Journal ArticleDOI
Polycatenation, polythreading and polyknotting in coordination network chemistry
TLDR
The use of crystal engineering concepts has produced a variety of coordination networks, many of which exhibit novel and fascinating types of entanglements of individual motifs as mentioned in this paper, and the structures of a number of entangled polymeric networks reported in these years by many groups.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2003-11-01. It has received 1881 citations till now. The article focuses on the topics: Polycatenane.read more
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Applied Topological Analysis of Crystal Structures with the Program Package ToposPro
Vladislav A. Blatov,Vladislav A. Blatov,A. P. Shevchenko,Davide M. Proserpio,Davide M. Proserpio +4 more
TL;DR: ToposPro as mentioned in this paper is a topological analysis of crystal structures realized in the current version of the program package ToposPro, which can be used to analyze various classes of chemical compounds including coordination polymers, molecular crystals, supramolecular ensembles, inorganic ionic compounds, intermetallics, fast-ion conductors, microporous materials.
Journal ArticleDOI
Reticular Chemistry: Occurrence and Taxonomy of Nets and Grammar for the Design of Frameworks
TL;DR: The structures of all 1127 three-periodic extended metal-organic frameworks reported in the Cambridge Structure Database have been analyzed, and their underlying topology has been determined, leading to a system of classification "taxonomy" for interpreting and rationalizing known MOF structures.
Journal ArticleDOI
The atom, the molecule, and the covalent organic framework
TL;DR: The ability to design COFs and to adjust their pore metrics using the principles of reticular synthesis has given rise to frameworks with ultralow densities, which has resulted in the first implementation of the concept of molecular weaving.
Journal ArticleDOI
Tuning the structure and function of metal–organic frameworks via linker design
Weigang Lu,Zhangwen Wei,Zhi-Yuan Gu,Tian-Fu Liu,Jinhee Park,Jihye Park,Jian Tian,Muwei Zhang,Qiang Zhang,Thomas Gentle,Mathieu Bosch,Hong-Cai Zhou +11 more
TL;DR: This critical review of metal-organic frameworks (MOFs) highlights advances in MOF synthesis focusing on linker design and examples of building MOFs to reach unique properties, such as unprecedented surface area, pore aperture, molecular recognition, stability, and catalysis, through linkers are described.
Journal ArticleDOI
Design and synthesis of metal-organic frameworks using metal-organic polyhedra as supermolecular building blocks.
TL;DR: This critical review highlights supermolecular building blocks (SBBs) in the context of their impact upon the design, synthesis, and structure of metal-organic materials (MOMs) by highlighting how the large size and high symmetry of such SBBs can afford improved control over the topology of the resulting MOM and a new level of scale to the resulting framework.
References
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MonographDOI
Supramolecular Chemistry: Concepts and Perspectives
TL;DR: From molecular to supramolescular chemistry: concepts and language of supramolecular chemistry, molecular recognition, information, complementarity molecular receptors - design principles and more.
Journal ArticleDOI
Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.