Journal ArticleDOI
A Kinetic Study of the ortho-Claisen Rearrangement1
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This article is published in Journal of the American Chemical Society.The article was published on 1958-07-01. It has received 113 citations till now. The article focuses on the topics: Specific kinetic energy.read more
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Notiz betreffend ladunsinduzierte Umlagerung von Allyl‐aryläthern mit Trifluoressiǵsäure
TL;DR: The rearrangement of allylarylethers in trifluoracetic acid to the corresponding 2-allylphenols according to Svanholm & Parker [1] is shown to be of the charge-induced [3s, 3s]-type.
Journal ArticleDOI
Das thermische Verhalten von 2,4,6-Trimethyl-phenyl-allyläther-[γ-14C]. Zur Kenntnis der CLAISEN-Umlagerung XI†‡§
P. Fahrni,H. Schmid +1 more
TL;DR: In this article, ausgehende Isomerisierungsreaktion ist von der Radikalspaltung unabhangig und stellt einen essentiell intramolekularen Prozess dar.
Journal ArticleDOI
Rearrangements of N-heteroaromatic-2-vinyl-aziridines. Synthesis of isothiazolo-, pyrido- and thieno-azepines
Hubert Figeys,R. Jammar +1 more
TL;DR: N-heteroaromatic 2-vinyl-aziridines have been synthesized and thermally isomerized to the corresponding isothiazolo-, pyrido- and thienoazepine derivatives.
Journal ArticleDOI
Liquid Crystal Solvents as Reaction Media for the Claisen Rearrangement
W. E. Bacon,Glenn H. Brown +1 more
TL;DR: In this paper, the authors report some kinetic data for the Claisen rearrangement of allyl phenyl ethers (1) which proceeds by an intramolecular path to give an ortho-dienone (II) which rapidly enolizes to 2-allylphenols (III).
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A facile claisen rearrangement involving the transient tautomeric enamine forms of α-allyloxy and α-propargyloxyimines
TL;DR: In this paper, α-propargyloxyimines gave 2-amino-2-allenylketones by rearranging the tautomeric secondary enamine.
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