Journal ArticleDOI
1,2,3-Triazole and its derivatives. Development of methods for the formation of the triazole ring
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In this paper, the synthetic routes to substituted 1,2,3-triazoles, including those containing functional groups, based on cyclisation of various nitrogen compounds published during the last 15 years are described.Abstract:
Data on the synthetic routes to substituted 1,2,3-triazoles, including those containing functional groups, based on cyclisation of various nitrogen compounds published during the last 15 years are described. Examples of using new triazole derivatives in agrochemistry, medicine and engineering are given.read more
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Copper-catalyzed azide–alkyne cycloaddition (CuAAC) and beyond: new reactivity of copper(I) acetylides
Jason E. Hein,Valery V. Fokin +1 more
TL;DR: This tutorial review examines the history of the development of the CuAAC reaction, its key mechanistic aspects, and highlights the features that make it useful to practitioners in different fields of chemical science.
Journal ArticleDOI
Transition Metal-Mediated Synthesis of Monocyclic Aromatic Heterocycles
TL;DR: The present review is a transition metal-catalyzed synthesis of aromatic monocyclic heterocycles, aiming at achieving greater levels of molecular complexity and better functional group compatibilities in a convergent and atom economical fashions from readily accessible starting materials and under mild reaction conditions.
Journal ArticleDOI
Intramolecular Cross-Linking Methodologies for the Synthesis of Polymer Nanoparticles.
Journal ArticleDOI
Copper‐Catalyzed Synthesis of N‐Sulfonyl‐1,2,3‐triazoles: Controlling Selectivity
Eun Jeong Yoo,Mårten S. G. Ahlquist,Seok Hwan Kim,Imhyuck Bae,Valery V. Fokin,K. Barry Sharpless,Sukbok Chang +6 more
TL;DR: 4-Substituted 1-(N-sulfonyl)-1,2,3-triazoles are selectively obtained by using the Cu-catalyzed azide-alkyne cycloaddition reaction with sulfonyl azides and provides convenient access to N-Sulfonyltriazoles in good to excellent yields.
Journal ArticleDOI
Electrochemical nanoarchitectonics and layer-by-layer assembly: From basics to future
Gaulthier Rydzek,Qingmin Ji,Mao Li,Pierre Schaaf,Jonathan P. Hill,Fouzia Boulmedais,Fouzia Boulmedais,Katsuhiko Ariga +7 more
TL;DR: The state of the art of electrochemical devices based on layer-by-layer (LbL) assemblies is described in this paper, with a focus on supercapacitors, biosensors, and electroresponsive LbL such as electrodissolution/electroswelling of coatings.
References
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Journal ArticleDOI
A stepwise huisgen cycloaddition process: copper(I)-catalyzed regioselective "ligation" of azides and terminal alkynes.
Book
Comprehensive Heterocyclic Chemistry II
TL;DR: In this article, the CHEC III is organized in 15 volumes and closely follows the organization used in the previous edition: Volumes 1 and 2: Cover respectively three and four-membered heterocycles, together with all fused systems containing a three- or four-measured heterocyclic ring.
Journal ArticleDOI
Peptidotriazoles on solid phase: [1,2,3]-triazoles by regiospecific copper(i)-catalyzed 1,3-dipolar cycloadditions of terminal alkynes to azides.
TL;DR: A novel regiospecific copper(I)-catalyzed 1,3-dipolar cycloaddition of terminal alkynes to azides on solid-phase is reported, and the X-ray structure of 2-azido-2-methylpropanoic acid has been solved, to yield structural information on the 1, 3-dipoles entering the reaction.
Journal ArticleDOI
The growing impact of click chemistry on drug discovery.
TL;DR: The copper-(I)-catalyzed 1,2,3-triazole formation from azides and terminal acetylenes is a particularly powerful linking reaction, due to its high degree of dependability, complete specificity, and the bio-compatibility of the reactants.
Book
1,3-Dipolar Cycloaddition Chemistry
TL;DR: The theory of 1-3-Dipolar Cycloadditions is discussed in this article. But it does not consider higher-order cycloaddings and higher order cycloreversions.