Journal ArticleDOI
Bonding properties of thiocyanate groups in copper(II) and copper(I) complexes
TLDR
The bonding properties of thiocyanate groups of over one hundred copper species, studied by X-ray analysis, were analyzed in this paper, where it was shown that the bonding properties depend on the size of the positive charge on the copper atom.About:
This article is published in Coordination Chemistry Reviews.The article was published on 1995-03-01. It has received 112 citations till now. The article focuses on the topics: Copper(I) thiocyanate & Thiocyanate.read more
Citations
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Constructing magnetic molecular solids by employing three-atom ligands as bridges
TL;DR: The combination of some three-atom bridges with paramagnetic 3d transition metal ions results in the systematic isolation of molecular magnetic materials, ranging from single-molecule and single-chain magnets to layered weak ferromagnets and three-dimensional porous magnets.
Journal ArticleDOI
Extended Networks of Co2+ and Mn2+ Bridged by NCS–/N3– Anions and Flexible Long Spacers: Syntheses, Structures, and Magnetic Properties
TL;DR: In this article, four new metal-organic polymers with short anion bridges and flexible long spacers were synthesized and characterized by single-crystal X-ray diffraction studies and their magnetic properties were investigated.
Journal ArticleDOI
First Example of Equatorial-Equatorial Disposition of End-to-End Thiocyanate Bridges in a Polynuclear Copper(II) Complex and Its Relation to the Very Efficient Transmission of the Magnetic Interaction
TL;DR: In this paper, the preparation, X-ray structure, and spectroscopic and magnetic properties of [Cu(NCS),μ-NCS)(Hmtpo)(H2O)]2 (where Hmtpo= 4H,7H-5-methyl-7-oxo[1,2,4]triazolo[1 5-a]pyrimidine) are described.
Journal ArticleDOI
Syntheses, crystal structures and magnetic properties of copper(II) polynuclear and dinuclear compounds with 2,3-bis(2-pyridyl)pyrazine (dpp) and pseudohalide as ligands
TL;DR: In this article, the preparation, crystal structures and magnetic properties of four heteroleptic copper(II) complexes with 2,3-bis(2-pyridyl)pyrazine (dpp) and azide, cyanate or thiocyanate as ligands are reported.
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Coordination polymer changing its magnetic properties and colour by thermal decomposition: synthesis, structure and properties of new thiocyanato iron(II) coordination polymers based on 4,4′-bipyridine as ligand
TL;DR: A new polymorphic metastable modification 1II of the pristine precursor compound 1I was obtained and characterized by single crystal X-ray determination.
References
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Journal ArticleDOI
Co-ordination of the Thiocyanate Group in Inorganic Compounds
TL;DR: There has been a rapid growth of interest in the study of the thiocyanate ion in inorganic compounds as discussed by the authors, and a number of papers have been published on the subject.
Journal ArticleDOI
Inorganic Linkage Isomerism of the Thiocyanate Ion
John L. Burmeister,Fred Basolo +1 more
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Crystal Structures of Organic Superconductor, (BEDT-TTF)2Cu(NCS)2, at 298 K and 104 K
Hatsumi Urayama,Hideki Yamochi,Gunzi Saito,Shoichi Sato,Atsushi Kawamoto,Jiro Tanaka,Takehiko Mori,Yusei Maruyama,Hiroo Inokuchi +8 more
TL;DR: The crystal structures of an organic superconductor (BEDT-TTF)2Cu(NCS)2 (Tc=10.4 K) at 298 K and 104 K are determined by X-ray analysis as mentioned in this paper.