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Complexation reactions in aquatic systems : an analytical approach / J. Buffle, translators S.P. Kounaves, A. Kounaves and R.S. Altman

J. Buffle
- Vol. 1990, Iss: 1990, pp 1-99
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The article was published on 1990-01-01 and is currently open access. It has received 812 citations till now.

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Effect of ionic strength on the complexation of Cu(II) with organic matter dissolved in freshwater

TL;DR: In this article, the effect of ionic strength on the copper complexation with organic matter dissolved in fresh surface waters was studied and the results showed a small linear decrease of the Cu-organic matter complex concentration with increasing ionic strengths.
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Application of DPASV to the study of heavy metal complexation in colloidal latex dispersions

TL;DR: Differential pulse anodic stripping voltammetry (DPASV) was applied to the study of the binding of ZnII, CdII and PbII by two kinds of polystyrene latex particles at different pH values and at different electrolyte concentrations.
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Sample treatment with focused ultrasound and bath sonication as a powerful tool for the evaluation of cadmium pollution in estuarine waters

TL;DR: In this article, a new sample treatment was developed for the determination of dissolved cadmium in Tagus estuarine waters, based on focused ultrasound in conjunction with small volumes in the extraction steps for Cd pre-concentration.
References
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WHAM—a chemical equilibrium model and computer code for waters, sediments, and soils incorporating a discrete site/electrostatic model of ion-binding by humic substances

E. Tipping
TL;DR: The WHAM (Windermere Humic Aqueous Model) as mentioned in this paper is a simple inorganic speciation code for aqueous solutions that combines Humic Ion-Binding Model V with a simple, inorganic inorganic specciation code.
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Ion binding to natural organic matter : competition, heterogeneity, stoichiometry and thermodynamic consistency

TL;DR: The NICCA-Donnan model as mentioned in this paper is a semi-empirical model that is similar to the NICA-donnan model except that it introduces an additional degree of scaling that ensures thermodynamic consistency and allows for variable stoichiometry of binding, which implicitly accounts for the large degree of chemical heterogeneity of humic particles.
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A unifying model of cation binding by humic substances

TL;DR: Model V describes the binding of ions by humic substances in terms of complexation at discrete sites, modified by electrostatic attraction and/or repulsion, and also takes account of nonspecific binding due to counterion accumulation.
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A Generalized Description of Aquatic Colloidal Interactions: The Three-colloidal Component Approach

TL;DR: In this article, the physicochemical properties of the different groups of colloids are described, and the role of each colloid class is discussed with respect to homoaggregation (aggregation within a given colloid) and hetero-aggregation among different colloid types.