D
Daniel N. Huh
Researcher at University of California, Irvine
Publications - 24
Citations - 313
Daniel N. Huh is an academic researcher from University of California, Irvine. The author has contributed to research in topics: Cryptand & 2.2.2-Cryptand. The author has an hindex of 9, co-authored 22 publications receiving 179 citations. Previous affiliations of Daniel N. Huh include University of San Diego & Illinois State University.
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Journal ArticleDOI
Engineering electronic structure to prolong relaxation times in molecular qubits by minimising orbital angular momentum.
Ana-Maria Ariciu,David H. Woen,Daniel N. Huh,Lydia E. Nodaraki,Andreas K. Kostopoulos,Conrad A. P. Goodwin,Nicholas F. Chilton,Eric J. L. McInnes,Richard E. P. Winpenny,William J. Evans,Floriana Tuna +10 more
TL;DR: The authors engineer the electronic configurations of the metal centres in a series of divalent rare-earth complexes and succeed in prolonging their phase memory times.
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Chelate-Free Synthesis of the U(II) Complex, [(C5H3(SiMe3)2)3U]1–, Using Li and Cs Reductants and Comparative Studies of La(II) and Ce(II) Analogs
TL;DR: To expand the range of synthetic options for generating complexes of the actinide metals in the +2 oxidation state, reduction of Cp″3U (Cp″ = C5H3(SiMe3)2) and the lanthanide analogs and the Lanthanides with lithium in the absence of crown ether and cryptand chelates was explored.
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Isolation of a Square-Planar Th(III) Complex: Synthesis and Structure of [Th(OC6H2tBu2-2,6-Me-4)4]1.
TL;DR: DFT calculations yield a C4-symmetric structure which accommodates a low-lying SOMO of 6dz2 character with 7s Rydberg admixture and an axial signal consistent with a metal-based radical in a planar complex is revealed.
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Reactivity of Ln(II) Complexes Supported by (C5H4Me)1– Ligands with THF and PhSiH3: Isolation of Ring-Opened, Bridging Alkoxyalkyl, Hydride, and Silyl Products
TL;DR: Reduction of CpMe3Ln(THF) with KC8 in the presence of 222-crypt and (crypt) generates dark solutions, 2-Ln, with EPR spectra consistent with Ln(II) complexes as mentioned in this paper.
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Synthesis of rare-earth-metal-in-cryptand dications, [Ln(2.2.2-cryptand)]2+, from Sm2+, Eu2+, and Yb2+ silyl metallocenes (C5H4SiMe3)2Ln(THF)2.
Daniel N. Huh,Christopher M. Kotyk,Milan Gembicky,Arnold L. Rheingold,Joseph W. Ziller,William J. Evans +5 more
TL;DR: A bimetallic, mixed-ligand metallocene/opened-crypt complex of Sm2+, [Sm(C16H32N2O6-κ2O:κ2 O')SmCp,''2], was obtained by KC8 reduction of Cp''2Sm(THF) [Cp'' = C5H3(SiMe3)2] in the presence of crypt.