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Complexation reactions in aquatic systems : an analytical approach / J. Buffle, translators S.P. Kounaves, A. Kounaves and R.S. Altman
J. Buffle
- Vol. 1990, Iss: 1990, pp 1-99
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The article was published on 1990-01-01 and is currently open access. It has received 812 citations till now.read more
Citations
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133Cs and 35Cl NMR spectroscopy and molecular dynamics modeling of Cs+ and Cl− complexation with natural organic matter
TL;DR: In this paper, a combined experimental 133 Cs and 35 Cl nuclear magnetic resonance (NMR) and computational molecular dynamics (MD) modeling study of the interaction of Cs + and Cl − with Suwannee River NOM is presented.
Journal ArticleDOI
Effect of the presence of lead on the biosorption of copper, cadmium and nickel by anaerobic biomass
TL;DR: In this article, a flow-through column packed with a calcium-saturated anaerobic sludge biosorbent was used to study the biosorption of Pb, Cu, Cd and Ni from single and binary metal systems.
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Stripping chronopotentiometry at scanned deposition potential (SSCP). part 4. The kinetic current regime
TL;DR: In this article, the theory for depletive stripping chronopotentiometry at scanned deposition potential (SSCP) has been extended to include the case of kinetic currents, and the Koutecky-Koryta approximation, assuming a spatially discontinuous transition from labile to non-labile behaviour, allows a rigorous expression to be obtained for the full SSCP wave.
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The role of geochemistry in environmental and epidemiological studies in developing countries: a review
TL;DR: The role of geochemistry in the preparation of high resolution baseline data to identify potential hazards, understanding the pathways of chemical elements from rocks and soils to man and animals, and developing amelioration strategies to reduce the impacts of inappropriate land use, power generation and mining is discussed in this paper.
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A nickel availability study in serpentinised areas of Portugal
TL;DR: In this paper, the factors that control Ni availability and adsorption in serpentine soils from the northeast of Portugal, which developed under temperate climacteric conditions, were investigated following characterisation of the soils' selected physicochemical properties.
References
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WHAM—a chemical equilibrium model and computer code for waters, sediments, and soils incorporating a discrete site/electrostatic model of ion-binding by humic substances
TL;DR: The WHAM (Windermere Humic Aqueous Model) as mentioned in this paper is a simple inorganic speciation code for aqueous solutions that combines Humic Ion-Binding Model V with a simple, inorganic inorganic specciation code.
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Ion binding to natural organic matter : competition, heterogeneity, stoichiometry and thermodynamic consistency
David G. Kinniburgh,Willem H. van Riemsdijk,Luuk K. Koopal,Michal Borkovec,Marc F. Benedetti,Marcelo Javier Avena +5 more
TL;DR: The NICCA-Donnan model as mentioned in this paper is a semi-empirical model that is similar to the NICA-donnan model except that it introduces an additional degree of scaling that ensures thermodynamic consistency and allows for variable stoichiometry of binding, which implicitly accounts for the large degree of chemical heterogeneity of humic particles.
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Ecosystem dynamics based on plankton functional types for global ocean biogeochemistry models
Corinne Le Quéré,Sandy P. Harrison,Sandy P. Harrison,I. Colin Prentice,I. Colin Prentice,Erik T. Buitenhuis,Olivier Aumont,Laurent Bopp,Hervé Claustre,Leticia Cotrim da Cunha,Richard J. Geider,Xavier Giraud,Christine Klaas,Christine Klaas,Karen E. Kohfeld,Louis Legendre,M. Manizza,M. Manizza,Trevor Platt,Richard B. Rivkin,Shubha Sathyendranath,Julia Uitz,Andrew J. Watson,Dieter Wolf-Gladrow +23 more
TL;DR: The Dynamic Green Ocean Model (DGOM) as mentioned in this paper is based on the identification of key plankton functional types that need to be simulated explicitly to capture important biogeochemical processes in the ocean, and sources of information necessary to parameterize each of these processes within a modeling framework.
Journal ArticleDOI
A unifying model of cation binding by humic substances
TL;DR: Model V describes the binding of ions by humic substances in terms of complexation at discrete sites, modified by electrostatic attraction and/or repulsion, and also takes account of nonspecific binding due to counterion accumulation.
Journal ArticleDOI
A Generalized Description of Aquatic Colloidal Interactions: The Three-colloidal Component Approach
TL;DR: In this article, the physicochemical properties of the different groups of colloids are described, and the role of each colloid class is discussed with respect to homoaggregation (aggregation within a given colloid) and hetero-aggregation among different colloid types.