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Journal ArticleDOI

Confinement-induced phase transitions in simple liquids.

Jacob Klein, +1 more
- 11 Aug 1995 - 
- Vol. 269, Iss: 5225, pp 816-819
TLDR
The liquid-to-solid transition of a simple model liquid confined between two surfaces was studied as a function of surface separation and the rigidity of the confined films increased reversibly by at least seven orders of magnitude.
Abstract
The liquid-to-solid transition of a simple model liquid confined between two surfaces was studied as a function of surface separation. From large surface separations (more than 1000 angstroms) down to a separation corresponding to seven molecular layers, the confined films displayed a liquid-like shear viscosity. When the surface separation was further decreased by a single molecular spacing, the films underwent an abrupt, reversible transition to a solid. At the transition, the rigidity of the confined films (quantified in terms of an "effective viscosity") increased reversibly by at least seven orders of magnitude.

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Citations
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Journal ArticleDOI

Measurement of viscoelasticity of UV photoresist used for nanoimprint lithography under confinement in nanometer-sized gaps

TL;DR: In this article, the authors measured the viscoelasticity of a UV photoresist, PAK-01, confined in nanometer-sized gap widths by the sensitive shear force measurement method developed in their previous study.
Journal ArticleDOI

A new method for measurement and quantification of tracer diffusion in nanoconfined liquids

TL;DR: Development of a novel instrument to measure tracer diffusion in water under nanoscale confinement finds that the diffusion of a tracer molecule is slowed down by more than 10 times for the probe-substrate separations of 5 nm and below.
Book ChapterDOI

Melting of atomic layers in carbon nanotubes

TL;DR: In this article, the melting temperature of a monolayer adsorbed in the pore is lower than the temperature of the 3D triple point, however, the adsorption of the second layer pushes the temperatures of melting of the contact layer up.
Journal ArticleDOI

Solidification of the Lennard-Jones fluid near a wall in thermohydrodynamic lubrication

TL;DR: The thermohydrodynamic lubrication of the Lennard-Jones (LJ) fluid in plain wall channels is investigated by using a molecular-dynamics simulation and it is found that the LJ fluid solidifies near the wall when the viscous heating of the L J fluid in the bulk regime is sufficiently large.
Journal ArticleDOI

Extremely slow dynamics of ionic liquid self-assembled nanostructures near a solid surface.

TL;DR: In this article , the dynamics of the self-assembled liquid nanostructure of the ionic liquids (ILs) near a mica surface can be determined from video-rate atomic force microscopy (AFM) data.
References
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Journal ArticleDOI

Surface energy and the contact of elastic solids

TL;DR: In this paper, the influence of surface energy on the contact between elastic solids is discussed and an analytical model for its effect upon the contact size and the force of adhesion between two lightly loaded spherical solid surfaces is presented.
Book

The friction and lubrication of solids

TL;DR: Tabor and Bowden as mentioned in this paper reviewed the many advances made in this field during the past 36 years and outlined the achievements of Frank Philip Bowden, and reviewed the behavior of non-metals, especially elastomers; elastohydrodynamic lubrication; and the wear of sliding surfaces.
Journal ArticleDOI

Slow viscous motion of a sphere parallel to a plane wall—I Motion through a quiescent fluid

TL;DR: Asymptotic solutions of the Stokes equations are derived for both the translational and rotational motions of a sphere parallel to a plane wall bounding a semi-infinite, quiescent, viscous fluid in the limit where the gap width tends to zero as discussed by the authors.
Journal ArticleDOI

Physics of the Granular State

TL;DR: The generation of analogies between the physics found in a simple sandpile and that found in complicated microscopic systems, such as flux motion in superconductors or spin glasses, has prompted a number of new theories and to a new era of experimentation on granular systems.
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