scispace - formally typeset
Search or ask a question

Showing papers on "Bilayer graphene published in 2023"


Journal ArticleDOI
TL;DR: In the presence of a large perpendicular electric field, Bernal-stacked bilayer graphene (BLG) features several broken-symmetry metallic phases as well as magnetic-field-induced superconductivity as discussed by the authors .
Abstract: In the presence of a large perpendicular electric field, Bernal-stacked bilayer graphene (BLG) features several broken-symmetry metallic phases as well as magnetic-field-induced superconductivity. The superconducting state is quite fragile, however, appearing only in a narrow window of density and with a maximum critical temperature $T_c\approx30$~mK. Here, we show that placing monolayer tungsten diselenide (WSe$_{2}$) on BLG promotes Cooper pairing to an extraordinary degree: superconductivity appears at zero magnetic field, exhibits an order of magnitude enhancement in $T_c$, and occurs over a density range that is wider by a factor of eight. By mapping quantum oscillations in BLG-WSe$_2$ as a function of electric field and doping, we establish that superconductivity emerges throughout a region whose normal state is polarized, with two out of four spin-valley flavours predominantly populated. In-plane magnetic field measurements further reveal a striking dependence of the critical field on doping, with the Chandrasekhar-Clogston (Pauli) limit roughly obeyed on one end of the superconducting dome yet sharply violated on the other. Moreover, the superconductivity arises only for perpendicular electric fields that push BLG hole wavefunctions towards WSe$_2$ -- suggesting that proximity-induced (Ising) spin-orbit coupling plays a key role in enhancing the pairing. Our results pave the way for engineering robust, highly tunable, and ultra-clean graphene-based superconductors.

20 citations


Journal ArticleDOI
TL;DR: In this paper , the authors show that bilayer Td-MoTe2 simultaneously exhibits ferroelectric switching and superconductivity, and show that the superconducting transition temperature is concomitant with compensated electron and hole carrier densities and vanishes when one of the Fermi pockets disappears with doping.
Abstract: Achieving electrostatic control of quantum phases is at the frontier of condensed matter research. Recent investigations have revealed superconductivity tunable by electrostatic doping in twisted graphene heterostructures and in two-dimensional semimetals such as WTe2 (refs. 1–5). Some of these systems have a polar crystal structure that gives rise to ferroelectricity, in which the interlayer polarization exhibits bistability driven by external electric fields6–8. Here we show that bilayer Td-MoTe2 simultaneously exhibits ferroelectric switching and superconductivity. Notably, a field-driven, first-order superconductor-to-normal transition is observed at its ferroelectric transition. Bilayer Td-MoTe2 also has a maximum in its superconducting transition temperature (Tc) as a function of carrier density and temperature, allowing independent control of the superconducting state as a function of both doping and polarization. We find that the maximum Tc is concomitant with compensated electron and hole carrier densities and vanishes when one of the Fermi pockets disappears with doping. We argue that this unusual polarization-sensitive two-dimensional superconductor is driven by an interband pairing interaction associated with nearly nested electron and hole Fermi pockets. The authors show a hysteretic behaviour of superconductivity as a function of electric field in bilayer Td-MoTe2, representing observations of coupled ferroelectricity and superconductivity.

15 citations


Journal ArticleDOI
TL;DR: In this paper , a gate-defined symmetry-broken Josephson junction was constructed in magic-angle twisted bilayer graphene, where the weak link was gate-tuned close to the correlated insulator state with a moiré filling factor of υ = -2.
Abstract: The coexistence of gate-tunable superconducting, magnetic and topological orders in magic-angle twisted bilayer graphene provides opportunities for the creation of hybrid Josephson junctions. Here we report the fabrication of gate-defined symmetry-broken Josephson junctions in magic-angle twisted bilayer graphene, where the weak link is gate-tuned close to the correlated insulator state with a moiré filling factor of υ = -2. We observe a phase-shifted and asymmetric Fraunhofer pattern with a pronounced magnetic hysteresis. Our theoretical calculations of the junction weak link-with valley polarization and orbital magnetization-explain most of these unconventional features. The effects persist up to the critical temperature of 3.5 K, with magnetic hysteresis observed below 800 mK. We show how the combination of magnetization and its current-induced magnetization switching allows us to realise a programmable zero-field superconducting diode. Our results represent a major advance towards the creation of future superconducting quantum electronic devices.

11 citations


Journal ArticleDOI
TL;DR: In this article , the authors demonstrate a quantum simulation of superfluid to Mott insulator transition in twisted-bilayer square lattices based on atomic Bose-Einstein condensates loaded into spin-dependent optical lattices.
Abstract: Observation of strong correlations and superconductivity in twisted-bilayer graphene1-4 has stimulated tremendous interest in fundamental and applied physics5-8. In this system, the superposition of two twisted honeycomb lattices, generating a moiré pattern, is the key to the observed flat electronic bands, slow electron velocity and large density of states9-12. Extension of the twisted-bilayer system to new configurations is highly desired, which can provide exciting prospects to investigate twistronics beyond bilayer graphene. Here we demonstrate a quantum simulation of superfluid to Mott insulator transition in twisted-bilayer square lattices based on atomic Bose-Einstein condensates loaded into spin-dependent optical lattices. The lattices are made of two sets of laser beams that independently address atoms in different spin states, which form the synthetic dimension accommodating the two layers. The interlayer coupling is highly controllable by a microwave field, which enables the occurrence of a lowest flat band and new correlated phases in the strong coupling limit. We directly observe the spatial moiré pattern and the momentum diffraction, which confirm the presence of two forms of superfluid and a modified superfluid to insulator transition in twisted-bilayer lattices. Our scheme is generic and can be applied to different lattice geometries and for both boson and fermion systems. This opens up a new direction for exploring moiré physics in ultracold atoms with highly controllable optical lattices.

5 citations


Journal ArticleDOI
TL;DR: Bilayer graphene in the presence of a superlattice potential can be an alternative platform to realize moir\ifmmode \acute{}\else \'{}\fi{}e physics as mentioned in this paper .
Abstract: Bilayer graphene in the presence of a superlattice potential can be an alternative platform to realize moir\ifmmode \acute{}\else \'{}\fi{}e physics, where the superlattice symmetry and geometry can be chosen on demand.

4 citations


Journal ArticleDOI
TL;DR: In this article , the authors predict that the spin/valley isospin magnetism, resembling that seen in moir\'{e} bands, coexists with momentum-polarized phases occurring via a ''flocking transition'' in momentum space.
Abstract: Electron bands in the untwisted bilayer graphene flatten out in a transverse electric field, offering a promising platform for correlated electron physics. We predict that the spin/valley isospin magnetism, resembling that seen in moir\'{e} bands, coexists with momentum-polarized phases occurring via a ``flocking transition'' in momentum space. This transition results in the electron momentum distribution being spontaneously displaced relative to the $K$ and $K'$ valley centers. These phases feature unusual observables such as persistent currents in the ground state. Momentum-polarized carriers ``sample'' the Berry curvature of the conduction band, resulting in a unique behavior of the anomalous Hall conductivity and other effects that do not occur in previously studied systems.

4 citations


Journal ArticleDOI
TL;DR: Vafek and Kang as discussed by the authors constructed effective continuum theories for two different microscopic tight-binding models of twisted bilayer graphene at a twist angle of $1.{05}^{\ensuremath{\circ}}$, one Slater-Koster based and the other ab initio Wannier based.
Abstract: Using the method developed in the companion paper [O. Vafek and J. Kang, Continuum effective Hamiltonian for graphene bilayers for an arbitrary smooth lattice deformation from microscopic theories, Phys. Rev. B 107, 075123 (2023)], we construct effective continuum theories for two different microscopic tight-binding models of twisted bilayer graphene at a twist angle of $1.{05}^{\ensuremath{\circ}}$, one Slater-Koster based and the other ab initio Wannier based. The energy spectra obtained from the continuum theory---either for rigid twist or including lattice relaxation---are found to be in nearly perfect agreement with the spectra from tight-binding models when the gradient expansion is carried out to second order, demonstrating the validity of the method. We also analyze the properties of the Bloch states of the resulting narrow bands, finding non-negligible particle-hole symmetry breaking near the $\mathrm{\ensuremath{\Gamma}}$ point in our continuum theory constructed for the ab initio-based microscopic model due to a term in the continuum theory that was previously overlooked. This reveals the difference with all existing continuum models where the particle-hole symmetry of the narrow band Hilbert space is nearly perfect.

4 citations


Journal ArticleDOI
TL;DR: In this paper , a topmost small-period graphene moiré pattern is introduced as a magnifying lens to magnify sub-Angstrom lattice distortions in small-angle twisted bilayer graphene.
Abstract: In two-dimensional small-angle twisted bilayers, van der Waals (vdW) interlayer interaction introduces an atomic-scale reconstruction, which consists of a moiré-periodic network of local subdegree lattice rotations. However, real-space measurement of the subdegree lattice rotation requires extremely high spatial resolution, which is an outstanding challenge in an experiment. Here, a topmost small-period graphene moiré pattern is introduced as a magnifying lens to magnify sub-Angstrom lattice distortions in small-angle twisted bilayer graphene (TBG) by about 2 orders of magnitude. Local moiré periods of the topmost graphene moiré patterns and low-energy van Hove singularities of the system are spatially modified by the atomic-scale reconstruction of the underlying TBG, thus enabling real-space mapping of the networks of the subdegree lattice rotations both in structure and in electronic properties. Our results indicate that it is quite facile to study subdegree lattice rotation in vdW systems by measuring the periods of the topmost moiré superlattice.

3 citations


Journal ArticleDOI
TL;DR: In this paper , a focused electron beam is used to define attachment points for foreign atoms through the controlled ejection of carbon atoms from the graphene lattice, which can induce migration of the source atoms across the sample surface.
Abstract: Atomic-scale engineering typically involves bottom-up approaches, leveraging parameters such as temperature, partial pressures, and chemical affinity to promote spontaneous arrangement of atoms. These parameters are applied globally, resulting in atomic scale features scattered probabilistically throughout the material. In a top-down approach, different regions of the material are exposed to different parameters resulting in structural changes varying on the scale of the resolution. In this work, we combine the application of global and local parameters in an aberration corrected scanning transmission electron microscope (STEM) to demonstrate atomic scale precision patterning of atoms in twisted bilayer graphene. The focused electron beam is used to define attachment points for foreign atoms through the controlled ejection of carbon atoms from the graphene lattice. The sample environment is staged with nearby source materials, such that the sample temperature can induce migration of the source atoms across the sample surface. Under these conditions, the electron-beam (top-down) enables carbon atoms in the graphene to be replaced spontaneously by diffusing adatoms (bottom-up). Using image-based feedback-control, arbitrary patterns of atoms and atom clusters are attached to the twisted bilayer graphene with limited human interaction. The role of substrate temperature on adatom and vacancy diffusion is explored by first-principles simulations. This article is protected by copyright. All rights reserved.

3 citations


Journal ArticleDOI
TL;DR: In this article , a zero-temperature phase diagram of a symmetric electron-hole bilayer with twofold valley degeneracy, as a function of the interlayer distance and in-layer density, is presented.
Abstract: Using quantum Monte Carlo simulations we have mapped out the zero-temperature phase diagram of a symmetric electron-hole bilayer with twofold valley degeneracy, as a function of the interlayer distance $d$ and in-layer density $n$. We find that the effect of the valley degeneracy is to shrink the region of stability of the excitonic condensate, in favor of quadriexcitons at small $d$ and of the four-component plasma at large $d$, with minor effects on the value of the excitonic condensate fraction. The enclosure of the condensate in a density window possibly explains why anomalous tunneling conductivity, interpreted as a signature of condensation, is observed only between two finite values of carrier density in graphene bilayers. Our phase diagram may provide directions to select device parameters for future experiments.

3 citations


Journal ArticleDOI
TL;DR: In this article , gate-defined Josephson junctions in magic angle twisted bilayer graphene (MATBG) were studied experimentally and highly unconventional Fraunhofer patterns were observed.
Abstract: Recently, gate-defined Josephson junctions in magic angle twisted bilayer graphene (MATBG) were studied experimentally and highly unconventional Fraunhofer patterns were observed. In this work, we show that an interaction-driven valley-polarized state connecting two superconducting regions of MATBG would give rise to a long-sought-after purely electric controlled $\varphi_0$-junction in which the two superconductors acquire a finite phase difference $\varphi_0$ in the ground state. We point out that the emergence of the $\varphi_0$-junction stems from the valley-polarized state which breaks time-reversal symmetry and trigonal warping effects which break the intravalley inversion symmetry. Importantly, a spatially non-uniform valley polarization order parameter at the junction can explain the highly unconventional Fraunhofer patterns observed in the experiment. Our work explores the novel transport properties of the valley-polarized state and suggests that gate-defined MATBG Josephson junctions could realize the first purely electric controlled $\varphi_0$-junctions with applications in superconducting devices.

Journal ArticleDOI
TL;DR: In this article , it was shown that bilayer graphene allows realizing electron-hole double quantum-dots that exhibit nearly perfect particle-hole symmetry, where transport occurs via the creation and annihilation of single electronhole pairs with opposite quantum numbers.
Abstract: Particle-hole symmetry plays an important role for the characterization of topological phases in solid-state systems. It is found, for example, in free-fermion systems at half filling, and it is closely related to the notion of antiparticles in relativistic field theories. In the low energy limit, graphene is a prime example of a gapless particle-hole symmetric system described by an effective Dirac equation, where topological phases can be understood by studying ways to open a gap by preserving (or breaking) symmetries. An important example is the intrinsic Kane-Mele spin-orbit gap of graphene, which leads to a lifting of the spin-valley degeneracy and renders graphene a topological insulator in a quantum spin Hall phase, while preserving particle-hole symmetry. Here, we show that bilayer graphene allows realizing electron-hole double quantum-dots that exhibit nearly perfect particle-hole symmetry, where transport occurs via the creation and annihilation of single electron-hole pairs with opposite quantum numbers. Moreover, we show that this particle-hole symmetry results in a protected single-particle spin-valley blockade. The latter will allow robust spin-to-charge conversion and valley-to-charge conversion, which is essential for the operation of spin and valley qubits.

Journal ArticleDOI
01 Jan 2023-Carbon
TL;DR: In this article , the authors combine Raman spectroscopy with the Gaussian mixture model (GMM) data clustering algorithm to identify areas with particular twist angles, from a TBLG sample with a mixture of orientations.

Journal ArticleDOI
TL;DR: In this article , the authors present and discuss practical techniques for formulating effective models to describe the low-energy electronic properties of bilayer graphene systems, and show that such effective models are constructed from a collection of appropriate single-layer Bloch states of two graphene layers.
Abstract: We present and discuss practical techniques for formulating effective models to describe the low-energy electronic properties of bilayer graphene systems. We show that such effective models are constructed from a collection of appropriate single-layer Bloch states of two graphene layers. In general, the obtained effective models allow the construction of a so-called moiré band structure. However, it is not the result of an irreducible representation of a translation symmetry group of the bilayer lattices except for the commensurate bilayer configurations. We also point out that the commensurate bilayer configurations are classified into three categories depending on the divisibility of the difference between two commensurate integer indices by 3. The electronic band structure of three lattice configurations, one for each category, is shown. Especially by combining with a real-space calculation, we validate the working ability of constructed effective models for generic bilayer graphene systems by showing that the effects of interlayer sliding are diminished by twisting. This result is consistent with the invariance of effective models under the interlayer sliding operation.

Journal ArticleDOI
TL;DR: In this paper , the authors proposed a paradigm for bilayer materials, where covalent bonding replaces the van der Waals interaction between the layers, showing promising properties for 2D ferroelectricity.
Abstract: Abstract The discovery of twisted bilayer graphene with tunable superconductivity has diverted great focus at the world of twisted van der Waals heterostructures. Here we propose a paradigm for bilayer materials, where covalent bonding replaces the van der Waals interaction between the layers. On the example of germanene-stanene bilayer, we show that such systems demonstrate fascinating topological properties and manifest giant capacitance effects of the order of C = 10 2 μ F as well as dipole-like charge densities of q = 1 − 2 × 10 −4 μ C cm −2 , showing promise for 2D ferroelectricity. The observed unique behaviour is closely linked to transverse strain-induced buckling deformations at the bilayer/substrate interface. In alternative GeSn bilayer structures with low twist angles the strain distortions trigger rich topological defect physics. We propose that the GeSn bilayer topology may be switched locally by a substrate-strain-induced electric fields. We demonstrate an approach to fabricate covalent bilayer materials, holding vast possibilities to transform applications technologies across solar, energy and optoelectronic sectors.

Journal ArticleDOI
TL;DR: In this article , the authors characterize correlated states in an alternating twisted Bernal bilayer-monolayer and Monolayer-Monoline-Monolayer (MONOLayer)-Monoline (MonOLayer) graph of ∼ 1.74° and find that both van Hove singularities and multiple correlated states are asymmetrically tuned by displacement fields.
Abstract: Highly controlled electronic correlation in twisted graphene heterostructures has gained enormous research interests recently, encouraging exploration in a wide range of moiré superlattices beyond the celebrated twisted bilayer graphene. Here we characterize correlated states in an alternating twisted Bernal bilayer–monolayer–monolayer graphene of ∼ 1.74°, and find that both van Hove singularities and multiple correlated states are asymmetrically tuned by displacement fields. In particular, when one electron per moiré unit cell is occupied in the electron-side flat band, or the hole-side flat band (i.e., three holes per moiré unit cell), the correlated peaks are found to counterintuitively grow with heating and maximize around 20 K – a signature of Pomeranchuk effect. Our multilayer heterostructure opens more opportunities to engineer complicated systems for investigating correlated phenomena.

Journal ArticleDOI
TL;DR: In this article , a real space derivation of the continuum Hamiltonian for a graphene bilayer starting from a microscopic lattice theory, allowing for an arbitrary inhomogeneous smooth lattice deformation, including a twist, is presented.
Abstract: We provide a systematic real space derivation of the continuum Hamiltonian for a graphene bilayer starting from a microscopic lattice theory, allowing for an arbitrary inhomogeneous smooth lattice deformation, including a twist. Two different microscopic models are analyzed: first, a Slater-Koster like model and second, ab-initio derived model. We envision that our effective Hamiltonian can be used in conjunction with an experimentally determined atomic lattice deformation in twisted bilayer graphene in a specific device to predict and compare the electronic spectra with scanning tunneling spectroscopy measurements. As a byproduct, our approach provides electron-phonon couplings in the continuum Hamiltonian from microscopic models for any bilayer stacking. In the companion paper we analyze in detail the continuum models for relaxed atomic configurations of magic angle twisted bilayer graphene.

Journal ArticleDOI
TL;DR: In this article , an electron-electron mechanism is applied to the continuum framework of Bernal bilayer and rhombohedral trilayer graphene, and the internal screening of the long-range Coulomb potential leads to an effective attraction between carriers, enabling the formation of Cooper pairs.
Abstract: What drives superconductivity in non-moir\'e graphene? Here, an electron-electron mechanism is applied to the continuum framework of Bernal bilayer and rhombohedral trilayer graphene. Within a Kohn-Luttinger-like approach, the internal screening of the long-range Coulomb potential leads to an effective attraction between carriers, enabling the formation of Cooper pairs. The calculations provide a filling-dependent critical temperature that is remarkably enhanced due to Ising spin-orbit coupling, and determine the spin-triplet valley-singlet symmetry of the superconducting order parameter, in line with recent experimental advances.

Journal ArticleDOI
TL;DR: In this paper , the density of states of multilayer graphene with up to four layers at the single-particle band structure level in the presence of a transverse electric field was investigated.
Abstract: Motivated by the recent discoveries of superconductivity in bilayer and trilayer graphene, we theoretically investigate superconductivity and other interaction-driven phases in multilayer graphene stacks. To this end, we study the density of states of multilayer graphene with up to four layers at the single-particle band structure level in the presence of a transverse electric field. Among the considered structures, tetralayer graphene with rhombohedral (ABCA) stacking reaches the highest density of states. We study the phases that can arise in ABCA graphene by tuning the carrier density and transverse electric field. For a broad region of the tuning parameters, the presence of strong Coulomb repulsion leads to a spontaneous spin and valley symmetry breaking via Stoner transitions. Using a model that incorporates the spontaneous spin and valley polarization, we explore the Kohn-Luttinger mechanism for superconductivity driven by repulsive Coulomb interactions. We find that the strongest superconducting instability is in the $p-$wave channel, and occurs in proximity to the onset of Stoner transitions. Interestingly, we find a range of densities and transverse electric fields where superconductivity develops out of a strongly corrugated, singly-connected Fermi surface in each valley, leading to a topologically non-trivial chiral $p+ip$ superconducting state with an even number of co-propagating chiral Majorana edge modes. Our work establishes ABCA stacked tetralayer graphene as a promising platform for observing strongly correlated physics and topological superconductivity.

Journal ArticleDOI
TL;DR: In this paper , the authors reported a local minimum in thermal conductivity in twisted bilayer graphene at the angle of 1.08°, which corresponds to the "magic angle" in the transition of several other reported properties.

Journal ArticleDOI
TL;DR: In this article , it was shown that for high-order magic angles, the zero flat band modes converged into coherent Landau states with a dispersion of π 2 = 1/3 π α, where α is a coupling parameter that incorporates the twist angle and energetic scales.
Abstract: Flat band electronic modes in twisted graphene bilayers are responsible for superconducting and other highly correlated electron-electron phases. Although some hints were known of a possible connection between the quantum Hall effect and zero flat band modes, it was not clear how such connection appears. Here the electronic behavior in twisted bilayer graphene is studied using the chiral model Hamiltonian. As a result, it is proved that for high-order magic angles, the zero flat band modes converge into coherent Landau states with a dispersion $\sigma^2=1/3\alpha$, where $\alpha$ is a coupling parameter that incorporates the twist angle and energetic scales. Then it is proved that the square of the hamiltonian, which is a $2\times 2$ matrix operator, turns out to be equivalent to a two-dimensional quantum harmonic oscillator. The interlayer currents between graphene's bipartite lattices are identified with the angular momentum term while the confinement potential is an effective quadratic potential. From there it is proved a limiting quantization rule for high-order magic angles, i.e., $\alpha_{m+1}-\alpha_{m}=3/2$ where $m$ is the order of the angle. All these results are in very good agreement with numerical calculations.


Journal ArticleDOI
TL;DR: In this article , the authors evaluate the differential conductance measured in an STM setting at arbitrary electron transmission between STM tip and a 2D superconductor with arbitrary gap structure.
Abstract: We evaluate the differential conductance measured in an STM setting at arbitrary electron transmission between STM tip and a 2D superconductor with arbitrary gap structure. Our analytical scattering theory accounts for Andreev reflections, which become prominent at larger transmissions. We show that this provides complementary information about the superconducting gap structure beyond the tunneling density of states, strongly facilitating the ability to extract the gap symmetry and its relation to the underlying crystalline lattice. We use the developed theory to discuss recent experimental results on superconductivity in twisted bilayer graphene.

Journal ArticleDOI
TL;DR: In this article , the behavior of bilayer graphene-carbon nanotube hybrid films with island topology under axial deformation was studied using the selfconsistent charge density functional tight binding (SCC-DFTB) method.
Abstract: Using the self-consistent charge density functional tight-binding (SCC-DFTB) method, we study the behavior of graphene-carbon nanotube hybrid films with island topology under axial deformation. Hybrid films are formed by AB-stacked bilayer graphene and horizontally aligned chiral single-walled carbon nanotubes (SWCNTs) with chirality indices (12,6) and 1.2 nm in diameter. In hybrid films, bilayer graphene is located above the nanotube, forming the so-called “islands” of increased carbon density, which correspond to known experimental data on the synthesis of graphene-nanotube composites. Two types of axial deformation are considered: stretching and compression. It has been established that bilayer graphene-SWCNT (12,6) hybrid films are characterized by elastic deformation both in the case of axial stretching and axial compression. At the same time, the resistance of the atomic network of bilayer graphene-SWCNT (12,6) hybrid films to failure is higher in the case of axial compression. Within the framework of the Landauer-Buttiker formalism, the current-voltage characteristics of bilayer graphene-SWCNT (12,6) hybrid films are calculated. It is shown that the slope of the current-voltage characteristic and the maximum values of the current are sensitive to the topological features of the bilayer graphene in the composition of graphene-SWCNT (12,6) hybrid film. Based on the obtained results, the prospects for the use of island-type graphene-nanotube films in flexible and stretchable electronic devices are predicted.


Journal ArticleDOI
TL;DR: In this article , the authors demonstrate the fast synthesis of meter-sized bilayer graphene film on commercial polycrystalline Cu foils by introducing trace CO 2 during high-temperature growth.
Abstract: Abstract Bilayer graphene (BLG) is intriguing for its unique properties and potential applications in electronics, photonics, and mechanics. However, the chemical vapor deposition synthesis of large-area high-quality bilayer graphene on Cu is suffering from a low growth rate and limited bilayer coverage. Herein, we demonstrate the fast synthesis of meter-sized bilayer graphene film on commercial polycrystalline Cu foils by introducing trace CO 2 during high-temperature growth. Continuous bilayer graphene with a high ratio of AB-stacking structure can be obtained within 20 min, which exhibits enhanced mechanical strength, uniform transmittance, and low sheet resistance in large area. Moreover, 96 and 100% AB-stacking structures were achieved in bilayer graphene grown on single-crystal Cu(111) foil and ultraflat single-crystal Cu(111)/sapphire substrates, respectively. The AB-stacking bilayer graphene exhibits tunable bandgap and performs well in photodetection. This work provides important insights into the growth mechanism and the mass production of large-area high-quality BLG on Cu.

Journal ArticleDOI
TL;DR: In this paper , the authors showed that due to the nearly perfect spin rotation symmetry of graphene, the fluctuations of the spin orientation of the triplet order parameter suppress the superconducting transition to nearly zero temperature and showed that both Ising spin-orbit coupling and in-plane magnetic field can eliminate these low-lying fluctuations and can greatly enhance the transition temperature.
Abstract: A recent experiment showed that proximity induced Ising spin-orbit coupling enhances the spin-triplet superconductivity in Bernal bilayer graphene. Here, we show that, due to the nearly perfect spin rotation symmetry of graphene, the fluctuations of the spin orientation of the triplet order parameter suppress the superconducting transition to nearly zero temperature. Our analysis shows that both Ising spin-orbit coupling and in-plane magnetic field can eliminate these low-lying fluctuations and can greatly enhance the transition temperature, consistent with the recent experiment. Our model also suggests the possible existence of a phase at small anisotropy and magnetic field which exhibits quasi-long-range ordered spin-singlet charge 4e superconductivity, even while the triplet 2e superconducting order only exhibits short-ranged correlations. Finally, we discuss relevant experimental signatures.

Journal ArticleDOI
01 Jan 2023-Carbon
TL;DR: In this paper , the authors investigated the quantum Hall effects in unipolar and bipolar monolayer-bilayer graphene (MLG-BLG) junctions and showed that the interference in such structures can be drastically affected by the type of (zigzag) edge termination of the second layer.

Journal ArticleDOI
TL;DR: In this article , a tight-binding description is utilized to investigate electronic structures and density of states of single-layer (SL) and bilayer (BL) graphene ribbons with and without the influence of external electric fields.
Abstract: Herein, a tight‐binding description is utilized to investigate electronic structures and density of states of single‐layer (SL) and bilayer (BL) graphene ribbons with and without the influence of external electric fields. Analyses are implemented to reveal the similarity and difference among electronic properties of three types of structures (specifically SL and BL ribbons with AA and AB stackings). Moreover, both armchair and zigzag edge orientations are considered. It is indicated in the results that variation in electronic properties of these structures in the presence of external electric fields depends on both structural form and edge orientation. The following two points are demonstrated: 1) a transverse field has a significant effect on adjusting bandgap of the zigzag configurations, whereas a vertical electric field has a distinct impact on energy bands of armchair edge structures, and 2) among considered structures, AB‐stacking BL ribbons are invariably the structures that are most strongly influenced by external fields. Interestingly, AB‐stacking BL ribbons are also capable of enlarging bandgap with both edge terminations. Herein, an insight into how the electronic structure and charge distribution of both SL and BL graphene nanoribbons can be controlled not only in armchair but also in zigzag edge terminations using electric stimulants is provided by the results.

Journal ArticleDOI
TL;DR: In this paper , the structural and electronic properties of bilayer SnS/graphene, bilayer NS/bilayer graphene (AA-stacked), bilayer n-type Schottky contacts and bilayer vdW van der Waals (vdW) heterostructures were investigated.