Journal ArticleDOI
A novel coordination polymer containing both interdigitated 1D chains and interpenetrated 2D grids.
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TLDR
A hydro(solvo)thermal reaction between zinc perchlorate and ethyl ester of a new pyridinecarboxylate bridging ligand of approximately 17.6 A in length yields a unique coordination polymer which contains both interdigitated infinite 1D chains and interpenetrated 2D rhombohedral grids.Abstract:
A hydro(solvo)thermal reaction between zinc perchlorate and ethyl ester of a new pyridinecarboxylate bridging ligand of ∼17.6 A in length yields a unique coordination polymer which contains both interdigitated infinite 1D chains and interpenetrated 2D rhombohedral grids [Zn2.5(L)4(μ3-OH)]·(H2O)5, 1, where L is 3-{[4-(4-pyridylethenyl)phenyl]ethenyl}benzoate. The 1D chains contain μ3-bridged hydroxy groups and have a [Zn4(μ3-OH)2(L)6] stoichiometry, while the 2D grids have a Zn(L)2 formula and diagonal distances of 31.7 and 25.2 A. Crystal data for 1: monoclinic space group P2/c, a = 15.686(2) A, b = 12.6103(16) A, c = 38.999(5) A, β = 98.397(2)°, and Z = 4.read more
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One-Dimensional Coordination Polymers: Complexity and Diversity in Structures, Properties, and Applications
Wei Lee Leong,Jagadese J. Vittal +1 more
TL;DR: The properties of Ladderlike Chains, and the role of Metal Cluster As Building Blocks for 1D CP 718, are described.
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Metal Nuclearity Modulated Four‐, Six‐, and Eight‐Connected Entangled Frameworks Based on Mono‐, Bi‐, and Trimetallic Cores as Nodes
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Ligand-Directed Molecular Architectures: Self-Assembly of Two-Dimensional Rectangular Metallacycles and Three-Dimensional Trigonal or Tetragonal Prisms
TL;DR: Three angular ditopic ligands (1,3-bis(benzimidazol-1-ylmethyl)-4,6-dimethylbenzene L(1), 1,3/2, and 1,4/2 are shape-specific designed ligands, representing an alternative strategy to assembling a trigonal prism, and three structures assembled from three linearly coordinated Ag(+) or Cu(+) ions and two tripodal ligands are presented.
Journal ArticleDOI
Structures and properties of Zn(II) coordination polymers
TL;DR: The properties and properties of coordination polymers derived from Zn(II) and polydentate organic ligands are reviewed in this paper, where a wide variety of structures ranging from simple 1D infinite chains to robust, porous 3D frameworks are discussed.
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Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications.
TL;DR: In this article, the authors provide an overview of different aspects of 2D MOF layered architectures such as topology, interpenetration, structural transformations, properties, and applications.