Journal ArticleDOI
A Kinetic Study of the ortho-Claisen Rearrangement1
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This article is published in Journal of the American Chemical Society.The article was published on 1958-07-01. It has received 113 citations till now. The article focuses on the topics: Specific kinetic energy.read more
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Flash vacuum pyrolysis. II. Electronic, vibrational, and electron spin resonance spectra of the benzyl radical
Journal ArticleDOI
A new synthesis of benzofurans from phenols via Claisen rearrangement and ring-closing metathesis
Tzu-Wei Tsai,Eng-Chi Wang,Sie-Rong Li,Yung-Hua Chen,Yu-Li Lin,You-Feng Wang,Keng-Shiang Huang +6 more
TL;DR: In this article, the double bond isomerization of O-allyl function together with the formation of Ovinyl function in one pot, and ring-closing metathesis (RCM), various phenols were transformed into various benzofurans in good yields.
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The carbon analogue of the claisen rearrangement of phenyl allyl ether : Equilibration of Butenylbenzenes and ortho-propenyltoluenes
W. von E. Doering,R.A. Bragole +1 more
TL;DR: In this article, the elusive carbon analogue of the Claise rearrangement of phenyl allyl ether has been realized under strongly basic conditions in t-butyl alcohol containing potassium tbutylate at 350° for 24 hours.
Journal ArticleDOI
Kinetic Pressure and Substituent Effects on the Thermal Isomerization of Triphenylformazans
Yoshimi Sueishi,Norio Nishimura +1 more
TL;DR: In this article, the rates of the thermal isomerization of substituted triphenylformazans were followed spectrophotometrically at various temperatures and under high pressures, and the activation parameters were determined.
Journal ArticleDOI
Highly selective non-catalytic Claisen rearrangement in a high-pressure and high-temperature water microreaction system
Hajime Kawanami,Masahiro Sato,Maya Chatterjee,Nobuhiro Otabe,Tomoya Tuji,Yutaka Ikushima,Takayuki Ishizaka,Toshiro Yokoyama,Toshishige M. Suzuki +8 more
TL;DR: In this paper, a high-pressure and high-temperature water (HPHT-H2O) microreaction system was used to carry out the non-catalytic Claisen rearrangement.
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