J
John R. Miller
Researcher at Brookhaven National Laboratory
Publications - 120
Citations - 8446
John R. Miller is an academic researcher from Brookhaven National Laboratory. The author has contributed to research in topics: Electron transfer & Ion. The author has an hindex of 41, co-authored 120 publications receiving 8084 citations. Previous affiliations of John R. Miller include Academy of Sciences of the Czech Republic & Tokyo Institute of Technology.
Papers
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Journal ArticleDOI
Intramolecular Long-Distance Electron Transfer in Organic Molecules
Gerhard L. Closs,John R. Miller +1 more
TL;DR: Theoretical predictions of an "inverted region," where increasing the driving force of the reaction will decrease its rate, have begun to be experimentally confirmed and a predicted nonlinear dependence of ET rates on the polarity of the solvent has also been confirmed.
Journal ArticleDOI
Charge Transfer on the Nanoscale: Current Status
David M. Adams,Louis E. Brus,Christopher E. D. Chidsey,Stephen E. Creager,Carol Creutz,Cherie R. Kagan,Prashant V. Kamat,X Marya Lieberman,O Stuart Lindsay,Rudolph A. Marcus,Robert M. Metzger,Maria-Elisabeth Michel-Beyerle,John R. Miller,Marshall D. Newton,Debra R. Rolison,Otto F. Sankey,Kirk S. Schanze,James T. Yardley,Xiaoyang Zhu +18 more
TL;DR: The current status of basic electron transfer research, both theoretical and experimental, with emphasis on the distance-dependent measurements, was discussed in this article, where the authors attempted to integrate terminology and notation of solution electron-transfer kinetics with that of conductance analysis.
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Intramolecular long-distance electron transfer in radical anions. The effects of free energy and solvent on the reaction rates
TL;DR: In this paper, a homologous series of eight compounds of the general structure A-Sp-B where B is 4-biphenylyl, Sp is a rigid saturated hydrocarbon spacer, the steroidal 5-cap alpha-androstane skeleton, and A is one of a series of 8 different molecular groups with π.. electron networks was synthesized.
Journal ArticleDOI
Distance, stereoelectronic effects, and the Marcus inverted region in intramolecular electron transfer in organic radical anions
TL;DR: A series of molecules with the general structure A/sub 1/-Sp-A/sub 2/ have been synthesized and the rates of intramolecular electron transfer were measured as mentioned in this paper.
Journal ArticleDOI
Effect of free energy on rates of electron transfer between molecules
TL;DR: In this paper, the electron transfer rate constant k(r) is quantitatively measured as a function of distance using the random distribution of distances between D/sup -/, A pairs.