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Journal ArticleDOI

Adsorption of uranyl onto ferric oxyhydroxides: Application of the surface complexation site-binding model

Ching-kuo Daniel Hsi, +1 more
- 01 Sep 1985 - 
- Vol. 49, Iss: 9, pp 1931-1941
TLDR
In this paper, the surface complexation-site binding model of Davis et al. was used to predict uranyl adsorption from aqueous electrolyte solution onto well-characterized goethite, amorphous ferric oxyhydroxide and hematite sols at 25°C.
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This article is published in Geochimica et Cosmochimica Acta.The article was published on 1985-09-01. It has received 777 citations till now. The article focuses on the topics: Uranyl carbonate & Uranyl.

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Journal ArticleDOI

Uranium speciation control by uranyl sulfate and phosphate in tailings subject to a Sahelian climate, Cominak, Niger

- 01 Jan 2022 - 
TL;DR: In this paper , two U-enriched layers, surficial and buried 14.5 m, of the tailings pile of Cominak, Niger, were studied and the role of uranyl sulfate groups in uranium speciation was highlighted.
Journal ArticleDOI

Evidence for Adsorption of Chlorine Species on Iron (III) (Hydr)oxides in the Sheepbed Mudstone, Gale Crater, Mars

TL;DR: In this article, the adsorption of perchlorate and chloride on ferrihydrite has been investigated in the Sheepbed mudstone at Yellowknife Bay, Gale crater.
Journal ArticleDOI

Geochemistry and environmental impact of neutral drainage from an uraniferous coal waste heap

TL;DR: In this paper, the authors assess to what extent the burnt and unburnt parts of the heap contribute to contamination of the local drainage system over a period lasting >40 years after the end of the mining.
References
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Book

Hydrolysis of Cations

Book

The hydrolysis of cations

Journal ArticleDOI

Uranium solution-mineral equilibria at low temperatures with applications to sedimentary ore deposits

TL;DR: The Gibbs free energies, enthalpies and entropies of 42 dissolved uranium species and 30 uranium-bearing solid phases have been critically evaluated from the literature and estimated when necessary for 25°C.
Journal ArticleDOI

Surface ionization and complexation at the oxide/water interface

TL;DR: In this article, a method for determination of intrinsic ionization and complexation constants of oxide surface sites from potentiometric titration data is reported using these experimental properties and the stoichiometry of surface reactions, surface charge, σo, adsorption density, Γi, and diffuse layer potentials, ψd, at the oxide/water interface.
Journal ArticleDOI

Surface ionization and complexation at the oxide/water interface II. Surface properties of amorphous iron oxyhydroxide and adsorption of metal ions

TL;DR: In this paper, the site-binding model for the electrical double layer of hydrous oxides reported in a previous paper is applied to the adsorption of metal ions from dilute solution and to complex heterogeneous systems, i.e., amorphous iron oxyhydroxide.
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