Nicholas J. Turro

TL;DR: In this paper, the generation of hydroxyl radicals produced by irradiation of aqueous TiO2 suspensions was investigated by electron paramagnetic resonance (EPR) and product analysis employing a stable free nitroxide radical (3-carboxyproxyl) as a spin trap of •OH.

TL;DR: A simple scheme involving atom transfer radical polymerization (ATRP) from a bifunctional initiator, conversion of the bromine end groups of the resulting telechelic polymer to azides, and cross-linking of this azido-telechelic macromonomer with multi-acetylene functionalized small molecules via copper-catalyzed azide-alkyne cycloaddition was employed to prepare the first tert-butyl acrylate model networks.

TL;DR: A DNA sequencing method that is a hybrid between the Sanger dideoxynucleotide terminating reaction and SBS, using four nucleotides modified as reversible terminators by capping the 3′-OH with a small reversible moiety so that they are still recognized by DNA polymerase as substrates to perform SBS.

TL;DR: In this article, the theory of intersystem crossing in radical pairs is presented, which provides a simple unified theoretical basis for understanding chemically induced nuclear polarization (CIDNP), the magnetic spin isotope effect, and magnetic field effects on chemical reactions.

TL;DR: The synthesis of neuromelanins in the various regions of the human brain is an important protective process because the melanic component is generated through the removal of reactive/toxic quinones that would otherwise cause neurotoxicity.