F
Fumitoshi Kakiuchi
Researcher at Keio University
Publications - 235
Citations - 12426
Fumitoshi Kakiuchi is an academic researcher from Keio University. The author has contributed to research in topics: Catalysis & Ruthenium. The author has an hindex of 56, co-authored 230 publications receiving 11505 citations. Previous affiliations of Fumitoshi Kakiuchi include National Presto Industries & Kagawa University.
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Journal ArticleDOI
Efficient catalytic addition of aromatic carbon-hydrogen bonds to olefins
Shinji Murai,Fumitoshi Kakiuchi,S. Sekine,Yasuo Tanaka,Asayuki Kamatani,Motohiro Sonoda,Naoto Chatani +6 more
TL;DR: The selective cleavage of carbon-hydrogen bonds in organic compounds is a critical step in many organic syntheses, and is particularly important in the conversion of hydrocarbons to useful organic compounds.
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Catalytic C−H/Olefin Coupling
Fumitoshi Kakiuchi,Shinji Murai +1 more
TL;DR: In this paper, the cleavage and addition of ortho C−H bonds in various aromatic compounds such as ketones, esters, imines, imidates, nitrile, and aldehydes to olefins and acetlylenes can be achieved with the aid of ruthenium catalysts.
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Catalytic Methods for C ? H Bond Functionalization: Application in Organic Synthesis
Fumitoshi Kakiuchi,Naoto Chatani +1 more
TL;DR: In this paper, a review of the results of these research activities with respect to the catalytic use of unreactive CH bonds in organic synthesis can be found, as well as a survey of catalytic reactions involving carbon-hydrogen bond cleavage.
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Transition-Metal-CatalyzedCarbon-Carbon Bond Formation via Carbon-HydrogenBond Cleavage
Fumitoshi Kakiuchi,Takuya Kochi +1 more
TL;DR: A review of catalytic reactions involving C-Hbond cleavage can be found in this article, where the authors briefly survey the reported research with respect to efficient and selective transition-metal-catalyzed C-C bond formation via CH bond cleavage.
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A Ruthenium-Catalyzed Reaction of Aromatic Ketones with Arylboronates: A New Method for the Arylation of Aromatic Compounds via C−H Bond Cleavage
TL;DR: The ruthenium-catalyzed reaction of aromatic ketones with arylboronic acid esters (arylboronates) gave the ortho arylation product and a RuH2(CO)(PPh3)3 complex exhibited the highest catalytic activity among the complexes screened.