F
Fernando Avecilla
Researcher at University of A Coruña
Publications - 155
Citations - 4142
Fernando Avecilla is an academic researcher from University of A Coruña. The author has contributed to research in topics: Catalysis & Schiff base. The author has an hindex of 35, co-authored 140 publications receiving 3553 citations. Previous affiliations of Fernando Avecilla include University of Valencia & Jamia Millia Islamia.
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Synthesis, characterization, and application of vanadium-salan complexes in oxygen transfer reactions.
Pedro Adão,João Costa Pessoa,Rui T. Henriques,Maxim L. Kuznetsov,Fernando Avecilla,Mannar R. Maurya,Umesh Kumar,Isabel Correia +7 more
TL;DR: The V-Salen and V-salan complexes show higher activity and normally better selectivity in alkene oxidation and higherActivity and enantioselectivity for sulfoxidation than their parent V- salen complexes, therefore being an advantageous alternative ligand system for oxidation catalysis.
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N,N'-Ethylenebis(pyridoxylideneiminato) and N,N'-Ethylenebis(pyridoxylaminato): Synthesis, Characterization, Potentiometric, Spectroscopic, and DFT Studies of Their Vanadium(IV) and Vanadium(V) Complexes
Isabel Correia,Joāo Costa Pessoa,M. Teresa Duarte,Rui Henriques,M. Fátima M. Piedade,Luis F. Veiros,Tamás Jakusch,Tamás Kiss,Tamás Kiss,Ágnes Dörnyei,M. Margarida C. A. Castro,Carlos F. G. C. Geraldes,Fernando Avecilla +12 more
TL;DR: The DFT calculations indicate that for almost all complexes the presence of a sixth equatorial or axial H(2)O ligand leads to much more stable compounds.
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Hydroxyquinoline derived vanadium(IV and V) and copper(II) complexes as potential anti-tuberculosis and anti-tumor agents.
Isabel Correia,Pedro Adão,Somnath C. Roy,Mohamed Wahba,Cristina P. Matos,Mannar R. Maurya,Fernanda Marques,Fernando Rogério Pavan,Clarice Queico Fujimura Leite,Fernando Avecilla,João Costa Pessoa +10 more
TL;DR: In the non-tumorigenic HEK cells poor selectivity toward cancer cells for most of the complexes was observed, as well as for cisplatin, while almost all tested vanadium complexes were very active against Mtb and theMICs were comparable to, or better than, the MICs of drugs, such as streptomycin.
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Polymer-Bound Oxidovanadium(IV) and Dioxidovanadium(V) Complexes As Catalysts for the Oxidative Desulfurization of Model Fuel Diesel
Mannar R. Maurya,Aarti Arya,Amit Kumar,Maxim L. Kuznetsov,Fernando Avecilla,João Costa Pessoa +5 more
TL;DR: The (51)V NMR spectra recorded for solutions in methanol confirm that complex 4, on treatment with H(2)O(2), is able to generate peroxo-vanadium(V) complexes, including quite stable protonated peroxO-V(V), and an outline of the mechanism is proposed.
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Vanadium(IV and V) Complexes of Schiff Bases and Reduced Schiff Bases Derived from the Reaction of Aromatic o-Hydroxyaldehydes and Diamines: Synthesis, Characterisation and Solution Studies
Isabel Correia,João Costa Pessoa,M. Teresa Duarte,M. Fátima M. Piedade,Tamás Jackush,Tamás Kiss,M. Margarida C. A. Castro,Carlos F. G. C. Geraldes,Fernando Avecilla +8 more
TL;DR: Several sal 2 en-type reduced Schiff bases have been prepared from the reaction of 2 equiv. of salicylaldehyde derivatives with ethylenediamine followed by reduction with NaBH 4 and subsequently characterised by X-ray diffraction as mentioned in this paper.