Journal ArticleDOI
Aqueous oxidation of sulfur dioxide by hydrogen peroxide at low pH
TLDR
In this article, the rate of formation of oxidized sulfur is given by: d(S VI d t = (8±2) × 10 4 (H 2 O 2 )(SO 2.aq ) 0.1+(H + ) mole l −1 s −1About:
This article is published in Atmospheric Environment.The article was published on 1981-01-01. It has received 325 citations till now. The article focuses on the topics: Hydrogen peroxide & Sulfur.read more
Citations
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Journal ArticleDOI
Pollutant scavenging from plumes: a modeling case study from the ASARCO smelter
TL;DR: In this paper, the ASARCO copper smelter plume in Tacoma, Washington, was examined with a Gaussian plume scavenging model employing multicomponent reaction kinetics.
Journal ArticleDOI
Theoretical study of the reactions of nitrogen dioxide with hydrogen and methyl peroxides
TL;DR: In this paper, the MP2 level of theory was used to explore four channels for HOOH+NO2 system and eight channels for CH3OOH + NO2 system.
Book ChapterDOI
Cloud chemistry research at great dun fell
A. S. Chandler,Thomas Choularton,T. A. Hill,Alun Jones,Andrew P. Morse,B. J. Tyler,G. J. Dollard,B. M. R. Jones,Stuart A. Penkett +8 more
TL;DR: In this article, a series of experiments designed to investigate the oxidation of SO2 to sulphate by H2O2 and O3 are performed in the cap cloud at Great Dun Fell.
Book ChapterDOI
Modelling Wet Deposition onto Elevated Topography
TL;DR: In this paper, a model for predicting deposition rates of chemical species onto the surface of hills by washout and turbulent deposition has been developed, which includes aqueous phase sulphur dioxide chemistry which is allowed to proceed within an evolving dynamical-microphysical framework.
References
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Book
Advanced Inorganic Chemistry
TL;DR: Cotton and Wilkinson's Advanced Inorganic Chemistry (AIC) as discussed by the authors is one of the most widely used inorganic chemistry books and has been used for more than a quarter century.
Book
Selected values of chemical thermodynamic properties
TL;DR: The Selected Values of Chemical Thermodynamic Properties as mentioned in this paper, published by the National Bureau of Standards (NBS) in 1952, is a seminal work in the field of thermodynamics.
Journal ArticleDOI
The importance of atmospheric ozone and hydrogen peroxide in oxidising sulphur dioxide in cloud and rainwater
TL;DR: In this paper, the authors used the experimental data to calculate the rate of sulphate formation in water droplets under atmospheric conditions for each of the three oxidants, i.e., ozone, ozone and hydrogen peroxide.
Journal ArticleDOI
Mechanism of the homogeneous oxidation of sulfur dioxide in the troposphere
TL;DR: In this article, an evaluation of the existing kinetic data related to the elementary, homogeneous reactions of SO 2 within the troposphere is made, and a set of preferred values of the rate constants for these reactions is presented.
Journal ArticleDOI
Kinetics of the oxidation of sulfite by hydrogen peroxide in acidic solution
M. R. Hoffmann,J. O. Edwards +1 more
TL;DR: In this article, the authors investigated the kinetics of sulfite by hydrogen peroxide over the pH range 4-8 and showed that the reaction probably proceeds via a nucleophilic displacement by H 2O_2 on HSO_3^- to form a peroxomonosulfurous acid intermediate which then undergoes a rate-determining rearrangement.