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Journal ArticleDOI

Confinement-induced phase transitions in simple liquids.

Jacob Klein, +1 more
- 11 Aug 1995 - 
- Vol. 269, Iss: 5225, pp 816-819
TLDR
The liquid-to-solid transition of a simple model liquid confined between two surfaces was studied as a function of surface separation and the rigidity of the confined films increased reversibly by at least seven orders of magnitude.
Abstract
The liquid-to-solid transition of a simple model liquid confined between two surfaces was studied as a function of surface separation. From large surface separations (more than 1000 angstroms) down to a separation corresponding to seven molecular layers, the confined films displayed a liquid-like shear viscosity. When the surface separation was further decreased by a single molecular spacing, the films underwent an abrupt, reversible transition to a solid. At the transition, the rigidity of the confined films (quantified in terms of an "effective viscosity") increased reversibly by at least seven orders of magnitude.

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Citations
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Thin film lubrication in the past 20 years

Abstract: Thin film lubrication (TFL), a lubrication regime that fills the gap between boundary lubrication (BL) and elastohydrodynamic lubrication (EHL) regimes, was proposed 20 years ago. Since it was first recorded in the literature, TFL has gained substantial interest and has been advanced in the fields of theoretical and experimental research. Following the revelation of the TFL phenomenon and its central ideas, many studies have been conducted. This paper attempts to systematically review the major developments in terms of both the history and the advances in TFL. It begins with the description and definition of TFL, followed by the state-of-art studies on experimental technologies and their applications. Future prospects of relevant studies and applications are also discussed.
Journal ArticleDOI

Segment density profiles of polyelectrolyte brushes determined by Fourier transform ellipsometry

TL;DR: In this paper, a method for the explicit determination of the segment density profile φ(z) of surface-attached polymer brushes with multiple angle of incidence null-ellipsometry is described.
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Computer Simulations of Friction, Lubrication and Wear

TL;DR: An overview of computer simulations of tribology is presented in this paper, with a brief overview of simulation techniques and the special requirements for simulation of tribological processes, and a simple one-dimensional models of friction between crystalline surfaces are introduced to illustrate general features of friction, such as the importance of metastability and the effect of commensurability.
Journal ArticleDOI

Relaxation of polymers in 2 nm slit-pores: confinement induced segmental dynamics and suppression of the glass transition

TL;DR: In this article, the structure and dynamics of polystyrene confined in 2 nm slit pores, between parallel, crystalline, mica-type surfaces, were explored using molecular dynamics simulations.
Journal ArticleDOI

Simulation Insights on the Structure of Nanoscopically Confined Poly(ethylene oxide)

TL;DR: In this paper, the structure and morphology of poly(ethylene oxide) (PEO) chains confined in 1-nm slit pores defined by montmorillonite silicate layers were investigated.
References
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Journal ArticleDOI

Surface energy and the contact of elastic solids

TL;DR: In this paper, the influence of surface energy on the contact between elastic solids is discussed and an analytical model for its effect upon the contact size and the force of adhesion between two lightly loaded spherical solid surfaces is presented.
Book

The friction and lubrication of solids

TL;DR: Tabor and Bowden as mentioned in this paper reviewed the many advances made in this field during the past 36 years and outlined the achievements of Frank Philip Bowden, and reviewed the behavior of non-metals, especially elastomers; elastohydrodynamic lubrication; and the wear of sliding surfaces.
Journal ArticleDOI

Slow viscous motion of a sphere parallel to a plane wall—I Motion through a quiescent fluid

TL;DR: Asymptotic solutions of the Stokes equations are derived for both the translational and rotational motions of a sphere parallel to a plane wall bounding a semi-infinite, quiescent, viscous fluid in the limit where the gap width tends to zero as discussed by the authors.
Journal ArticleDOI

Physics of the Granular State

TL;DR: The generation of analogies between the physics found in a simple sandpile and that found in complicated microscopic systems, such as flux motion in superconductors or spin glasses, has prompted a number of new theories and to a new era of experimentation on granular systems.
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