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Complexation reactions in aquatic systems : an analytical approach / J. Buffle, translators S.P. Kounaves, A. Kounaves and R.S. Altman

J. Buffle
- Vol. 1990, Iss: 1990, pp 1-99
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The article was published on 1990-01-01 and is currently open access. It has received 812 citations till now.

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Comparison of AGNES (absence of gradients and Nernstian equilibrium stripping) and SSCP (scanned stripping chronopotentiometry) for trace metal speciation analysis

TL;DR: In this article, the free metal ion concentrations obtained by SSCP (stripping chronopotentiometry at scanned deposition potential) and by AGNES (absence of gradients and Nernstian equilibrium stripping) techniques have been compared and the usefulness of the combination of both techniques in the same electrochemical cell for trace metal speciation analysis is assessed.
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Size fractionation of humic substances: Effect on protonation and metal binding properties

TL;DR: In this paper, Humic substances have been extracted from a standard reference peat at pH 2.0, 6.0 and 12.0 using 0.01 M or 0.001 M Na4P2O7.
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The influence of Cu concentration on ethanolic fermentation by Saccharomyces cerevisiae.

TL;DR: Only minor effects were observed at different Cu concentrations, which indicates that Cu levels do not effect changes in fermentation, and, therefore, are below any toxic level regarding the yeast performance.
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Influence of Dissolved Organic Matter On the Bio-Availability and Toxicity of Metals in Soils and Aquatic Systems

TL;DR: In this paper, the importance of DOM in relation to soil solution, particularly the rhizosphere, and also in relation with aquatic systems is discussed, and the mechanism of DOM complexation with dissolved organic matter is discussed.
References
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WHAM—a chemical equilibrium model and computer code for waters, sediments, and soils incorporating a discrete site/electrostatic model of ion-binding by humic substances

E. Tipping
TL;DR: The WHAM (Windermere Humic Aqueous Model) as mentioned in this paper is a simple inorganic speciation code for aqueous solutions that combines Humic Ion-Binding Model V with a simple, inorganic inorganic specciation code.
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Ion binding to natural organic matter : competition, heterogeneity, stoichiometry and thermodynamic consistency

TL;DR: The NICCA-Donnan model as mentioned in this paper is a semi-empirical model that is similar to the NICA-donnan model except that it introduces an additional degree of scaling that ensures thermodynamic consistency and allows for variable stoichiometry of binding, which implicitly accounts for the large degree of chemical heterogeneity of humic particles.
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A unifying model of cation binding by humic substances

TL;DR: Model V describes the binding of ions by humic substances in terms of complexation at discrete sites, modified by electrostatic attraction and/or repulsion, and also takes account of nonspecific binding due to counterion accumulation.
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A Generalized Description of Aquatic Colloidal Interactions: The Three-colloidal Component Approach

TL;DR: In this article, the physicochemical properties of the different groups of colloids are described, and the role of each colloid class is discussed with respect to homoaggregation (aggregation within a given colloid) and hetero-aggregation among different colloid types.