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An overview of creep in tungsten and its alloys

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TLDR
In this article, the authors provide an overview on the current understanding of creep in tungsten and its alloys, and discuss the role of different factors such as grain size and grain shape, rhenium concentration, potassium as dopant, dispersion strengthening with HfC, ThO2, La2O3 and effect of oxygen containing environment on the creep behaviour of tengsten.
Abstract
The objective of this short review is to provide an overview on the current understanding of creep in tungsten and its alloys. Tungsten is a high temperature material on account of its high melting point and has been historically used for light bulb filaments. In recent years it has been under active consideration for plasma facing liners; an application that demands high temperature strength and durability wherein creep performance becomes important. However, tungsten suffers from poor formability which causes difficulties in making complex parts and components from it. A lot of work has been conducted to improve the formability of tungsten and factors such as amount of cold work, alloying additions and grain size and shape were found to play an important role in improving formability of tungsten. Contrary to conventional metals, the ductility of tungsten is enhanced with increasing cold work. Since recrystallization leads to creation of strain-free grains, and recrystallization is a high temperature phenomena, the ductility of tungsten is intricately related to its ability to resist recrystallization to as high temperatures as possible. Since high temperatures invariably make the role of creep deformation important, a lot of work has been carried out to understand the influence of the ductility-enhancing factors on creep of tungsten and its alloys. The review discusses the role of different factors such as grain size and grain shape, rhenium concentration, potassium as dopant, dispersion strengthening with HfC, ThO2, La2O3 and effect of oxygen containing environment on the creep behaviour of tungsten. Wherever possible, data from literature was analyzed to extract important creep parameters such as stress exponent, grain size exponent, activation energy and Larson-Miller parameter to gain an understanding of the mechanism of creep deformation in tungsten and its alloys. It was observed that fine grain size, low rhenium concentration, high potassium content, addition of dispersions especially of HfC, low oxygen concentration and oblong shaped grains are all beneficial for high creep resistance of tungsten.

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Citations
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References
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Book

Deformation-Mechanism Maps: The Plasticity and Creep of Metals and Ceramics

TL;DR: Deformation-mechanism maps: the plasticity and creep of metals and ceramics as discussed by the authors, Deformation-Mechanism Maps of metal deformation: the deformation and the creep of metal and ceramic.
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Physical Metallurgy Principles

TL;DR: Physical Metallurgy Principles as mentioned in this paper is intended for use in an introductory course in physical metallurgy and is designed for all engineering students at the junior or senior level and is largely theoretical, but covers all aspects of physical metelurgy and behavior of metals and alloys.
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Journal ArticleDOI

Diffusional Viscosity of a Polycrystalline Solid

TL;DR: In this article, it is suggested that mosaic boundaries and boundaries between grains of nearly the same orientation may not serve as sources or sinks of the diffusion currents, in which case the creep rate will depend only on the configuration of grain boundaries having a sizable orientation differen...
Journal ArticleDOI

A Model for Boundary Diffusion Controlled Creep in Polycrystalline Materials

TL;DR: In this article, the authors discussed the mechanism of creep in polycrystalline alumina based on the differences between the lattice and boundary diffusion models and showed that the boundary diffusion model is more stable than lattice diffusion model, while the grain size dependence and the numerical constant are greater.
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