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Helge Müller-Bunz

Researcher at University College Dublin

Publications -  255
Citations -  7111

Helge Müller-Bunz is an academic researcher from University College Dublin. The author has contributed to research in topics: Ligand & Enantioselective synthesis. The author has an hindex of 42, co-authored 248 publications receiving 6406 citations. Previous affiliations of Helge Müller-Bunz include University of Stuttgart.

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Water Oxidation Catalyzed by Strong Carbene‐Type Donor‐Ligand Complexes of Iridium

TL;DR: Water oxidation catalyzed by strong carbene-type donor ligand complexes of iridium by Angewandte Chemie International Edition.
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Synthesis, X-ray crystal structures and biomimetic and anticancer activities of novel copper(II)benzoate complexes incorporating 2-(4'-thiazolyl)benzimidazole (thiabendazole), 2-(2-pyridyl)benzimidazole and 1,10-phenanthroline as chelating nitrogen donor ligands.

TL;DR: The catalase and superoxide dismutase (SOD) activities of the four complexes along with those of the known phenanthroline complexes were investigated and the structural results for 4 represent a re-examination of this crystallographically known compound for which no hydrogen atom coordinates have been previously reported.
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PEPPSI‐Type Palladium Complexes Containing Basic 1,2,3‐Triazolylidene Ligands and Their Role in Suzuki–Miyaura Catalysis

TL;DR: Mechanical investigations provide evidence for ligand dissociation and the formation of nanoparticles as a catalyst resting state and the substitution of a normal N-heterocyclic carbene for a more basic triazolylidene ligand in the precatalyst has a profound impact on the mode of action of the catalytic system.
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Novel benzyl-substituted N-heterocyclic carbene–silver acetate complexes: synthesis, cytotoxicity and antibacterial studies

TL;DR: Six NHC-silver complexes showed improved cytotoxicity against Caki-1, most notably for 4c, which is a three times more cytotoxic than cisplatin (IC₅₀ value = 3.3 μM) itself.
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Synthesis and Tunability of Abnormal 1,2,3-Triazolylidene Palladium and Rhodium Complexes

TL;DR: In this article, N3-alkylated 1,2,3-triazolium salts with Pd(OAc)2 afforded a μ2−I2 bridged bimetallic complex [Pd(trz)I2]2 and monometallic bis(carbene) complexes Pd[trz]2I2 as a mixture of trans and cis isomers.