according to the structural and mechanistic aspects: (i) catalyst precursors of peroxotungstate or peroxomolybdate species and (ii) oxidatively and hydrolytically stable transition-metal-substituted polyoxmetalates.
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Present General Status of Understanding of Heteropoly Electrolytes and a Tracing of Some Major Highlights in the History of Their Elucidation
Louis C. W. Baker,Diana C. Glick +1 more
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Magnetic clusters from polyoxometalate complexes
TL;DR: In this article, the authors highlight the increasing interest of polyoxometalates in molecular magnetism, providing at the same time a perspective of the state-of-the-art in this area.
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