R
Rosario Scopelliti
Researcher at École Polytechnique Fédérale de Lausanne
Publications - 422
Citations - 15903
Rosario Scopelliti is an academic researcher from École Polytechnique Fédérale de Lausanne. The author has contributed to research in topics: Ligand & Chemistry. The author has an hindex of 65, co-authored 394 publications receiving 13844 citations.
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The Hetero-Diels–Alder Addition of Sulfur Dioxide to 1-Fluorobuta-1,3-dienes: The Sofa Conformations Preferred by 6-Fluorosultines (6-Fluoro-3,6-dihydro-1,2-oxathiin-2-oxides) Enjoy Enthalpic and Conformational Anomeric Effects
Elena Roversi,Rosario Scopelliti,Euro Solari,Raphaël Estoppey,Pierre Vogel,Pedro Braña,Bibiana Menéndez,José A. Sordo +7 more
TL;DR: Experiments and high-level quantum calculations confirm the existence of a stabilizing, enthalpic, anomeric (gem-disubstitution by sulfinyloxy and fluoro groups) effect, interpreted in terms of (lone pair) n(O1)-->sigma*(C-F) hyperconjugative interactions.
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Copper(ii) complexes with tridentate halogen-substituted Schiff base ligands: synthesis, crystal structures and investigating the effect of halogenation, leaving groups and ligand flexibility on antiproliferative activities.
Nazanin Kordestani,Hadi Amiri Rudbari,Alexandra R. Fernandes,Luís Raposo,André Luz,Pedro V. Baptista,Giuseppe Bruno,Rosario Scopelliti,Zohreh Fateminia,Nicola Micale,Nikolay Tumanov,Johan Wouters,Abolghasem Abbasi Kajani,Abdol Khalegh Bordbar,Abdol Khalegh Bordbar +14 more
TL;DR: In this paper, the effect of different halogen substituents and leaving groups and the flexibility of ligands on the anticancer activity of copper complexes were investigated and characterized by spectroscopic methods.
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Ruthenium–benzocrownether complexes: Synthesis, structures, catalysis and immobilisation in ionic liquids
TL;DR: In this paper, a facile pathway to [RuCl2(η6-benzocrownether)]2 complexes is described and crystal structures of the complexes are reported and evaluated in the enantioselective transfer-hydrogenation of acetophenone.
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A Simple Approach to Room Temperature Phosphorescent Allenylidene Complexes
Florian Kessler,Basile F. E. Curchod,Ivano Tavernelli,Ursula Rothlisberger,Rosario Scopelliti,Davide Di Censo,Michael Grätzel,Md. K. Nazeeruddin,Etienne Baranoff +8 more
TL;DR: The chiral stationary phase for high-performance liquid chromatography showed good chiral recognition ability towards various racemates, including phosphorescent iridium complexes and alkynyl complexes.
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Pd, Pt, and Ru complexes of a pincer bis(amino)amide ligand
TL;DR: An improved synthesis of pincer ligand bis[(2-dimethylamino)phenyl]amine ((Me)N(2)NH) was reported, and the Ru complex showed activity in catalytic transfer hydrogenation of aryl and alkyl ketones.