Asymmetric Hydrogenation of Methyl Benzoylformate Using Platinum-Carbon Catalysts Modified with Cinchonidine
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In this paper, the asymmetric hydrogenation of methyl benzoylformate to R- (-) -methyl mandelate was studied using Pt-C catalysts modified with cinchonidine.Abstract:
The asymmetric hydrogenation of methyl benzoylformate to R- (-) -methyl mandelate was studied using Pt-C catalysts modified with cinchonidine. High asymmetric selectivities (over 80% optical yield) were attained in the hydrogenation using some ethers, esters, or benzene as solvent.read more
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Unexpected inversions in asymmetric reactions: reactions with chiral metal complexes, chiral organocatalysts, and heterogeneous chiral catalysts.
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