Anusha S. Basavaraj

Bio: Anusha S. Basavaraj is an academic researcher from Indian Institute of Technology Madras. The author has contributed to research in topics: Cement & Portland cement. The author has an hindex of 5, co-authored 8 publications receiving 124 citations.

Service life and life cycle assessment of reinforced concrete systems with limestone calcined clay cement (LC3)

Abstract: This paper presents data on the chloride diffusion coefficient (Dcl), ageing coefficient (m) and chloride threshold (Clth) related to seven concrete mixes (four M35 and three M50) with OPC, OPC + PFA (pulverised fuel ash) and limestone-calcined clay cement (LC3). Using these, the service lives of a typical bridge pier and girder with the PFA and LC3 concrete were found to be much higher than those with OPC concrete of similar strength. From life-cycle assessment, the CO2 footprint of PFA and LC3 concrete were found to be significantly lower than those of OPC concrete of similar strength. Further, the CO2 emissions per unit of concrete per year of estimated service life, as a combined indicator of service life and carbon footprint, are similar for concrete with PFA and LC3, which are much lower than that with OPC.

Sustainable materials for 3D concrete printing

Abstract: This paper explores the sustainability aspects of binders used in concrete 3D concrete printing. Firstly, a prospective approach to conduct sustainability-assessment based on the life cycle of 3D printed structures is presented, which also highlights the importance of considering the functional requirements of the mixes used for 3D printing. The potential of the material production phase is emphasized to enhance the sustainability potential of 3DCP by reducing the embodied impacts. The literature on the different binder systems used for producing 3D printable mixtures is reviewed. This review includes binders based on portland cement and supplementary cementing materials (SCMs) such as fly ash, silica-fume and slag. Also, alternative binders such as geopolymer, calcium sulfo-aluminate cement (CSA), limestone calcined clay cement (LC3) and reactive magnesium oxide systems are explored. Finally, sustainability assessment by quantifying the environmental impacts in terms of energy consumed and CO2 emissions of mixtures is illustrated with different binder systems. This paper underlines the effect of using SCMs and alternative binder systems for improving the sustainability of 3D printed structures.

Influence of supplementary cementitious materials on the sustainability parameters of cements and concretes in the Indian context

Abstract: The consumption of cement in India and other emerging economies is expected to increase because of the continuing push towards development of housing and infrastructure. The increasing production of cement and utilization of concrete are bound to have a major impact on sustainability. The present work proposes a framework for sustainability assessment, in terms of the CO2 emissions and energy demand, that can be adopted in cases where suitable databases are not readily available. Case studies for cement manufacture have been considered in South India, with different system boundaries such as ground-to-gate, gate-to-gate and CSI. The assessment made using data from the plant and other sources highlights the benefits of using supplementary cementitious materials (SCMs) in terms of reducing the impact of cement and concrete. More importantly, limestone calcined clay cement shows considerable promise in terms of reduction in CO2 emissions and energy demand in both cement and concrete, with more improvement in higher grade concrete.

Sustainability-based decision support framework for choosing concrete mixture proportions

Abstract: A framework is proposed, along with two objective indices, for the selection of concrete mixture proportions based on sustainability criteria. The indices combine energy demand and long-term strength as energy intensity, and carbon emissions and durability parameters as A-indices, which represent the apathy toward these essential features of sustainability. The decision support framework is demonstrated by considering a set of 30 concretes with different binders, including ordinary portland cement (OPC), fly ash, slag and limestone calcined clay cement (LC3). In addition to the experimental data on compressive strength, chloride diffusion and carbonation, life cycle assessment has been performed for the concretes considering typical situations in South India. The most sustainable of the concretes studied here, for service life limited by chloride ingress, are those with LC3, OPC replaced by 50% slag, and ternary blends with 20% each of slag and fly ash. In the case of applications where carbonation is critical, the appropriate concretes are those with OPC replaced by 15–30% slag or 15% fly ash, or with ternary blends having 20% slag and 20% Class F fly ash.

Durability, service life prediction, and modelling for reinforced concrete structures – review and critique

Abstract: Ever increasing attention is being paid to deterioration prediction and service life modelling of reinforced concrete structures. Research has progressed to a stage where service life models and design philosophies are, to varying degrees, included in some codes and standards, such as the fib Model Codes and ISO 13823. This has helped to base practical durability design on sound engineering approaches. This paper reviews service life modelling and prediction, and service life design, covering limit state design philosophies and deterioration models. An overview on recent developments, and a critical review on common assumptions in service life modelling and on the application and limitations of the various approaches, are presented. It is emphasised that design approaches and models need to be validated with field observations. It is argued that a performance-based approach is the most suitable engineering tool for durability design.

Service life and life cycle assessment of reinforced concrete systems with limestone calcined clay cement (LC3)

Abstract: This paper presents data on the chloride diffusion coefficient (Dcl), ageing coefficient (m) and chloride threshold (Clth) related to seven concrete mixes (four M35 and three M50) with OPC, OPC + PFA (pulverised fuel ash) and limestone-calcined clay cement (LC3). Using these, the service lives of a typical bridge pier and girder with the PFA and LC3 concrete were found to be much higher than those with OPC concrete of similar strength. From life-cycle assessment, the CO2 footprint of PFA and LC3 concrete were found to be significantly lower than those of OPC concrete of similar strength. Further, the CO2 emissions per unit of concrete per year of estimated service life, as a combined indicator of service life and carbon footprint, are similar for concrete with PFA and LC3, which are much lower than that with OPC.

Limestone calcined clay cement and concrete: A state-of-the-art review

Abstract: This article reviews the rapidly developing state-of-the-art literature available on the subject of the recently developed limestone calcined clay cement (LC3). An introduction to the background leading to the development of LC3 is first discussed. The chemistry of LC3 hydration and its production are detailed. The influence of the properties of the raw materials and production conditions are discussed. The mixture design of concrete using LC3 and the mechanical and durability properties of LC3 cement and concrete are then compared with other cements. At the end the economic and environmental aspects of the production and use of LC3 are discussed. The paper ends with suggestions on subjects on which further research is required.

Towards ternary binders involving limestone additions — A review

Abstract: The review summarises literature to examine the transition from portland limestone cement system to composite ternary binder systems involving limestone. Interest in limestone addition as an ideal component in multicomponent binder systems has surged as evident from the large volume of literature published in the recent past. A ternary blended system, with co-substitution of limestone, has the potential to complement the reaction of the supplementary cementitious materials (SCMs). The direct addition of limestone powder helps to attain higher substitution levels of portland cement clinker, improve early age properties, and supplement SCM's reactivity. However, the dilution of hydrates could hamper the long-term benefits. In this review, the interaction of fine limestone is classified and elaborated under two broad umbrellas: physical and chemical interactions. The physical interactions can manifest in three ways, namely, filler action, shearing action and improved packing, which alters reaction rate and extent at early ages. The chemical interactions also modify the reaction kinetics and phase assemblage due to nucleation of C-S-H on calcite surfaces, preservation of the ettringite phase and formation of carboaluminates. Two different forms of carboaluminate hydrates — hemicarboaluminate and mono-carboaluminate can be present in the hydrate matrix depending on the balance between carbonate ions and aluminates in the pore solution. Several factors such as replacement level, particle size, choice of SCM, its reactivity and reactive aluminates content, sulphate levels, curing temperature, and duration of curing can control the carboaluminate formation, reaction degree of SCMs and chemical interaction from limestone additions. A combination of physical and chemical effects makes fine limestone a potential material for co-substitution with aluminosilicate based SCMs, mainly fly ash, slag, and calcined clay. In this review, the factors affecting limestone-SCM composites are summarised based on a detailed literature survey. The effects of SCM-limestone cement composites on hydration kinetics, reaction chemistry, the reactivity of SCMs, the stability of hydrated phases, and contribution to the physical structure development and macroscopic properties by evaluating hydration and mechanical properties are discussed. The importance of AFm (Al2O3–Fe2O3-mono) phases in various deterioration mechanisms in concrete and their influence on performance characteristics in different exposure environment is critically appraised.

The effect of the steel–concrete interface on chloride-induced corrosion initiation in concrete: a critical review by RILEM TC 262-SCI

Abstract: The steel–concrete interface (SCI) is known to influence corrosion of steel in concrete. However, due to the numerous factors affecting the SCI—including steel properties, concrete properties, execution, and exposure conditions—it remains unclear which factors have the most dominant impact on the susceptibility of reinforced concrete to corrosion. In this literature review, prepared by members of RILEM technical committee 262-SCI, an attempt is made to elucidate the effect of numerous SCI characteristics on chloride-induced corrosion initiation of steel in concrete. We use a method to quantify and normalize the effect of individual SCI characteristics based on different literature results, which allows comparing them in a comprehensive context. It is found that the different SCI characteristics have received highly unbalanced research attention. Parameters such as w/b ratio and cement type have been studied most extensively. Interestingly, however, literature consistently indicates that those parameters have merely a moderate effect on the corrosion susceptibility of steel in concrete. Considerably more pronounced effects were identified for (1) steel properties, including metallurgy, presence of mill scale or rust layers, and surface roughness, and (2) the moisture state. Unfortunately, however, these aspects have received comparatively little research attention. Due to their apparently strong influence, future corrosion studies as well as developments towards predicting corrosion initiation in concrete would benefit from considering those aspects. Particularly the working mechanisms related to the moisture conditions in microscopic and macroscopic voids at the SCI is complex and presents major opportunities for further research in corrosion of steel in concrete.