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Journal ArticleDOI

One-Dimensional Coordination Polymers: Complexity and Diversity in Structures, Properties, and Applications

Wei Lee Leong, +1 more
- 09 Feb 2011 - 
- Vol. 111, Iss: 2, pp 688-764
TLDR
The properties of Ladderlike Chains, and the role of Metal Cluster As Building Blocks for 1D CP 718, are described.
Abstract
2.4.2. Interpenetrated Ladders 711 2.4.3. Unusual Motifs of Ladders 713 2.4.4. Properties of Ladderlike Chains 713 2.5. Rotaxane Polymers 714 2.5.1. 1D Polyrotaxanes 714 2.5.2. 2D Polyrotaxanes 715 2.5.3. 3D Polyrotaxanes 716 2.5.4. Hydrogen-Bonded Polyrotaxanes 716 2.6. Ribbon/Tape Polymers 717 2.7. Metal Cluster As Building Blocks for 1D CP 718 2.7.1. Metal Carboxylate Clusters 718 2.7.2. Metal Halide Clusters 719 2.7.3. Metal Chalcogenide Clusters 720 2.7.4. Polyoxometalate Clusters 721 2.7.5. Single Molecular Magnets as Building Blocks 722

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Citations
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Stimuli-responsive supramolecular polymeric materials.

TL;DR: This critical review of recent developments in supramolecular polymeric materials is addressed, which can respond to appropriate external stimuli at the fundamental level due to the existence of noncovalent interactions of the building blocks.
Journal ArticleDOI

Engineering multifunctional capsules through the assembly of metal-phenolic networks

TL;DR: The ability to incorporate multiple metals into functional metal-phenolic network (MPN) capsules demonstrates that a diverse range of functional materials can be generated.
Journal ArticleDOI

Interpenetration control in metal–organic frameworks for functional applications

TL;DR: An overview of interpenetration involved in coordination polymers with different dimensionalities and property changes (including gas uptake capabilities and catalysis) is provided in this paper, where several approaches for control of interbenetration in MOFs have also been introduced and summarized.
Journal ArticleDOI

Functional Supramolecular Polymers for Biomedical Applications

TL;DR: The trends and representative achievements in the design and synthesis of supramolecular polymers with specific functions are summarized, as well as their wide‐ranging biomedical applications such as drug delivery, gene transfection, protein delivery, bioimaging and diagnosis, tissue engineering, and biomimetic chemistry are summarized.
Journal ArticleDOI

Nanoporous Cobalt(II) MOF Exhibiting Four Magnetic Ground States and Changes in Gas Sorption upon Post-Synthetic Modification

TL;DR: The present stabilization of four magnetic ground states is unique in the field of metal-organic frameworks as well as the electrical conductivity of 1·2.7I2.
References
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MonographDOI

Supramolecular Chemistry: Concepts and Perspectives

TL;DR: From molecular to supramolescular chemistry: concepts and language of supramolecular chemistry, molecular recognition, information, complementarity molecular receptors - design principles and more.
Journal ArticleDOI

Interpenetrating Nets: Ordered, Periodic Entanglement.

TL;DR: A detailed and systematic examination of many interpenetrating nets of this kind is made, and implications for crystal engineering are discussed.
Journal ArticleDOI

Engineering coordination polymers towards applications

TL;DR: In this paper, the development in the field of coordination polymers or metal-organic coordination networks, MOCNs (metal-organic frameworks, MOFs) is assessed in terms of property investigations in the areas of catalysis, chirality, conductivity, luminescence, magnetism, spin-transition (spin-crossover), nonlinear optics (NLO) and porosity or zeolitic behavior upon which potential applications could be based.
Journal ArticleDOI

Magnetic metal-organic frameworks.

TL;DR: The diversity of magnetic exchange interactions between nearest-neighbour moment carriers is examined, covering from dimers to oligomers and their implications in infinite chains, layers and networks, having a variety of topologies.
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