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Complexation reactions in aquatic systems : an analytical approach / J. Buffle, translators S.P. Kounaves, A. Kounaves and R.S. Altman

J. Buffle
- Vol. 1990, Iss: 1990, pp 1-99
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The article was published on 1990-01-01 and is currently open access. It has received 812 citations till now.

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Dissertation

Modélisation de la dynamique sédimentaire pour les transferts des radionucléides dans les cours d'eau

TL;DR: In this article, a multi-class radioecological water quality model (TRACE code) was proposed to determine the required parameters for erosion and deposition fluxes for the Bas Rhone Languedoc channel (BRL).
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Tentacle ion exchange separation of Pb-NOM in aquatic systems

TL;DR: In this article, a new tentacle Fractogel dimethylaminoethyl (DMAE) anionic exchanger for the separation of metal−organic species in natural freshwaters is investigated using synthetic solutions and natural waters.
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Influence of UV-B radiation on lead speciation in the presence of natural particles of estuarine waters.

TL;DR: Under UV-B radiation, the complexing strength decreased with time in both filtered and non-filtered water samples, but this effect was more pronounced in the non- Filtered water, which might be due to some adsorption of dissolved macromolecular ligands on the particles and/or to further degradation of dissolved organic matter (DOM).
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Target transform fitting in a voltammetric study of metal complexation.

TL;DR: Results show that analysis can be performed correctly even in presence of unknown species, and the proposed target transform fitting method is in a good agreement with reported results in the literature.
References
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WHAM—a chemical equilibrium model and computer code for waters, sediments, and soils incorporating a discrete site/electrostatic model of ion-binding by humic substances

E. Tipping
TL;DR: The WHAM (Windermere Humic Aqueous Model) as mentioned in this paper is a simple inorganic speciation code for aqueous solutions that combines Humic Ion-Binding Model V with a simple, inorganic inorganic specciation code.
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Ion binding to natural organic matter : competition, heterogeneity, stoichiometry and thermodynamic consistency

TL;DR: The NICCA-Donnan model as mentioned in this paper is a semi-empirical model that is similar to the NICA-donnan model except that it introduces an additional degree of scaling that ensures thermodynamic consistency and allows for variable stoichiometry of binding, which implicitly accounts for the large degree of chemical heterogeneity of humic particles.
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A unifying model of cation binding by humic substances

TL;DR: Model V describes the binding of ions by humic substances in terms of complexation at discrete sites, modified by electrostatic attraction and/or repulsion, and also takes account of nonspecific binding due to counterion accumulation.
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A Generalized Description of Aquatic Colloidal Interactions: The Three-colloidal Component Approach

TL;DR: In this article, the physicochemical properties of the different groups of colloids are described, and the role of each colloid class is discussed with respect to homoaggregation (aggregation within a given colloid) and hetero-aggregation among different colloid types.