T
Takahiro Ikegami
Researcher at Kyushu University
Publications - 4
Citations - 171
Takahiro Ikegami is an academic researcher from Kyushu University. The author has contributed to research in topics: Myoglobin & Ligand (biochemistry). The author has an hindex of 4, co-authored 4 publications receiving 161 citations. Previous affiliations of Takahiro Ikegami include Kyoto Pharmaceutical University.
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Journal ArticleDOI
Ligand binding properties of myoglobin reconstituted with iron porphycene: unusual O2 binding selectivity against CO binding.
Takashi Matsuo,Hirohisa Dejima,Shun Hirota,Dai Murata,Hideaki Sato,Takahiro Ikegami,Hiroshi Hori,Yoshio Hisaeda,Takashi Hayashi +8 more
TL;DR: The high O2 affinity and the unique characteristics of the myoglobin with the iron porphycene indicate that reconstitution with a synthesized heme is a useful method not only to understand the physiological function of myoglobin but also to create a tailor-made function on the protein.
Journal ArticleDOI
Synthesis, structure, and chemical property of the first fluorine-containing porphycene.
Takashi Hayashi,Yuji Nakashima,Kazuyuki Ito,Takahiro Ikegami,Isao Aritome,and Akihiro Suzuki,Yoshio Hisaeda +6 more
TL;DR: A pyrrolic macrocycle, beta-tetrakis(trifluoromethyl)porphycene, is the first example of a fluorine-containing porphycenes, where four electron-withdrawing CF(3) substituents provide a highly distorted structure and an attractive electron-deficient nature for the porphyCene framework.
Journal ArticleDOI
Synthesis, characterization, and autoreduction of a highly electron-deficient porphycenatoiron(III) with trifluoromethyl substituents.
Takashi Hayashi,Yuji Nakashima,Kazuyuki Ito,Takahiro Ikegami,Isao Aritome,Katsuhiro Aoyagi,Tsutomu Ando,Yoshio Hisaeda +7 more
TL;DR: The results indicate that the trifluoromethylated iron porphycene is a highly electron-deficient complex with a pyrrolic macrocycle ligand.
Journal ArticleDOI
Ligand binding properties of two kinds of reconstituted myoglobins with iron porphycene having propionates : Effect of β-pyrrolic position of two propionate side chains in porphycene framework
TL;DR: The present myoglobin showed a faster O(2) dissociation than the previously studied myoglobin, which suggests that the position of the two propionates as well as the symmetry of the porphycene framework is an important factor for obtaining a stable oxygenated iron porphyCene myoglobin.