scispace - formally typeset
Search or ask a question

Showing papers on "Reverse osmosis published in 1989"


Journal ArticleDOI
TL;DR: The economic feasibility of preconcentrating dilute sugar solutions prior to fermentation is investigated and reverse osmosis was found to be economically feasible for preconcentration to about 5–10 wt % depending on the concentration of the feed.
Abstract: The economic feasibility of preconcentrating dilute sugar solutions prior to fermentation is investigated. Two methods, evaporation and reverse osmosis, are compared. A computer program to determine the optimal preconcentration conditions for glucose solutions of 1.5–16 wt% has been developed. It was used to compute the fractional cost for labor and maintenance, preconcentration, fermentation, and distillation. Preconcentration with evaporation resulted in a higher total cost, compared with no preconcentration, for all cases studied, although a six-effect unit was used. Reverse osmosis was found to be economically feasible for preconcentration to about 5–10 wt % depending on the concentration of the feed.

200 citations


Patent
25 Aug 1989
TL;DR: In this article, an interfacially synthesized reverse osmosis membrane was proposed for desalination of an aqueous solution, which is useful for the separation of fluid mixtures and solutions.
Abstract: The present invention relates to an interfacially synthesized reverse osmosis membrane useful for the separation of fluid mixtures and solutions. In particular, the present invention relates to an aromatic polyamide water permeable membrane containing an amine salt therein, which is useful for desalination of an aqueous solution. The present invention also relates to processes for preparing the membrane.

136 citations


Journal ArticleDOI
TL;DR: In this paper, a new class of selective reverse osmosis membranes is described and the performance of such membranes is demonstrated with an observed negative rejection of the organic ions of molecular weight lower than a few hundred daltons from NaCl.

119 citations


Patent
02 Oct 1989
TL;DR: An installation for filtering drinking water out of contaminated water, which can be used in many different situations, as it consists of a hydrocyclone, a micro filter unit, a unit for reverse osmosis, a mixed bed ion exchange, a re-salting unit, unit for ozonization, an activated carbon filter and unit for chlorinization as mentioned in this paper.
Abstract: An installation for filtering drinking water out of contaminated water, which can be used in many different situations, as it consists of a hydrocyclone, a micro filter unit, a unit for reverse osmosis, a mixed bed ion exchange, a re-salting unit, a unit for ozonization, an activated carbon filter and a unit for chlorinization.

100 citations


Patent
30 Aug 1989
TL;DR: A vending or dispensing system for providing purified water in response to a customer request is described in this article, where water dispensing systems have a water reservoir or tank containing first stage purified water and is provided with a subsystem for circulating water from the reservoir through a microbial sterilizer on at least a periodic basis for a predetermined period of time to maintain water quality within the tank.
Abstract: A vending or dispensing system for providing purified water in response to a customer request is described. The water dispensing system has a water reservoir or tank containing first stage purified water and is provided with a subsystem for circulating water from the reservoir through a microbial sterilizer on at least a periodic basis for a predetermined period of time to maintain water quality within the tank. In one aspect, the water is passed through the microbial sterilizer before entering the tank for the first time as first stage water. Additional features described to insure water purity include flushing or rinsing the lines between a first stage water purification mechanism and the water reservoir prior to topping off the reservoir with purified water, and providing control mechanisms for ensuring that sump liquid cannot be suctioned back into the system. The purification mechanism, of which there may be more than one, may include, but is not limited to, an activated carbon filter, an ion exchange resin bed, a reverse osmosis (RO) filter and the like. The microbial sterilizer may include such equipment as one or more or multi-stage ultraviolet (UV) sterilizers. In one embodiment, the entire system is operated by a microcontroller in response to user commands.

96 citations


Journal ArticleDOI
TL;DR: In this article, nanofiltration membranes have been used to remove trihalomethanes (THMs) from water containing natural substances such as humic and fulvic acids, called THM precursors.

79 citations


Journal ArticleDOI
TL;DR: In this article, a pilot study was undertaken to evaluate the efficacy of membrane filtration for the removal of particulate material from two untreated water supplies in Northern California, and the study showed that the ultrafiltration process was very effective in removing particulates from both sources.
Abstract: A pilot study was undertaken to evaluate the efficacy of membrane filtration for the removal of particulate material from two untreated water supplies in Northern California. The permeate produced by the hollow-fiber ultrafiltration module was assessed by monitoring four water quality parameters: turbidity, suspended solids, direct particle counts, and selected indicator bacteria. The study showed that the ultrafiltration process was very effective in removing particulates from both sources. It appeared that a constant final water quality in relation to particulate material was achieved regardless of the differences in concentrations or numbers of particles in the raw waters. Membrane technology is becoming increasingly popular as an alternative process in the drinking water treatment train. The anticipation of more stringent water quality regulations, a decrease in adequate water resources, and an emphasis on water reuse have made membrane processes more viable for drinking water treatment. As advancements are being made in membrane technology, capital and operation and maintenance costs decline, further supporting the use of membrane treatment techniques. Figure 1 presents various separation processes that are employed in water treatment and the typical size ranges of materials found in raw waters.’ The primary driving force behind the development of membrane processes for municipal drinking water supplies has been desalination, i.e., reverse osmosis (RO), in which high pressures have traditionally been used for salt removal. Recent advances have included the development of nanofilters or softening membranes that commonly use pressures in the range of 75-250 psi.2 Other membrane processes include ultrafiltration (UF) and microfiltration. Although UF has been employed for water treatment in manufacturing and other industries, its use as a treatment for drinking water is a recent concept. Only in the last 20 years have membranes been available on a commercial scale, and only in the last few years has UF of drinking water been regularly studied on a pilot scale. There are many potential advantages to treatment of drinking water by UF for liquid-solid separation compared with conventional treatment. These include production of a superior quality water, addition of fewer chemicals in the treatment process, lower energy requirements for operation and maintenance, and design and construc68

54 citations


Patent
Robert C. Schucker1
09 Aug 1989
TL;DR: In this paper, nonporous isocyanurate-crosslinked polyurethane membranes are used for the separation of aromatic hydrocarbons from non-aromatic hydrocarbonbons, using any commonly accepted membrane separation technique, e.g. reverse osmosis, dialysis, pervaporation or perstraction.
Abstract: The present invention is directed to non-porous isocyanurate-crosslinked polyurethane membranes. These membranes are useful for the separation of aromatic hydrocarbons from non-aromatic hydrocarbons. The separation can be performed using any commonly accepted membrane separation technique, e.g. reverse osmosis, dialysis, pervaporation or perstraction but is preferably performed under pervaporation or perstraction conditions.

51 citations


Journal ArticleDOI
TL;DR: In this paper, the surface force-pore flow (SF-PF) model has been modified and extended to describe and predict the performance of reverse osmosis type membranes, which is based on the same physical precepts.

44 citations


Patent
13 Dec 1989
TL;DR: In this article, a reverse osmosis membrane is prepared by treating a crosslinked, polyamide discriminating layer with an amine-reactive reagent or compatible oxidant at conditions whereby the passage of the selected solute at a selected transmembrane pressure is reduced by at least 30 percent.
Abstract: A method of separating water of reduced concentration of a selected solute via reverse osmosis, wherein the selected solute is sulfuric acid, sodium hydroxide, isopropanol, sodium nitrate or another solute having a much higher solute passage than sodium chloride. The reverse osmosis membrane is prepared by treating a crosslinked, polyamide discriminating layer with an amine-reactive reagent or compatible oxidant at conditions whereby the passage of the selected solute at a selected transmembrane pressure is reduced by at least 30 percent.

44 citations


Patent
10 Mar 1989
TL;DR: A self-filling bottled-water cooler dispenses pure water from a transparent water bottle mounted on the top of a free-standing cabinet body as mentioned in this paper, which attaches to a tap-water or other continuous water source.
Abstract: A self-filling bottled-water cooler dispenses pure water from a transparent water bottle mounted on the top of a free-standing cabinet body. The cooler attaches to a tap-water or other continuous water source and provides a continuous supply of pure water without need to change the water bottle The free-standing cabinet body includes a water tank located within the upper portion of the cabinet body and at least one tap for dispensing water from the water tank. The water bottle is securely attached on the top of the cabinet body to the water tank such that water freely flows between the bottle and the tank. Water from the tap water or other source is purified in a reverse osmosis, carbon block or other water purifier and is routed to the water tank. An inlet valve connected to a float mechanism within the water bottle regulates the flow of purified water into the water tank. The fload mechanism closes the inlet valve only when the purified water in the water bottle is at or above a desired full level. A venting system prevents overfilling of the water bottle and a change in air pressure within the bottle whenever the level of purified water in the bottle changes.

Patent
24 Jan 1989
TL;DR: In this paper, the method of preparing dried asymmetric cellulose acetate blend membranes through the use of at least one drying agent which is a hydrophobic organic compound, such as polysiloxanes, hydrocarbons, ethers, ketones, chlorohydrocarbons or nitro-hydro-carbons was described.
Abstract: The method of preparing dried asymmetric cellulose acetate blend membranes through the use of at least one drying agent which is a hydrophobic organic compound, such as polysiloxanes, hydrocarbons, ethers, ketones, chlorohydrocarbons or nitrohydrocarbons. The membranes are dried from their aqueous state by direct evaporation of water. The resulting air dried membranes are suitable for the desalination of water by reverse osmosis, non-­aqueous liquid separation, ultrafiltration, pervaporation, and for the separation of various gaseous mixtures into their constituent parts.

Patent
11 May 1989
TL;DR: In this article, a reverse osmosis system with an inlet port coupled to a source of feed water under predetermined pressure via a feed water inlet conduit, a product water outlet port for filtered outlet product water, and a brine outletport for brine.
Abstract: A reverse osmosis system including a reverse osmosis filter with a reverse osmosis membrane and having an inlet port coupled to a source of feed water under predetermined pressure via a feed water inlet conduit, a product water outlet port for filtered outlet product water, and a brine outlet port for brine. A pump coupled into the feed water inlet conduit between the source of feed water and the inlet port of the filter and driven by the feed water under pressure. The pump increases the pressure of the feed water so that the reverse osmosis filter receives feed water at an increased pressure.

Journal ArticleDOI
TL;DR: The softening properties of the Desal-5 membrane along with calculations illustrating how softening efficiency may be estimated for specific feed streams are discussed in this article, where the softening property of the membrane is discussed.

Journal ArticleDOI
TL;DR: In this paper, the potential use of reverse osmosis (RO) for the regeneration of ethanol from ethanol-rich miscellas by conventional evaporation is costly, due to the high latent heat of ethanol.
Abstract: Residual free gossypol in hexane-extracted cottonseed meal is a frequent concern of the feed industry. It is known that ethanol can efficiently extract the gossypol from cottonseed. However, regeneration of ethanol from ethanol-rich miscellas by conventional evaporation is costly, due to the high latent heat of ethanol. As an alternative to the evaporative regeneration, reverse osmosis (RO) has been investigated. It was found that commercially available RO membranes which have pore diameter around 20 A‡ (evaluated with deionized water flux) or less perform the necessary partitioning. Among the commercially available RO membranes, cellulose acetate (CA) type membranes with a nominal MWCO (molecular weight cutoff) value between 500 and 1000 were found to be efficient in partitioning the cottonseed triglycerides from the base solvent, but were not chemically compatible with the base solvent. RO membranes made from aromatic polyamide (PA) with MWCO value 1000 were found to have both the chemical stability and the necessary pore characteristics. Experimental results indicated the potential use of RO membranes for the regeneration of ethanol from ethanol miscellas. The required membrane pore characteristics and applicable permeate flux equations are discussed.

Patent
10 Oct 1989
TL;DR: A reverse osmosis filtration device which comprises a flexible elongated membrane bladder spirally wrapped around a purified water duct in a series of spaced-apart coils supported about their edges by perforated spacers is described in this article.
Abstract: A reverse osmosis filtration device which comprises a flexible elongated membrane bladder spirally wrapped around a purified water duct in a series of spaced-apart coils supported about their edges by perforated spacers. The device is installed in a water supply conduit to extract a volume of purified water under typical household line pressure while allowing the brine-carrying feed water for other normal household usage such as clothes and dishwashing, toilet flushing, showering and bathing.

Patent
Vic E. Lewis1
18 Dec 1989
TL;DR: An improved deionized water treatment system and method that consists of using a first and second water treatment train wherein the second train improves water quality by reducing particulate and total organic carbon by means of a reverse osmosis membrane assembly as mentioned in this paper.
Abstract: An improved deionized water treatment system and method that consists of using a first and second water treatment train wherein the second train improves water quality by reducing particulate and total organic carbon by means of a reverse osmosis membrane assembly. The final pure water having particulate sizes less than one micron and a total organic carbon measure of less than one part per billion.

Patent
20 Jul 1989
TL;DR: Simultaneous double reverse osmosis process for production of low and non-alcoholic beverages, particularly wines, from any traditionally fermented table wine feedstock was proposed in this article.
Abstract: Simultaneous double reverse osmosis process for production of low and non-alcoholic beverages, particularly wines, from any traditionally fermented table wine feedstock. A portion of the feed wine is subjected to remove alcohol and water as a permeate, with recycle of the concentrated retentate, while simultaneously a volume-balanced amount of reverse osmosis water is input back into the feed tank to maintain the in process wine at the initial level of the feedstock wine. The process may be run batch-wise, alternately, or in a modified semi-continuous operation to produce non-alcoholic wines (wines having residual alcohol content of less than 0.01% by volume) low alcohol wires (less than 0.5 volume percent alcohol), or wines having reduced alcohol content (less than 11-13 volume percent). The process also overcomes the 5% alcohol barrier problem of conventional reverse osmosis. The resulting finished wine has flavor, aroma and color solids concentrations of a level acceptable in good commercial practice. Actual non-alcoholic wine produced by the process has won a gold medal in a blind professional taste test.

Patent
13 Oct 1989
TL;DR: In this article, a dual-stage reverse osmosis water purification system is described, which includes a first stage having a filter medium for removing selected contaminants from incoming feed water, and a second stage including a reverse Osmosis membrane for converting a portion of the filtered feed water to a relatively purified water supply.
Abstract: A dual stage filter cartridge is provided for use in a reverse osmosis water purification system or the like. The filter cartridge includes a first stage having a filter medium for removing selected contaminants from incoming feed water, and a second stage including a reverse osmosis membrane for converting a portion of the filtered feed water to a relatively purified water supply. The filter media in the first state is particularly selected to remove contaminants which are otherwise potentially harmful to the reverse osmosis membrane. The dual stage cartridge is configured as a single unit adapted for simple drop-in installation into an open-ended cartridge housing.

Journal ArticleDOI
TL;DR: In this article, the reverse osmosis membrane separation process was applied to treat uranium conversion process effluent, and the results showed that the most important factor is the feed pH value.

Journal ArticleDOI
TL;DR: In this paper, the authors discuss issues such as when to clean, how to select a chemical treatment and how to evaluate the success of the cleaning procedure, and operating histories of several RO systems are discussed to illustrate these concepts.

Journal Article
TL;DR: There are two types of membrane technologies, nanofiltration and electrodialysis, which are well-known in the U.S. as discussed by the authors and are used for desalination in a growing number of applications.
Abstract: Membrane technology, using reverse osmosis to treat drinking water, is a promising alternative to conventional treatment. The method is now being used for desalination in a growing number of U.S. applications, including the world's largest desalination plant that recently went on line in Yuma, Arizona. Other well-established membrane methods are nanofiltration and electrodialysis, although these techniques are just beginning to be used in the U.S. Ultrafiltration is another membrane technology that is just emerging. All are described, along with their appropriate applications for treating drinking water. There are also different types of membranes; their characteristics, such as molecular weight cutoffs, are defined. Advantages are listed, principal among them that fewer chemicals are needed. The method generates less sludge, reducing disposal problems. They also offer potential for reducing treatment plant size and thus cutting costs. A major drawback is that membranes can become fouled with materials such as iron manganese, clay, and other organic substances that physically plug the surfaces, reducing efficiency. Nonetheless, costs are becoming competitive with conventional methods and much research is now being conducted that will make membrane technology even more attractive.

Patent
06 May 1989
TL;DR: In this article, a supply of less than ideal quality is delivered to a purifier holding one or more semi-permeable membranes, which with suitable differential pressure pass through the purifier and produce pure drinking water.
Abstract: A supply of water of less than ideal quality is delivered to a purifier (5) holding one or more semi-permeable membranes (6) which with suitable differential pressure pass through the purifier a supply of pure drinking water. Additives such as flavour enhancing CO2 are electronically controlled. Water travelling past, but not through, the membranes is used for domestic purposes such as baths, toilet flushing etc. The purified water is delivered to a storage cotnainer, e.g. an expandible flexible bag (18) inside a rigid casing. If not used in a set period, e.g. 3 days, this stored water is returned to the domestic usage distributor. If the storage cotnainer is full, a counter-pressure is applied near the membrane to halt reverse osmosis and further pure water prodn. USE - Produces pure water, largely free of bacteria, at low cost.


Journal ArticleDOI
TL;DR: In this paper, the authors present an exam de l'utilisation des techniques de dessalement pour approvisionner en eau potable les municipalites, in order to evaluate their effectiveness.
Abstract: Examen de l'utilisation des techniques de dessalement pour approvisionner en eau potable les municipalites

Patent
17 Aug 1989
TL;DR: In this paper, a water filtering canister unit having self-contained reverse osmosis and activated carbon filtering systems which are adapted for connection onto the water tap in a home, apartment or office is described.
Abstract: A water filtering canister unit having self-contained reverse osmosis and activated carbon filtering systems which are adapted for connection onto the water tap in a home, apartment or office. The canister unit includes a housing defining an inner chamber in which a cylindrical reverse osmosis membrane is mounted. Water molecules which pass through the membrane continue through a capsule containing a body of activated carbon particles and thence outwardly through a discharge conduit. Dissolved salts and minerals as well as particulate matter rejected by the membrane are discharged in brine water at a controlled rate through a lower end cap on the housing.

Patent
09 May 1989
TL;DR: In this paper, a surface-hydrophilic, highly selective semipermeable membrane with a hydrophilic segment having at least one end directly bonded to the surface of the membrane is described.
Abstract: A surface-hydrophilic, highly selective semipermeable membrane comprising a semipermeable membrane of a hydrophobic polymer and a hydrophilic segment having at least one end directly bonded to at least one surface of the semipermeable membrane is disclosed. The hydrophilic segment comprises at least one methylene group or substituted methylene group which is positioned at least at one end of the segment and at least one neutral hydroxyl group. The surface-hydrophilic, highly selective semipermeable membrane not only has excellent resistance to heat and organic solvents, but also non-adsorptivity for organic substances including even ionic organic substances. Therefore, the surface-hydrophilic, highly selective semipermeable membrane of the present invention can advantageously be used for microfiltration, ultrafiltration, reverse osmosis and dialysis.

Proceedings ArticleDOI
01 Jul 1989
TL;DR: In this article, the results from tests to evaluate a microgravity whole body shower and waste water recovery system design for possible use on the Space Station were presented from tests from tests.
Abstract: Results are presented from tests to evaluate a microgravity whole body shower and waste water recovery system design for possible use on the Space Station. Several water recovery methods were tested, including phase change distillation, a thermoelectric hollow fiber membrane evaporation subsystem, and a reverse osmosis dynamic membrane system. Consideration is given to the test hardware, the types of soaps evaluated, the human response to showering with reclaimed water, chemical treatment for microbial control, the procedures for providing hygienic water, and the quality of water produced by the systems. All three of the waste water recovery systems tested successfully produced reclaimed water for reuse.

Patent
05 Jun 1989
TL;DR: In this paper, a reverse osmosis membrane is manufactured by casting a polysulfone casting composition comprising an aromatic poly sulfone derivative having repeat units, at least an average of about 20% of which are carboxylated.
Abstract: Reverse osmosis membranes are manufactured by casting a polysulfone casting composition comprising: (i) an aromatic polysulfone derivative having repeat units, at least an average of about 20% of which are carboxylated and are of the formula I: ##STR1## , wherein each R in each formula is ortho to the sulfone, at least one R in each formula is a carboxyl group with any remainder thereof being hydrogen, and (ii) a solvent for the aromatic polysulfone derivative, then evaporating solvent from the casting composition and then gelling the casting composition into a reverse osmosis membrane. The permeability of the reverse osmosis membrane may be increased by the addition of a non-solvent for the aromatic polysulfone derivative to the casting composition.

Journal ArticleDOI
TL;DR: In this article, a mathematical model was proposed and solved, which can predict the permeate flux, as well as the mass of deposits on the membrane as a function of time, based on the following assumptions: (1) the rate of deposition is proportional to the deviations from equilibrium conditions.