How does annealing affect the properties of CsI films?5 answersAnnealing has a significant effect on the properties of CsI films. The annealing temperature plays a crucial role in the formation and stability of Cs2TeI6 films. At an annealing temperature of 240ºC, the Cs2TeI6 film is black, tightly packed, and pin-hole free, with good adhesion to the substrate. It exhibits high absorbance in the visible region with an optical bandgap of 1.61 eV and remains stable in humid air for 20 weeks. The annealing process also affects the magnetic properties of films. For Co2FeSi (CFS) films, annealing induces perpendicular magnetic anisotropy (PMA) and increases the saturation magnetization. In the case of silicon carbon nitride (Si-C-N) films, annealing at different temperatures leads to shifts in the photoluminescence (PL) bands and changes in mechanical properties. Additionally, annealing temperature influences the electrochemical performance of silicon carbide (SiC) anode films, with higher annealing temperatures resulting in improved capacity and rate performance.
What is the optimal annealing temperature for antimony tin oxide?5 answersThe optimal annealing temperature for antimony tin oxide (ATO) varies depending on the study. Flores-Hernández et al. found that the ATO thin film annealed at 425°C exhibited the lowest electrical resistivity. Salwa et al. observed that the energy gap of tin sulfide films decreased with increasing annealing temperature in the range of 400-550°C. Arora and Hiroya reported that the direct band gap of SnO2-t phase synthesized from a solution pH of 8 and annealed at 400°C was approximately 4.50 eV. Sujatha Lekshmy et al. discovered that the optical energy band gap values of antimony-doped tin oxide films increased with the increase in annealing temperature, ranging from 4.13 eV to 4.83 eV. Chen et al. found that the optimal resistivity for ATO thin films was achieved at an annealing temperature of 550°C, with a value of 2.7×10-3 Ω cm. Therefore, the optimal annealing temperature for antimony tin oxide can range from 400°C to 550°C, depending on the specific properties being targeted.
What is the effect of post-annealing on the structural and optical properties of ZnO and AZO thin films?4 answersPost-annealing has a significant effect on the structural and optical properties of ZnO and AZO thin films. The annealing process improves the texture coefficient of the films, leading to an increase in the crystallite size and a reduction in the amorphous phase. This results in a narrowing of the band gap energy and an improvement in the crystalline phase, leading to an increase in transmittance values. The annealed films also show improved optical response and photoluminescence emission intensities. Additionally, the annealing process can increase the carrier mobility and decrease the sheet resistances of the films. Overall, post-annealing enhances the structural and optical properties of ZnO and AZO thin films, making them suitable for applications such as optical sensing, light emitting diodes (LEDs), and biological applications.
Gas sensing performance of pure and doped tin oxides films for H2S and methane gas detection?5 answersGas sensing performance of pure and doped tin oxide films for H2S and methane gas detection has been studied in several papers. The sensitivity of gas sensors has been found to increase as the thickness of the metal oxide semiconductor film decreases. Tin oxide (SnO2) and nickel-doped tin oxide (NSO) thin films have been shown to have good gas sensing properties, with NSO films exhibiting enhanced performance towards NO2 gas at 100 °C. Undoped and PbO-doped SnO2 thick films have also been investigated, with PbO doping resulting in decreased crystallite size and improved sensing response to ethanol gas. Ni-doped ZnO nanowire arrays have been found to have high selectivity for H2S gas and a large response compared to other gases, with an optimum Ni precursor concentration of 8 at. %. Fe-doped SnO2 films have shown a decrease in optical transmittance and energy gap with increasing Fe doping.
What are the effects of laser annealing on the properties of semiconductors?4 answersLaser annealing has several effects on the properties of semiconductors. It allows for localized heating and the ability to tune the effective heating depth, which is beneficial for semiconductor processing. Laser annealing can control the direction of recrystallization, resulting in larger crystal grains with fewer boundaries and improved electron mobility in the semiconductor layer. It also enables the formation of two molten regions with elongate shapes congruent to each other, arranged in line symmetry, during the annealing process. Additionally, laser annealing can be performed multiple times with a prescribed time interval between irradiation of different regions, leading to improved annealing of the semiconductor substrate. By irradiating the semiconductor film with a pulse laser beam within a specific power density range, laser annealing can achieve uniform crystallization without inducing abnormal grain growth, resulting in uniform crystals with little variation.
What is the effect of annealing on the dual phase structure?5 answersAnnealing has a significant effect on the dual-phase structure. Increasing the intercritical annealing temperature leads to an increase in the volume fraction and grain size of martensite, while the volume fraction and grain size of ferrite decrease. The amount of martensite in the microstructure can be controlled by adjusting the intercritical annealing temperature, which affects the strength level of the dual-phase steel. The annealing process also influences the evolution of the microstructure and texture, as well as the final mechanical properties of the dual-phase steel. Non-isothermal annealing processes can affect the hardness and lattice tetragonality of the martensite phase, as well as the structure parameters of the martensite phase in dual-phase steel. Overall, annealing plays a crucial role in determining the microstructure, mechanical properties, and strength of dual-phase steels.