Controlled Radical Polymerization of Vinyl Acetate with Cyclopentadienyl Chromium β-Diketiminate Complexes: ATRP vs OMRP
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In this article, the ability of compounds CpCrII(nacnacAr,Ar) (Ar = Dipp, 1; Xyl, 2) to catalyze the atom transfer radical polymerization (ATRP) of vinyl acetate has been explored using methyl 2-chloropropionate as initiator.About:
This article is published in Organometallics.The article was published on 2010-06-22 and is currently open access. It has received 49 citations till now. The article focuses on the topics: Living free-radical polymerization & Cobalt-mediated radical polymerization.read more
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Organometallic: Mediated Radical Polymerization
TL;DR: In this paper, an organized and detailed review of one particular CRP technique, organometallic mediated radical polymerization (OMRP), focusing on individual catalysts developed, their efficacy and monomer scope is presented.
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Insight into Organometallic-Mediated Radical Polymerization
TL;DR: Organometallic-Mediated radical polymerization (OMRP) as discussed by the authors is an emerging class of controlled radical polymers, which is based on the temporary deactivation of the growing radical species by a transition metal complex and the reversible formation of a carbon-metal covalent bond.
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Iron-mediated reversible deactivation controlled radical polymerization
TL;DR: A review comprehensively covers all the work reported so far on RDRP mediated by iron complexes, organized according to ligand type, and discusses the specificities of this metal in terms of the multitude of accessible spin states and the interplay of different equilibria as discussed by the authors.
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Iron-catalyzed atom transfer radical polymerization
Zhigang Xue,Dan He,Xiaolin Xie +2 more
TL;DR: In this paper, the preparation of polymers using iron-catalyzed atom transfer radical polymerization (ATRP) has been reviewed according to mechanistic considerations; iron complexes and ligand types.
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Radical Coordination Chemistry and Its Relevance to Metal‐Mediated Radical Polymerization
TL;DR: The reactions engaged by organic radicals with transition metal complexes are reviewed in this article with a particular focus on how they can interplay with and affect the results of radical polymerization, and various ways in which metal complexes can play a role in radical polymers.
References
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