Journal ArticleDOI
Binuclear oxidative addition—reductive elimination reactions☆
TLDR
In this paper, the mechanistic aspects of reductive elimination reactions in systems involving binuclear complexes are discussed and a variety of mechanisms are identified, including mononuclear complexes, binuclear species, and a single metal atom site.About:
This article is published in Inorganica Chimica Acta.The article was published on 1982-01-01. It has received 50 citations till now. The article focuses on the topics: Reductive elimination & Oxidative addition.read more
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Hydrogen Production by Molecular Photocatalysis
Journal ArticleDOI
Bimetallic Reductive Elimination from Dinuclear Pd(III) Complexes
TL;DR: Results of a thorough experimental and theoretical investigation of the mechanism of reductive elimination from dinuclear Pd(III) complexes are reported, which establish the role of each metal during reductive Elimination and suggest that redox synergy between the two metals is responsible for the facile reductive eliminated reactions observed.
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Cooperative Bimetallic Redox Reactivity
TL;DR: In this paper, the authors investigated the redox properties of nucleating ligands possessing contiguous 6-coordinate and 4coordinate sites and found that, if the two sites behave as they do in the corresponding monometallic complexes, these bimetallic complexes would be expected to bind a substrate, such as dioxygen, and to reduce it by two electrons, one from each metal, as occurs in the respiratory protein, hemerythrin.
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Direct observation of c-o reductive elimination from palladium aryl alkoxide complexes to form aryl ethers
TL;DR: In this paper, the reaction of KOCH2CMe3 with [(R)-Tol-BINAP]Pd(p-C6H4CN)Br formed [(R]-Tol BINAP]-PdP-C 6H 4CN(OCH2cMe3) (5) in quantitative yield (1H NMR spectroscopy) Thermolysis of 5 in THF-d8 at 47 °C led to C−O
Journal ArticleDOI
Oxygen and hydrogen photocatalysis by two-electron mixed-valence coordination compounds
Joel Rosenthal,Julien Bachman,Jillian L. Dempsey,Arthur J. Esswein,Thomas G. Gray,Justin M. Hodgkiss,David R. Manke,Thomas D. Luckett,Bradford Pistorio,Adam S. Veige,Daniel G. Nocera +10 more
TL;DR: In this paper, the photochemistry for hydrogen and oxygen activation using two-electron mixed-valence complexes of three different motifs: (a) Mn-Mn+2 bimetallic complexes, (b) tetrapyrrole macrocycles and (c) externally bridged di-iron(III) μ-oxo porphyrin dimers.