scispace - formally typeset
Search or ask a question

Showing papers by "Mahesh Kumar published in 2017"


Journal ArticleDOI
TL;DR: This corrects the article DOI: 10.1038/srep36132 to indicate that the author of the paper is a doctor of medicine rather than a scientist, as previously reported.
Abstract: Scientific Reports 6: Article number: 36132; published online: 31 October 2016; updated: 26 June 2017. This Article contains errors. The Acknowledgements section is incomplete. “We thank the Department of Biotechnology (DBT), Government of India for research support to the Institute of Bioinformatics (IOB), Bangalore.

839 citations


Journal ArticleDOI
TL;DR: The demonstrated ultrafast detection and reversible MoS2 gas sensor at room temperature shows reliable selectivity toward NO2 against various other gases and reveals the potential of 2D MoS 2 to develop a low power portable gas sensor.
Abstract: Two-dimensional materials have gained considerable attention in chemical sensing owing to their naturally high surface-to-volume ratio. However, the poor response time and incomplete recovery at room temperature restrict their application in high-performance practical gas sensors. Herein, we demonstrate ultrafast detection and reversible MoS2 gas sensor at room temperature. The sensor’s performance is investigated to NO2 at room temperature, under thermal and photo energy. Incomplete recovery and high response time of ∼249 s of sensor are observed at room temperature. Thermal energy is enough to complete recovery, but it is at the expense of sensitivity. Further, under photo excitation, MoS2 exhibits an enhancement in sensitivity with ultrafast response time of ∼29 s and excellent recovery to NO2 (100 ppm) at room temperature. This significant improvement in sensitivity (∼30%) and response time (∼88%) is attributed to the charge perturbation on the surface of the sensing layer in the context of NO2/MoS2 i...

314 citations


Journal ArticleDOI
TL;DR: This highly hydrogen selective Pd contacted ZnO nanorods based sensor detecting low concentration even at low operating temperature of 50 °C is reported, which exhibits dual characteristics as metal contact and excellent catalyst to hydrogen molecules.
Abstract: We report highly hydrogen selective Pd contacted ZnO nanorods based sensor detecting low concentration even at low operating temperature of 50 °C. The sensor performance was investigated for various gases such as H2, CH4, H2S and CO2 at different operating temperatures from 50 °C to 175 °C for various gas concentrations ranging from 7 ppm to 10,000 ppm (1%). The sensor is highly efficient as it detects hydrogen even at low concentration of ~7 ppm and at operating temperature of 50 °C. The sensor’s minimum limit of detection and relative response at 175 °C were found 7 ppm with ~38.7% for H2, 110 ppm with ~6.08% for CH4, 500 ppm with ~10.06% for H2S and 1% with ~11.87% for CO2. Here, Pd exhibits dual characteristics as metal contact and excellent catalyst to hydrogen molecules. The activation energy was calculated for all the gases and found lowest ~3.658 kJ/mol for H2. Low activation energy accelerates desorption reactions and enhances the sensor’s performance.

112 citations


Journal ArticleDOI
TL;DR: In this article, the authors reported strong evidence for preferential hydrogen adsorption at edge-sites in an edge oriented vertically aligned 3-D network of MoS2 flakes at room temperature.
Abstract: The increased usage of hydrogen as a next generation clean fuel strongly demands the parallel development of room temperature and low power hydrogen sensors for their safety operation. In this work, we report strong evidence for preferential hydrogen adsorption at edge-sites in an edge oriented vertically aligned 3-D network of MoS2 flakes at room temperature. The vertically aligned edge-oriented MoS2 flakes were synthesised by a modified CVD process on a SiO2/Si substrate and confirmed by Scanning Electron Microscopy. Raman spectroscopy and PL spectroscopy reveal the signature of few-layer MoS2 flakes in the sample. The sensor's performance was tested from room temperature to 150 °C for 1% hydrogen concentration. The device shows a fast response of 14.3 s even at room temperature. The sensitivity of the device strongly depends on temperature and increases from ∼1% to ∼11% as temperature increases. A detail hydrogen sensing mechanism was proposed based on the preferential hydrogen adsorption at MoS2 edge ...

52 citations


Journal ArticleDOI
TL;DR: In this paper, the effect of self-heating of AlGaN/GaN high electron mobility transistors (HEMTs) characteristics fabricated on Si(111) substrate has been carried out by Sentaurus TCAD simulator tool.
Abstract: In order to study the effect of self-heating of AlGaN/ GaN high electron mobility transistors (HEMTs) characteristics fabricated on Si(111) substrate, simulations of 2DEG temperature on different drain voltages have been carried out by Sentaurus TCAD simulator tool. Prior to the electrical direct-current (DC) characteristics studies, structural properties of the HEMT structures were examined by scanning transmission electron microscopy. The comparative analysis of simulation and experimental data provided sheet carrier concentration, mobility, surface traps, electron density at 2DEG by considering factors such as high field saturation, tunneling and recombination models. Mobility, surface trap concentration and contact resistance were obtained by TCAD simulation and found out to be ∼1270cm2/Vs, ∼2×1013 cm-2 and ∼0.2 Ω.mm, respectively, which are in agreement with the experimental results. Consequently, simulated current-voltage characteristics of HEMTs are in good agreement with experimental results. The ...

49 citations


Journal ArticleDOI
TL;DR: The UV-photoactivated mode enhanced the adsorption of photo-induced O- and O2- ions, and the d-band electron transition from the Au nanoparticles to ZnO-which increased the chemisorbed reaction between hydrogen and oxygen.
Abstract: Room temperature hydrogen sensors were fabricated from Au embedded ZnO nano-networks using a 30 mW GaN ultraviolet LED. The Au-decorated ZnO nano-networks were deposited on a SiO2/Si substrate by a chemical vapour deposition process. X-ray diffraction (XRD) spectrum analysis revealed a hexagonal wurtzite structure of ZnO and presence of Au. The ZnO nanoparticles were interconnected, forming nano-network structures. Au nanoparticles were uniformly distributed on ZnO surfaces, as confirmed by FESEM imaging. Interdigitated electrodes (IDEs) were fabricated on the ZnO nano-networks using optical lithography. Sensor performances were measured with and without UV illumination, at room temperate, with concentrations of hydrogen varying from 5 ppm to 1%. The sensor response was found to be ∼21.5% under UV illumination and 0% without UV at room temperature for low hydrogen concentration of 5 ppm. The UV-photoactivated mode enhanced the adsorption of photo-induced O- and O2- ions, and the d-band electron transition from the Au nanoparticles to ZnO-which increased the chemisorbed reaction between hydrogen and oxygen. The sensor response was also measured at 150 °C (without UV illumination) and found to be ∼18% at 5 ppm. Energy efficient low cost hydrogen sensors can be designed and fabricated with the combination of GaN UV LEDs and ZnO nanostructures.

33 citations


Journal ArticleDOI
TL;DR: In this paper, temperature dependent currentvoltage (I-V ) characteristics of metal-TiO 2 nanoplates-M planer electrodes were measured in air and 1% hydrogen atmosphere.

24 citations


Patent
03 May 2017
TL;DR: In this paper, the authors proposed a method for evaluating driver performance, which comprises receiving driver activity associated with a driver of a vehicle in a fleet, determining a driver score based on predetermined criteria and generating and updating a driver profile based on the driver activity and evaluating the driver score to generate rewards for the driver and updating the driver profile accordingly.
Abstract: The present invention is directed towards a method for evaluating driver performance. In exemplary embodiments, the method comprises receiving driver activity associated with a driver of a vehicle in a fleet, determining a driver score based on predetermined criteria and generating and updating a driver profile based on the driver activity and evaluating the driver score to generate rewards for the driver and updating the driver profile accordingly.

16 citations


Journal ArticleDOI
TL;DR: In this paper, the effects of solute concentration in the KCl-flux growth and partial A-and B-site substitution are investigated in order to further improve the photocatalytic performance of LaFeO 3.

14 citations


Journal ArticleDOI
TL;DR: In this article, transmission electron-microscopy examination revealed the appearance of hexagonal silicon inclusions in the subsrface silicon layer upon ion implantation and subsequent heat treatment of the SiO2/Si structure.
Abstract: Transmission electron-microscopy examination revealed the appearance of a hexagonal silicon (9R polytype) inclusions in the subsrface silicon layer upon ion implantation and subsequent heat treatment of the SiO2/Si structure. The formation of this hexagonal phase is stimulated by mechanical stresses arising in the heterophase system in the course of ion implantation.

8 citations


Journal ArticleDOI
TL;DR: In this paper, the surface chemical states of Ba 0.5 Sr and TiO 3 (BST) thin films were studied as a function of high energy photon doses and the gamma-ray irradiated BST films showed a higher binding energy shift of Ba, Sr, and Ti core level with increasing gamma doses due to shift in Fermi level.

Journal ArticleDOI
TL;DR: In this paper, the chemical composition and photoluminescence of implanted layers have been investigated with the aim to establish the possibility of synthesis of GaN inclusions by co-implantation of Ga and N ions in silicon and SiO2 films on a silicon substrate.
Abstract: With the aim to establish the possibility of synthesis of GaN inclusions by co-implantation of Ga and N ions in silicon and SiO2 films on a silicon substrate, the chemical composition and photoluminescence of implanted layers have been investigated. It is observed that the heavy loss of implanted atoms occurs owing to the out-diffusion (Ga from Si, and Ga and N from SiO2) in the process of post-implantation annealing. Preliminary implantation of nitrogen to form silicon nitride or oxynitride layers is shown to reduce the degree of impurity losses. In the photoluminescence spectrum of both Si and SiO2 subjected to Ga and N co-implantation, the band at 530-550 nm is present, which can be related to 'defect' luminescence of GaN.


Journal Article
TL;DR: In this article, crystalline, uniform and stoichiometric thin films of CdS were fabricated on soda lime glass (SLG) substrates using vacuum thermal deposition method in the presence of hydrogen sulphide (H 2 S) atmosphere.
Abstract: Crystalline, uniform and stoichiometric thin films of CdS have been fabricated on soda lime glass (SLG) substrates using vacuum thermal deposition method in the presence of hydrogen sulphide (H 2 S) atmosphere. The consequence of ambient H 2 S on the growth, quality and structure-property relationship of vacuum deposited CdS thin films has been investigated. The deposited films have been characterized by XRD, SEM with EDX analysis, AFM, XPS and optical spectroscopy. The physical characterization of as-deposited CdS films reveals that the films deposited in controlled H 2 S ambient are more crystalline, highly uniform and stoichiometric in comparison to films deposited without H 2 S atmosphere.

Journal ArticleDOI
01 Feb 2017
TL;DR: In this article, a variable temperature inserts (VTI) was designed and developed for measurement of physical properties at low temperature and high magnetic field, using the helium exchange gas principle.
Abstract: A cryocooler based variable temperature inserts (VTI) has been designed and developed for measurement of physical properties at low temperature and high magnetic field. The VTI, designed using the helium exchange gas principle, needs to be integrated in the warm bore of an existing 6 T cryogen free magnet system. The lowest temperature achieved at the sample is 5 K at 34.5 kPa (~5 psi) gaseous helium environment in the sample space. The equilibrium temperature of the sample, at the vacuum condition, is 8.7 K. The cool-down time of the sample at vacuum environment is 9 hrs whereas it takes 7 hrs in presence of helium exchange gas. The temperature of the sample was varied up to 325 K. The stability of the temperature achieved is less than 50 mK. The cooling and heating curves has been studied to estimate time required for a complete cycle of experiment. This paper will briefly present the design and performance of VTI system in temperature range of 5-325 K.