A number of materials have been explored for their use as artificial muscles Among these, dielectric elastomers (DEs) appear to provide the best combination of properties for true muscle-like actuation DEs behave as compliant capacitors, expanding in area and shrinking in thickness when a voltage is applied Materials combining very high energy densities, strains, and efficiencies have been known for some time To date, however, the widespread adoption of DEs has been hindered by premature breakdown and the requirement for high voltages and bulky support frames Recent advances seem poised to remove these restrictions and allow for the production of highly reliable, high-performance transducers for artificial muscle applications

Advances in dielectric elastomers for actuators and artificial muscles.

The investigation of the conversion of vibrational energy into electrical power has become a major field of research. In recent years, bistable energy harvesting devices have attracted significant attention due to some of their unique features. Through a snap-through action, bistable systems transition from one stable state to the other, which could cause large amplitude motion and dramatically increase power generation. Due to their nonlinear characteristics, such devices may be effective across a broad-frequency bandwidth. Consequently, a rapid engagement of research has been undertaken to understand bistable electromechanical dynamics and to utilize the insight for the development of improved designs. This paper reviews, consolidates, and reports on the major efforts and findings documented in the literature. A common analytical framework for bistable electromechanical dynamics is presented, the principal results are provided, the wide variety of bistable energy harvesters are described, and some remaining challenges and proposed solutions are summarized.

https://iopscience.iop.org/article/10.1088/0964-1726/22/2/023001/pdf

A review of the recent research on vibration energy harvesting via bistable systems

A magnetically, electrically or mechanically responsive material can undergo significant thermal changes near a ferroic phase transition when its order parameter is modified by the conjugate applied field. The resulting magnetocaloric, electrocaloric and mechanocaloric (elastocaloric or barocaloric) effects are compared here in terms of history, experimental method, performance and prospective cooling applications.

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Caloric materials near ferroic phase transitions

An insight into the analogies, state-of-the-art technologies, concepts, and prospects under the umbrella of perovskite materials (both inorganic-organic hybrid halide perovskites and ferroelectric perovskites) for future multifunctional energy conversion and storage devices is provided. Often, these are considered entirely different branches of research; however, considering them simultaneously and holistically can provide several new opportunities. Recent advancements have highlighted the potential of hybrid perovskites for high-efficiency solar cells. The intrinsic polar properties of these materials, including the potential for ferroelectricity, provide additional possibilities for simultaneously exploiting several energy conversion mechanisms such as the piezoelectric, pyroelectric, and thermoelectric effect and electrical energy storage. The presence of these phenomena can support the performance of perovskite solar cells. The energy conversion using these effects (piezo-, pyro-, and thermoelectric effect) can also be enhanced by a change in the light intensity. Thus, there lies a range of possibilities for tuning the structural, electronic, optical, and magnetic properties of perovskites to simultaneously harvest energy using more than one mechanism to realize an improved efficiency. This requires a basic understanding of concepts, mechanisms, corresponding material properties, and the underlying physics involved with these effects.

Mutual Insight on Ferroelectrics and Hybrid Halide Perovskites: A Platform for Future Multifunctional Energy Conversion.

This paper reviews energy harvesting technology from mechanical vibration. Recent advances on ultralow power portable electronic devices and wireless sensor network require limitless battery life for better performance. People searched for permanent portable power sources for advanced electronic devices. Energy is everywhere around us and the most important part in energy harvesting is energy transducer. Piezoelectric materials have high energy conversion ability from mechanical vibration. A great amount of researches have been conducted to develop simple and efficient energy harvesting devices from vibration by using piezoelectric materials. Representative piezoelectric materials can be categorized into piezoceramics and piezopolymers. This paper reviews key ideas and performances of the reported piezoelectric energy harvesting from vibration. Various types of vibration devices, piezoelectric materials and mathematical modeling of vibrational energy harvestings are reviewed.

A Review of Piezoelectric Energy Harvesting Based on Vibration

This paper deals with small-power energy harvesting from heat. It can be achieved using both thermoelectric and pyroelectric effects. In the first case, temperature gradients are necessary. The main difficulty of thermoelectric energy harvesting is imposing a large temperature gradient. This requires huge heat flows because of the limited surface heat exchanges and the large heat conductivity of thermoelectric materials. This results in a drastic decrease of power and the efficiency of conversion. In case of pyroelectric energy harvesting, a time varying temperature is necessary. Although such a temperature time profile is hard to find, the overall optimization is easier than the thermoelectric strategy. Indeed, it depends much less on heat exchange between the sample and the outer medium, than on heat capacity that dimensions optimization may easily compensate. As a consequence, it is shown that the efficiency and output power may be much larger using pyroelectric energy harvesting than thermoelectric methods. For instance, using a limited temperature gradient due to the limited heat exchange, a maximum efficiency of 1.7% of Carnot efficiency can be expected using a thermoelectric module. On the contrary, a pyroelectric device may reach an efficiency up to 50% of Carnot efficiency. Finally, an illustration shows an estimation of the output power that could be expected from natural time variations of temperature of a wearable device. Power peaks up to 0. 2m W cm −3 were found and a mean power of 1 μ Wc m −3 on average was determined within 24 h testing.

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On thermoelectric and pyroelectric energy harvesting

In the framework of microgenerators, we present in this paper the key points for energy harvesting from temperature using ferroelectric materials. Thermoelectric devices profit from temperature spatial gradients, whereas ferroelectric materials require temporal fluctuation of temperature, thus leading to different applications targets. Ferroelectric materials may harvest perfectly the available thermal energy whatever the materials properties (limited by Carnot conversion efficiency) whereas thermoelectric material's efficiency is limited by materials properties (ZT figure of merit). However, it is shown that the necessary electric fields for Carnot cycles are far beyond the breakdown limit of bulk ferroelectric materials. Thin films may be an excellent solution for rising up to ultra-high electric fields and outstanding efficiency. Different thermodynamic cycles are presented in the paper: principles, advantages, and drawbacks. Using the Carnot cycle, the harvested energy would be independent of materials properties. However, using more realistic cycles, the energy conversion effectiveness remains dependent on the materials properties as discussed in the paper. A particular coupling factor is defined to quantify and check the effectiveness of pyroelectric energy harvesting. It is defined similarly to an electromechanical coupling factor as k2 = p2thetas0/(epsivthetas 33 CE), where p, thetas0, epsivthetas 33, Ce are pyroelectric coefficient, maximum working temperature, dielectric permittivity, and specific heat, respectively. The importance of the electrothermal coupling factor is shown and discussed as an energy harvesting figure of merit. It gives the effectiveness of all techniques of energy harvesting (except the Carnot cycle). It is finally shown that we could reach very high efficiency using lang111rang0.75Pb(Mg1/3Nb2/3)-0.25PbTiO3 single crystals and synchronized switch harvesting on inductor (almost 50% of Carnot efficiency). Finally, practical implementation key points of pyroelectric energy harvesting are presented showing that the different thermodynamic cycles are feasible and potentially effective, even compared to thermoelectric devices.

Pyroelectric energy conversion: Optimization principles

This paper presents an experimental piezoelectric energy harvester exhibiting strong mechanical nonlinear behavior. Vibration energy harvesters are usually resonant mechanical systems working at resonance. The resulting mechanical amplification gives an output power multiplied by the mechanical quality factor Q when compared to non-resonant systems, provided that the electromechanical coupling k2 is high as well as the mechanical quality factor Q. However, increasing the Q value results in a narrowband energy harvester, and the main drawback is the difficulty of matching a given vibration frequency range to the energy harvester's resonance frequency. Mechanical nonlinear stiffness results in a distortion of the resonance peak that may lead to a broadband energy harvesting capability while keeping a large output power as for high Q systems. This paper is devoted to an experimental study of a Duffing oscillator exhibiting piezoelectric electromechanical coupling. A nonlinear electromechanical model is first presented including piezoelectric coupling, a nonlinear stiffness as for a Duffing oscillator, and an additional nonlinear loss term. Under harmonic excitation, it is shown that for a particular excitation range, the power frequency bandwidth is multiplied by a factor of 5.45 whereas the output power is decreased by a factor of 2.4. In addition, when compared to a linear system exhibiting the same power bandwidth as for the nonlinear one (which is here 7.75%), the output power is increased by a factor of 16.5. Harmonic study is, however, partially irrelevant, because Duffing oscillators exhibit a frequency range where two stable harmonic solutions are possible. When excited with sine bursts or colored noise, the oscillator remains most of the time at the lowest solution. In this paper, we present a technique—called fast burst perturbation—which consists of a fast voltage burst applied to the piezoelectric element. It is then shown that the resonator may jump from the low solution to the high solution at a very small energy cost. Time-domain solution of the model is presented to support experimental data.

https://iopscience.iop.org/article/10.1088/0964-1726/20/10/102001/pdf

Experimental Duffing oscillator for broadband piezoelectric energy harvesting

Synchronized switch damping (SSD) principle and derived techniques have been developed to address the problem of structural damping. Compared with standard passive piezoelectric damping, these new semi-passive techniques offer the advantage of self-adaptation with environmental variations. Unlike active damping systems, their implementation does not require any sophisticated signal processing nor any bulky power amplifier. This paper presents an enhancement of the SSD technique on voltage source (SSDV) which is the most effective of the SSD techniques. The former SSDV technique uses a constant continuous voltage sources whereas the proposed enhancement uses an adaptive continuous voltage source which permits fitting the mechanical braking force resulting from the SSDV process to the vibration level. A theoretical analysis of the SSDV techniques is proposed. Experimental results for structural damping under single frequency and for vibration control of a smart board under white noise excitation are presented and confirm the interest of the enhanced SSDV compared to other SSD techniques. Depending on the excitation type, a 4- to 10-dB damping gain can be achieved.

Piezoelectric vibration control by synchronized switching on adaptive voltage sources: Towards wideband semi-active damping

Pyroelectric and electrocaloric characterization has been determined for 0.75Pb(Mg1∕3Nb2∕3)O3–0.25PbTiO3 relaxor based single crystal and ceramic. Differential scanning calorimetry was used for measuring the electrocaloric response for different electric fields in the vicinity of the Curie temperature. For both ceramic and crystals the maximum activity is found to be around the transition temperature. On the other hand hysteresis loops for different temperatures were used to predict the electrocaloric effect with very good qualitative agreements with direct measurements. Pyroelectric coefficient is found to be much larger for ⟨111⟩ single crystals reaching 1300×10−6Cm−2K−1 whereas the ceramic reaches only 750×10−6Cm−2K−1. Higher pyroelectric coefficient and lower dielectric permittivity lead to outstanding figures of merits for sensors and energy harvesting, with a gain of 260% for voltage responsivity and more than 500% for energy harvesting. Although having a much larger pyroelectric activity, the elect...

Gael Sebald

Papers

On thermoelectric and pyroelectric energy harvesting

Pyroelectric energy conversion: Optimization principles

Experimental Duffing oscillator for broadband piezoelectric energy harvesting

Piezoelectric vibration control by synchronized switching on adaptive voltage sources: Towards wideband semi-active damping

Electrocaloric and pyroelectric properties of 0.75Pb(Mg1∕3Nb2∕3)O3–0.25PbTiO3 single crystals