Structure and nanostructure in ionic liquids.

This review gives a survey on the latest most representative developments and progress concerning ionic liquids, from their fundamental properties to their applications in catalytic processes. It also highlights their emerging use for biomass treatment and transformation.

Ionic liquids and catalysis: Recent progress from knowledge to applications

Preface 1.General Considerations 2.Basic Processes in Atomization 3.Drop Size Distributions of Sprays 4.Atomizers 5.Flow in Atomizers 6.Atomizer Performance 7.External Spray Charcteristics 8.Drop Evaporation 9.Drop Sizing Methods Index

Atomization and Sprays

The first part of this two-part review focused on the fundamental and diagnostics aspects of laser-induced plasmas, only touching briefly upon concepts such as sensitivity and detection limits and largely omitting any discussion of the vast panorama of the practical applications of the technique. Clearly a true LIBS community has emerged, which promises to quicken the pace of LIBS developments, applications, and implementations. With this second part, a more applied flavor is taken, and its intended goal is summarizing the current state-of-the-art of analytical LIBS, providing a contemporary snapshot of LIBS applications, and highlighting new directions in laser-induced breakdown spectroscopy, such as novel approaches, instrumental developments, and advanced use of chemometric tools. More specifically, we discuss instrumental and analytical approaches (e.g., double- and multi-pulse LIBS to improve the sensitivity), calibration-free approaches, hyphenated approaches in which techniques such as Raman and fluorescence are coupled with LIBS to increase sensitivity and information power, resonantly enhanced LIBS approaches, signal processing and optimization (e.g., signal-to-noise analysis), and finally applications. An attempt is made to provide an updated view of the role played by LIBS in the various fields, with emphasis on applications considered to be unique. We finally try to assess where LIBS is going as an analytical field, where in our opinion it should go, and what should still be done for consolidating the technique as a mature method of chemical analysis.

https://journals.sagepub.com/doi/pdf/10.1366/11-06574

Laser-induced breakdown spectroscopy (LIBS), part II: review of instrumental and methodological approaches to material analysis and applications to different fields.

Until recently, “room-temperature” (<100–150 °C) liquid-state electrochemistry was mostly electrochemistry of diluted electrolytes(1)–(4) where dissolved salt ions were surrounded by a considerable amount of solvent molecules. Highly concentrated liquid electrolytes were mostly considered in the narrow (albeit important) niche of high-temperature electrochemistry of molten inorganic salts(5-9) and in the even narrower niche of “first-generation” room temperature ionic liquids, RTILs (such as chloro-aluminates and alkylammonium nitrates).(10-14) The situation has changed dramatically in the 2000s after the discovery of new moisture- and temperature-stable RTILs.(15, 16) These days, the “later generation” RTILs attracted wide attention within the electrochemical community.(17-31) Indeed, RTILs, as a class of compounds, possess a unique combination of properties (high charge density, electrochemical stability, low/negligible volatility, tunable polarity, etc.) that make them very attractive substances from fundamental and application points of view.(32-38) Most importantly, they can mix with each other in “cocktails” of one’s choice to acquire the desired properties (e.g., wider temperature range of the liquid phase(39, 40)) and can serve as almost “universal” solvents.(37, 41, 42) It is worth noting here one of the advantages of RTILs as compared to their high-temperature molten salt (HTMS)(43) “sister-systems”.(44) In RTILs the dissolved molecules are not imbedded in a harsh high temperature environment which could be destructive for many classes of fragile (organic) molecules.

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Ionic Liquids at Electrified Interfaces

Electric field control of combustion offers the potential of stabilizing flames and reducing emissions with comparatively little effort. Previous investigations of the effects of electric fields on flames were restricted to atmospheric pressure and the question whether field effects persist at higher pressures remained open. In the present work effects of electric fields on flame behavior are established for pressures up to 10 bar without any indication that this should be an upper limit. Voltage-current measurements and optical emission spectroscopy gave clear evidence that at all experimental conditions under investigation electric field induced ionization and dissociation reactions were negligible with regard to the combustion process. Thus it is concluded that all observed effects are due to electro-hydrodynamic distortions of the gas flow caused by electrostatic forces acting on the ions generated in the reaction zones of the flames. The concentration of pollutants such as CO, NO and NO2 in the presence of an electric field depends on the ratio U/p of electrode voltage U and pressure p which implies that the electric field strength required to obtain a given effect increases linearly with pressure. In an electric field directed towards the burner CO emissions could be reduced by about 90%, irrespective of pressure. The decrease of CO was accompanied by an increase of NOx by about 20%. The electric power required for a CO reduction of 90% amounted to 0.1% of the thermal power. The improvement of the lean blow-off limit upon application of an electric field observed so far ranges from 1 to 3% and increases with pressure.Copyright © 2005 by ASME

Electro-Hydrodynamic Control of Premixed Turbulent Methane Flames at Pressures Above 1 ATM

A SIGNAL ENHANCED PORTABLE RAMAN PROBE FOR ANESTHETIC GAS MONITORING S. Schlüter, S. Asbach, N. Popovska-Leipertz, Th. Seeger, A. Leipertz a Institute of Engineering Thermodynamics, University of Erlangen-Nuremberg, Erlangen, 91058, Germany b Erlangen Graduate School in Advanced Optical Technologies (SAOT), University of Erlangen-Nuremberg, Erlangen, 91052, Germany с Institute of Engineering Thermodynamics, University of Siegen, Siegen, 57076, Germany d ESYTEC Energieund Systemtechnik GmbH, Erlangen, 91058, Germany Corresponding author: Sebastian.schlueter@uni-siegen.de Article info Received 23.01.15, accepted 25.02. 15 doi: 10.17586/2226-1494-2015-15-2-218-226 Article in English For citation: Schlüter S., Asbach S., Popovska-Leipertz N., Seeger Th., Leipertz A. A signal enhanced portable raman probe for anesthetic gas monitoring. Scientific and Technical Journal of Information Technologies, Mechanics and Optics, 2015, vol.15, no. 2, pp. 218–226. (in English) Abstract. The spontaneous Raman scattering technique is an excellent tool for a quantitative analysis of multi-species gas mixtures. It is a noninvasive optical method for species identification and gas phase concentration measurement of all Raman active molecules, since the intensity of the species specific Raman signal is linearly dependent on the concentration. Applying a continuous wave (CW) laser it typically takes a few seconds to capture a gas phase Raman spectrum at room temperature. Nevertheless in contrast to these advantages the weak Raman signal intensity is a major drawback. Thus, it is still challenging to detect gas phase Raman spectra in alow-pressure regime with a temporal resolution of only a few 100 ms. In this work a fully functional gas phase Raman system for measurements in the low-pressure regime (p ≥ 980 hPa (absolute)) is presented. It overcomes the drawback of a weak Raman signal by using a multipass cavity. A description of the sensor setup and of the multipass arrangement will be presented. Moreover the complete functionality of the sensor system will be demonstrated by measurements at an anesthesia simulator under clinical relevant conditions and in comparison to a conventional gas monitor.

/pdf/a-signal-enhanced-portable-raman-probe-for-anesthetic-gas-5dw9s51iic.pdf

A signal enhanced portable Raman probe for anesthetic gas monitoring

Monitoring of chemical reactors is key to optimizing yield and efficiency of chemical transformation processes. Aside from tracking pressure and temperature, the measurement of the chemical composition is essential in this context. We present an infrared difference spectroscopy approach for determining the reactant (cyclooctene) and product (cyclooctane) concentrations during a catalytic hydrogenation reaction in the solvent cyclohexane, which is present in large excess. Subtracting the spectrum of the pure solvent from the reactor mixture spectra yields infrared (IR) spectra, which can ultimately be evaluated using a curve-fitting procedure based on spectral soft modeling. An important feature of our evaluation approach is that the calibration only requires recording the pure component spectra of the reactants, products, and solvent. Hence, no time-consuming preparation of mixtures for calibration is necessary. The IR concentration results are in good agreement with gas chromatography measurements.

Attenuated total reflection infrared difference spectroscopy (ATR-IRDS) for quantitative reaction monitoring.

Stoffdaten des neuen Kältemittels R134a

This paper describes a computer simulation of diesel spray formation and the locations of self-ignition nuclei. The spray is divided into small elementary volumes, in which the amounts of fuel, fuel vapors, and air and mean, maximum, and minimum fuel droplet diameters are calculated, as well as their number. The total air/fuel and air/fuel-vapor ratios are calculated for each elementary volume. The paper introduces a new criterion for determining self-ignition nuclei based on assumptions that the strongest self-ignition probability lies in those elementary volumes containing the stoichiometric air ratio, where the fuel is evaporated or the fuel droplet diameter is equal to or lower than 0.0065 mm. The most efficient combustion with regard to consumption and emission will be in those elementary volumes containing the stoichiometric air ratio and fuel droplets with the lowest mean diameters. Measurements of injection and combustion were carried out in a transparent research engine. This engine is a single-c...

Alfred Leipertz

Papers

Electro-Hydrodynamic Control of Premixed Turbulent Methane Flames at Pressures Above 1 ATM

A signal enhanced portable Raman probe for anesthetic gas monitoring

Attenuated total reflection infrared difference spectroscopy (ATR-IRDS) for quantitative reaction monitoring.

Stoffdaten des neuen Kältemittels R134a

Calculation and Measurements of Self-Ignition Nuclei in Diesel Combustion