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Daniel J. Martin
Researcher at Yale University
Publications - 23
Citations - 1244
Daniel J. Martin is an academic researcher from Yale University. The author has contributed to research in topics: Catalysis & Porphyrin. The author has an hindex of 13, co-authored 22 publications receiving 869 citations. Previous affiliations of Daniel J. Martin include University of North Carolina at Chapel Hill.
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Journal ArticleDOI
Oxygen Reduction by Homogeneous Molecular Catalysts and Electrocatalysts.
TL;DR: The thermochemistry of oxygen reduction and the factors influencing ORR efficiency are described to contextualize the discussion of catalytic studies that follows, and reports of ORR catalysis are presented in terms of their mechanism.
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Electrochemical Reduction of Brønsted Acids by Glassy Carbon in Acetonitrile—Implications for Electrocatalytic Hydrogen Evolution
TL;DR: Examination of acid electroreduction in acetonitrile on glassy carbon electrodes by cyclic voltammetry provides a guide for selecting acids to use in electrocatalysis experiments such that direct electrode reduction is avoided.
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Linear Free Energy Relationships in the Hydrogen Evolution Reaction: Kinetic Analysis of a Cobaloxime Catalyst
TL;DR: In this article, the mechanism of hydrogen evolution is governed by three elementary steps; two are acid concentration and pKa dependent, whereas the third is intrinsic to the catalyst, likely reflecting either H-H bond formation or H2 release.
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Mechanism of Catalytic O2 Reduction by Iron Tetraphenylporphyrin.
Michael L. Pegis,Daniel J. Martin,Catherine F. Wise,Anna C. Brezny,Samantha I. Johnson,Lewis E. Johnson,Neeraj Kumar,Simone Raugei,James M. Mayer +8 more
TL;DR: These results are the first example of oxygen reduction by iron tetraphenylporphyrin where the pre-equilibria among ferric, ferrous, and ferric-superoxide intermediates have been quantified under catalytic conditions.
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Rational Design of Mononuclear Iron Porphyrins for Facile and Selective 4e–/4H+ O2 Reduction: Activation of O–O Bond by 2nd Sphere Hydrogen Bonding
Sarmistha Bhunia,Atanu Rana,Pronay Roy,Daniel J. Martin,Michael L. Pegis,Michael L. Pegis,Bijan Roy,Abhishek Dey +7 more
TL;DR: A series of mononuclear iron porphyrin complexes are rationally designed to achieve efficient O-O bond activation and site-selective proton transfer to effect facile and selective electrochemical reduction of O2 to water with rate constants higher than all known heme/Cu complexes.