Journal ArticleDOI
A Catalytic Enantioselective Michael Addition of a Simple Malonate to Prochiral α,β‐Unsaturated Ketoses and Aldehydes
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This article is published in Angewandte Chemie.The article was published on 1993-08-01. It has received 152 citations till now. The article focuses on the topics: Michael reaction & Malonate.read more
Citations
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Asymmetric enamine catalysis.
Journal ArticleDOI
Organocatalytic asymmetric conjugate additions
TL;DR: An overview of the most important developments and concepts of this flourishing area of catalysis organized by the type of nucleophile involved in the process is reported.
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The ying and yang of asymmetric aminocatalysis
TL;DR: An overview of asymmetric catalysis of carbonyl transformations via iminium ion and enamine intermediates using chiral amines as organocatalysts has been given and their recent merger in tandem sequences is discussed.
References
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New Type of Asymmetric Cyclization to Optically Active Steroid CD Partial Structures
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Neuartige asymmetrische Cyclisierung zu optisch aktiven Steroid‐CD‐Teilstücken
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Asymmetric Total Synthesis of Erythromycin. 1. Synthesis of an Erythronolide A Seco Acid Derivative via Asymmetric Induction
TL;DR: The specific incorporation per C4 unit, 3.3%, calculated from 13C NMR data (Table I), is identical with that obtained from I4C radioactivity measurements.