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Journal ArticleDOI

Confinement-induced phase transitions in simple liquids.

Jacob Klein, +1 more
- 11 Aug 1995 - 
- Vol. 269, Iss: 5225, pp 816-819
TLDR
The liquid-to-solid transition of a simple model liquid confined between two surfaces was studied as a function of surface separation and the rigidity of the confined films increased reversibly by at least seven orders of magnitude.
Abstract
The liquid-to-solid transition of a simple model liquid confined between two surfaces was studied as a function of surface separation. From large surface separations (more than 1000 angstroms) down to a separation corresponding to seven molecular layers, the confined films displayed a liquid-like shear viscosity. When the surface separation was further decreased by a single molecular spacing, the films underwent an abrupt, reversible transition to a solid. At the transition, the rigidity of the confined films (quantified in terms of an "effective viscosity") increased reversibly by at least seven orders of magnitude.

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Citations
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"Freezing" of nanoconfined fluids under an electric field.

TL;DR: It is deduced that the EF can induce more liquid molecules to be aligned to form more ordered layers in the nanogap and be correlated with the liquid polarity and the film thickness.
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Understanding nanorheology and surface forces of confined thin films

TL;DR: In this paper, the authors reviewed the fundamentals of nanoreheolgy, advances in experimental techniques and theoretical simulation methods, as well as important progress in the nanorheology of confined thin films.
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Shape effects on nanoparticle engulfment for metal matrix nanocomposites

TL;DR: In this paper, the shape and size of Al2O3 nanoparticles are identified for their optimal dispersion in the Al matrix and critical velocity of solidification is calculated numerically for spherical, cylindrical and disk-shaped nanoparticles using an analytical model which incorporates drag force, intermolecular force and inertia effect.
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Brownian Force Profile Reconstruction of Interfacial 1-Nonanol Solvent Structure

TL;DR: The solvent structure force profile of interfacial 1-nonanol between graphite and methyl terminated alkane thiol SAM surfaces was measured using Brownian force profile reconstruction (BFPR) to enable the measurement of stiff or rough energy landscapes such as solvent structure or ligand-protein binding.
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Structure of a model lubricant in a mica slit pore

TL;DR: In this article, a monolayer octamethylcyclotetrasiloxane (OMCTS) film confined between micalike surfaces is used to better understand the relationship between fluid properties and the atomic structure of the surfaces.
References
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Journal ArticleDOI

Surface energy and the contact of elastic solids

TL;DR: In this paper, the influence of surface energy on the contact between elastic solids is discussed and an analytical model for its effect upon the contact size and the force of adhesion between two lightly loaded spherical solid surfaces is presented.
Book

The friction and lubrication of solids

TL;DR: Tabor and Bowden as mentioned in this paper reviewed the many advances made in this field during the past 36 years and outlined the achievements of Frank Philip Bowden, and reviewed the behavior of non-metals, especially elastomers; elastohydrodynamic lubrication; and the wear of sliding surfaces.
Journal ArticleDOI

Slow viscous motion of a sphere parallel to a plane wall—I Motion through a quiescent fluid

TL;DR: Asymptotic solutions of the Stokes equations are derived for both the translational and rotational motions of a sphere parallel to a plane wall bounding a semi-infinite, quiescent, viscous fluid in the limit where the gap width tends to zero as discussed by the authors.
Journal ArticleDOI

Physics of the Granular State

TL;DR: The generation of analogies between the physics found in a simple sandpile and that found in complicated microscopic systems, such as flux motion in superconductors or spin glasses, has prompted a number of new theories and to a new era of experimentation on granular systems.
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