Journal ArticleDOI
Controlled Radical Polymerization of Methacrylic Monomers in the Presence of a Bis(ortho-chelated) Arylnickel(II) Complex and Different Activated Alkyl Halides
TLDR
In this article, a novel class of homogeneous nickel(II) catalysts, denoted as Ni(NCN)Br, is reported to mediate in the presence of activated alkyl halides, e.g., CCl4 or α-halocarbonyl compounds, and remarkably enough, poly(methyl methacrylate) (PMMA) with molecular weight up to at least 105 g/mol was synthesized in a controlled fashion.Abstract:
A novel class of homogeneous nickel(II) catalysts, i.e [Ni{o,o‘(CH2NMe2)2C6H3}Br], denoted as Ni(NCN‘)Br, is reported to mediate in the presence of activated alkyl halides, e.g., CCl4 or α-halocarbonyl compounds, a well-controlled radical polymerization of methacrylic monomers [methyl and n-butyl methacrylate), (MMA, n-BuMA)] at rather low temperatures (<100 °C). The number-average molecular weight of the polymer gradually increased with the monomer conversion and was inversely proportional to the initiator concentration of alkyl halides. The molecular weight distribution (MWD) remained very narrow during the whole course of the polymerization (MWD < 1.3). All the experimental data including a successful block copolymerization (n-BuMA-b-MMA) experiment were in agreement with a living polymerization process, and remarkably enough, poly(methyl methacrylate) (PMMA) with molecular weight up to at least 105 g/mol was synthesized in a controlled fashion. Increased thermal stability of the PMMA is a further indi...read more
Citations
More filters
Journal ArticleDOI
Poly(n-butyl acrylate) Homopolymer and Poly[n-butyl acrylate-b-(n-butyl acrylate-co-styrene)] Block Copolymer Prepared via Nitroxide-Mediated Living/Controlled Radical Polymerization in Miniemulsion
Journal ArticleDOI
Atom Transfer Polymerization of Methyl Methacrylate. Effect of Acids and Effect with 2-Bromo-2-Methylpropionic Acid Initiation
Journal ArticleDOI
Controlled/“Living” Radical Polymerization of Glycidyl Methacrylate at Ambient Temperature
R. Krishnan,K. S. V. Srinivasan +1 more
Journal ArticleDOI
Iron(III)‐Mediated ATRP of Methyl Methacrylate Using Activators Generated by Electron Transfer
TL;DR: In this article, an atom-transfer radical polymerization using activators generated by electron transfer mediated by iron catalyst was developed, using an oxidatively stable FeCl 3 /triphenylphosphine as a catalyst complex, ascorbic acid as a reducing agent, and methyl methacrylate as a monomer.
Book ChapterDOI
Free radical polymerization
TL;DR: Inverse free radical suspension polymerization as a route to encapsulate biologically active materials (C. I. as discussed by the authors ) was used to construct a ternary phase diagram through in situ polymerization.
References
More filters
Journal ArticleDOI
Controlled/"living" radical polymerization. atom transfer radical polymerization in the presence of transition-metal complexes
Journal ArticleDOI
Polymerization of Methyl Methacrylate with the Carbon Tetrachloride/Dichlorotris- (triphenylphosphine)ruthenium(II)/Methylaluminum Bis(2,6-di-tert-butylphenoxide) Initiating System: Possibility of Living Radical Polymerization
Journal ArticleDOI
Narrow molecular weight resins by a free-radical polymerization process
TL;DR: In this paper, free radical polymerization was used to obtain polystyrene and poly(styrene-co-butadiene) with narrow polydispersity (1.19-1.36) in the presence of 2,2,6, 6,6-tetramethyl-1-piperidinyloxy using benzoyl peroxide as initiator
Journal ArticleDOI
Controlled Living Radical Polymerization - Halogen Atom-Transfer Radical Polymerization Promoted by a Cu(I)Cu(II) Redox Process
TL;DR: An extension of ATRA to atom transfer radical addition, ATRP, provided a new and efficient way to conduct controlled/living radical polymerization as mentioned in this paper, using a simple alkyl halide, R-X (X = Cl and Br), as an initiator and a transition metal species complexed by suitable ligand(s), M t n /L x, e.g., CuX/2,2'-bipyridine, as a catalyst.
Related Papers (5)
Controlled/"living" radical polymerization. atom transfer radical polymerization in the presence of transition-metal complexes
Living radical polymerization of styrene initiated by arenesulfonyl chlorides and CuI(bpy)nCl
Virgil Percec,Bogdan Barboiu +1 more