Journal ArticleDOI
Amine basicity: measurements of ion pair stability in ionic liquid media
Francesca D'Anna,Renato Noto +1 more
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TLDR
In this paper, the stability constants relevant to the formation of amine/p-nitrophenol ion pairs have been determined in [bmim][BF4] solution, in the presence of butylamine, piperidine, and triethylamine by using spectrophotometric measurements.About:
This article is published in Tetrahedron.The article was published on 2007-11-19. It has received 27 citations till now. The article focuses on the topics: Ionic liquid & Piperidine.read more
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Ionic liquids and catalysis: Recent progress from knowledge to applications
TL;DR: In this paper, a survey on the latest most representative developments and progress concerning ionic liquids, from their fundamental properties to their applications in catalytic processes, is presented, highlighting their emerging use for biomass treatment and transformation.
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Screening of pairs of ions dissolved in ionic liquids.
TL;DR: It is concluded that ionic liquids provide very effective electrostatic screening between solute molecules.
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Probing the importance of ionic liquid structure: a general ionic liquid effect on an SNAr process
TL;DR: These data demonstrate a generalised ionic liquid effect, with an increase in rate constant observed in each ionic solvent, though the microscopic origins of the rate constant enhancement differ with the nature of the ionicliquid.
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Electrochemical Determination of pKa of N-Bases in Ionic Liquid Media
TL;DR: It was observed that the strength of N-bases is highly dependent on the anion of the ionic liquid; this observation indicates that pH-dependent reactions could be controlled by the appropriate choice of anion for bulk ILs or as an added co-ion to bulk IL.
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A Comparison of the Acidity Levels in Room-Temperature Ionic Liquids
TL;DR: In this article, the authors evaluated the Bronsted acidity level of several ionic liquids for which a strong acid, such as HNTf 2 and HOTf 2, has been added.
References
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Book
CRC Handbook of Chemistry and Physics
TL;DR: CRC handbook of chemistry and physics, CRC Handbook of Chemistry and Physics, CRC handbook as discussed by the authors, CRC Handbook for Chemistry and Physiology, CRC Handbook for Physics,
Journal ArticleDOI
Ionic Liquids-New "Solutions" for Transition Metal Catalysis.
Peter Wasserscheid,Wilhelm Keim +1 more
TL;DR: There are indications that switching from a normal organic solvent to an ionic liquid can lead to novel and unusual chemical reactivity, which opens up a wide field for future investigations into this new class of solvents in catalytic applications.
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Nanostructural Organization in Ionic Liquids
TL;DR: As the length of the alkyl chain increases, the nonpolar domains become larger and more connected and cause swelling of the ionic network, in a manner analogous to systems exhibiting microphase separation.
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Molecular states of water in room temperature ionic liquids
TL;DR: In this paper, the authors used ATR and transmission IR spectroscopy to investigate the state of water in room temperature ionic liquids (RTILs) based on the 1-alkyl-3-methylimidazolium cation with the anions.