Journal ArticleDOI
Aqueous oxidation of sulfur dioxide by hydrogen peroxide at low pH
TLDR
In this article, the rate of formation of oxidized sulfur is given by: d(S VI d t = (8±2) × 10 4 (H 2 O 2 )(SO 2.aq ) 0.1+(H + ) mole l −1 s −1About:
This article is published in Atmospheric Environment.The article was published on 1981-01-01. It has received 325 citations till now. The article focuses on the topics: Hydrogen peroxide & Sulfur.read more
Citations
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SO2 promoted ultrafine nano-sulfur dispersion for efficient and stable removal of gaseous elemental mercury
TL;DR: In this paper, a low-cost, stable and high-efficiency method is developed for elemental mercury decontamination from nonferrous smelting flue gas. But the method is limited to the ultrafine size (
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Methyl hydroperoxide (CH 3 OOH) in urban, suburban and rural atmosphere: ambient concentration, budget, and contribution to the atmospheric oxidizing capacity
TL;DR: In this article, the authors report measurements of MHP from seven field campaigns at urban, suburban and rural sites in China in winter 2007 and summer 2006/2007/2008, and investigate the impact of meteorological and chemical parameters on the atmospheric MHP budget.
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Kinetics and mechanism of the oxidation of sulfur (IV) by peroxomonosulfuric acid anion
TL;DR: In this paper, a stochastic analyzer was used to study the oxidation of S(IV) by peroxomonosulfuric acid anion, HOOSO3− (=PMS), at 285 K in the pH range 0-12.5 in buffered aqueous solution under pseudo-first-order conditions.
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Distribution of hydrogen peroxide, methyl hydroperoxide and formaldehyde over central Europe during the HOOVER project
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Electrolyte effects on aqueous atmospheric oxidation of sulphur dioxide by hydrogen peroxide
TL;DR: In this paper, the rate of oxidation of sulphur dioxide by hydrogen peroxide in the presence of various supporting electrolytes has been determined by the stopped flow method, and the effect of temperature and traces of metals ions (Mn2+, Fe3+, Cu2+ and Cr3+) was studied.
References
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Book
Advanced Inorganic Chemistry
TL;DR: Cotton and Wilkinson's Advanced Inorganic Chemistry (AIC) as discussed by the authors is one of the most widely used inorganic chemistry books and has been used for more than a quarter century.
Book
Selected values of chemical thermodynamic properties
TL;DR: The Selected Values of Chemical Thermodynamic Properties as mentioned in this paper, published by the National Bureau of Standards (NBS) in 1952, is a seminal work in the field of thermodynamics.
Journal ArticleDOI
The importance of atmospheric ozone and hydrogen peroxide in oxidising sulphur dioxide in cloud and rainwater
TL;DR: In this paper, the authors used the experimental data to calculate the rate of sulphate formation in water droplets under atmospheric conditions for each of the three oxidants, i.e., ozone, ozone and hydrogen peroxide.
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Mechanism of the homogeneous oxidation of sulfur dioxide in the troposphere
TL;DR: In this article, an evaluation of the existing kinetic data related to the elementary, homogeneous reactions of SO 2 within the troposphere is made, and a set of preferred values of the rate constants for these reactions is presented.
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Kinetics of the oxidation of sulfite by hydrogen peroxide in acidic solution
M. R. Hoffmann,J. O. Edwards +1 more
TL;DR: In this article, the authors investigated the kinetics of sulfite by hydrogen peroxide over the pH range 4-8 and showed that the reaction probably proceeds via a nucleophilic displacement by H 2O_2 on HSO_3^- to form a peroxomonosulfurous acid intermediate which then undergoes a rate-determining rearrangement.