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Journal ArticleDOI

Application of peroxymonosulfate and its activation methods for degradation of environmental organic pollutants: Review

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TLDR
A literature review on environmental application of peroxymonosulfate (PMS) in degradation of contaminants to clarify the performance of PMS is carried out in this paper, which describes the PMS usage in remediation of environmental pollutants with focus on the different methods of activation and the effect of main operational parameters on PMS-based processes.
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This article is published in Chemical Engineering Journal.The article was published on 2017-02-15. It has received 1650 citations till now.

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Chemical oxidation of benzene and trichloroethylene by a combination of peroxymonosulfate and permanganate linked by in-situ generated colloidal/amorphous MnO2

TL;DR: In this article, the combined use of peroxymonosulfate (PMS) and permanganate (CUPP) for the degradation of benzene and trichloroethylene (TCE) in simulated groundwater was demonstrated.
Journal ArticleDOI

Understanding spatial effects of tetrahedral and octahedral cobalt cations on peroxymonosulfate activation for efficient pollution degradation

TL;DR: In this article, the spatial occupation-activity relationship of cobalt sites was investigated to design efficient peroxymonosulfate (PMS) activators in water treatment, and the feasibility of Co2+/Co3+ transformation and charge transfer resistance at catalyst-electrolyte interface determine intrinsic activity.
Journal ArticleDOI

Single-atom dispersed Co-N-C: A novel adsorption-catalysis bifunctional material for rapid removing bisphenol A

TL;DR: In this paper, a single-atom dispersed Co-N-C catalyst was prepared by a calcination-acid treatment method, which was confirmed to possess excellent performances of both adsorption and catalytic ability of activating peroxymonosulfate.
Journal ArticleDOI

Highly efficient degradation of trichloroethylene in groundwater based on peroxymonosulfate activation by bentonite supported Fe/Ni bimetallic nanoparticle.

TL;DR: Analysis of the underlying mechanisms indicated that SO4- has a dominant role whereas OH was rather trivial, and a novel BNF/PMS system holds promise as a superior AOP to remediate emerging organic pollutants in groundwater.
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Influence of surface functionalities of pyrogenic carbonaceous materials on the generation of reactive species towards organic contaminants: A review

TL;DR: In this paper, the surface functionalities of carbonaceous materials (PCM) have been investigated for the degradation of organic contaminants, including oxygen, peroxides, persulfate, ozone, and persistent free radicals.
References
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Journal ArticleDOI

Advanced Oxidation Processes for Organic Contaminant Destruction Based on the Fenton Reaction and Related Chemistry

TL;DR: In this paper, the complex mechanisms of Fenton and Fenton-like reactions and the important factors influencing these reactions, from both a fundamental and practical perspective, in applications to water and soil treatment, are discussed.
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Electro-Fenton process and related electrochemical technologies based on Fenton's reaction chemistry

TL;DR: Electro-Fenton (EF) Process 6585 4.2.1.
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Radical generation by the interaction of transition metals with common oxidants.

TL;DR: Nine transition metals were tested for the activation of three oxidants and the generation of inorganic radical species such as sulfate, peroxymonosulfate, and hydroxyl radicals to postulate the rate-determining step of the redox reactions taking place when a metal is coupled with an oxidant in aqueous solution.
Journal ArticleDOI

Generation of sulfate radical through heterogeneous catalysis for organic contaminants removal: Current development, challenges and prospects

TL;DR: In this paper, the authors provide a state-of-the-art review on the development in heterogeneous catalysts including single metal, mixed metal, and nonmetal carbon catalysts for organic contaminants removal, with particular focus on peroxymonosulfate (PMS) activation.
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