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Journal ArticleDOI

Application of Ultrasonics in the On-line Determination of Supersaturation

Waid Omar, +1 more
- 01 Mar 1999 - 
- Vol. 34, Iss: 3, pp 379-389
TLDR
In this paper, an ultrasonic technique is used to develop a method based on the measurement of both ultrasonic velocity and temperature of the supersaturated media for the on-line determination of supersaturation.
Abstract
An ultrasonic technique is used to develop a method based on the measurement of both ultrasonic velocity and temperature of the supersaturated media for the on-line determination of the supersaturation. It is demonstrated by the example of aqueous K 2 SO 4 solution in a seeded batch crystallizer. The feasibility of this technique was investigated using a commercial available sensor. The experimental measurements for the desupersaturation versus time trajectory proved that this technique can be successfully employed to measure supersaturation with sufficient accuracy and precision. Such sensor is preferred in the on-line application due to its fast response and the availability to be applied directly in the slurries without any need to the solid-liquid separation.

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Citations
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Journal ArticleDOI

Crystallization study of potassium sulfate-water system, metastable zone width and induction time measurements using ultrasonic, turbidity and 3D-ORM techniques

TL;DR: In this article, a batch cooling crystallizer was used to explore the solubility, metastable zone width (MSZW), induction time and crystallization kinetics of potassium sulphate-water as a model system.
Journal ArticleDOI

Crystallization kinetics of citric acid anhydrate

TL;DR: In this paper, the solubility curve, metastable zone width (MSZW) and crystallization kinetics of citric acid anhydrate were measured and estimated during batch crystallization of CAA.
Journal ArticleDOI

Online analytical investigations on solvent-, temperature- and water vapour-induced phase transformations of citric acid

TL;DR: In this paper, the authors investigated the influence of different solvent compositions (water and ethanol-water) on the crystallization of citric acid and found that increasing the ethanol content shifted the transformation point towards higher temperatures.
Journal ArticleDOI

Modeling ultrasonic compression wave absorption during the seeded crystallization of copper (II) sulphate pentahydrate from aqueous solution

TL;DR: Ultrasonic compression wave absorption is investigated as a means to monitor the seeded crystallization of copper (II) sulphate pentahydrate from aqueous solution and experiments confirm that simulated attenuation is in agreement with measured results.
Journal ArticleDOI

No Product Design without Process Design (Control)

TL;DR: In this paper, the authors highlight the interrelations between product design and process design in the field of industrial crystallization, based on four examples from the entire field of crystallization (commodities, solvates, polymorphs, batch crystallization).
References
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Journal ArticleDOI

Programmed cooling crystallization of potassium sulphate solutions

TL;DR: In this article, the size distribution from a batch cooling crystallizer is predicted by the numerical solution of a mathematical model which uses empirical kinetics of nucleation and crystal growth, and the predictions clearly point out the potential advantages of controlled cooling at a constant nucleation rate for improving the product crystal size over that obtained by either natural or linear cooling.
Journal ArticleDOI

ATR FTIR spectroscopy for in situ measurement of supersaturation

TL;DR: In this paper, the feasibility of the Attenuated Total Reflection (ATR) Fourier transform infrared (FTIR) spectroscopy for the in situ measurement of supersaturation in crystallization processes is established.
Journal ArticleDOI

Effects of temperature on the crystallization of potassium nitrate by direct measurement of supersaturation

TL;DR: In this paper, the effects of temperature on the kinetics of crystallization of potassium nitrate were investigated in a continuous mixed-suspension, mixed-product-removal (MPM) crystallizer.
Journal ArticleDOI

Growth and dissolution of succinic acid crystals in a batch stirred crystallizer

TL;DR: In this paper, the growth and dissolution of succinic acid crystals were studied in an isothermal stirred tank crystallizer and an implicit equation was given to accurately represent the crystal growth rate as a function of the supersaturation.
Journal ArticleDOI

Evaluation of crystal growth kinetics from a desupersaturation curve using initial derivatives

TL;DR: A technique to evaluate crystal growth kinetics from batch experiments performed in the integral mode is described in this paper, which only requires calculation of the first two derivatives of the desupersaturation curve evaluated at time zero.
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