Rosario Scopelliti

TL;DR: In this article, a molecularly engineered hole-transport material with a simple dissymmetric fluorene-dithiophene core substituted by N,N-di-p-methoxyphenylamine donor groups is presented.

TL;DR: Observations establish that a molecular uranium complex can promote the stoichiometric transformation of N2 into NH3 or cyanate, and that a flexible, electron-rich, multimetallic, nitride-bridged core unit is a promising starting point for the design of molecular complexes capable of cleaving and functionalizing N2 under mild conditions.

TL;DR: The condensation of multiple building blocks in a ball mill allows molecular cages with a size up to 3.1 nm to be built.

TL;DR: The chiral stationary phase for zinc selectivity has been reported for the first time and the chiral phase for transition mas nmr has also been reported.

TL;DR: This work reproduced the loss of picolinate and acetylacetonate ancillary ligands in solution by the addition of Brønsted or Lewis acids and advantageously used this degradation reaction for the efficient synthesis of tris-heteroleptic cyclometalated iridium(III) complexes.