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Corrosion behaviour of laser-cleaned AA7024 aluminium alloy

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TLDR
In this article, the authors investigated the corrosion behavior of laser-cleaned AA7024-T4 aluminium alloy using potentiodynamic polarisation, electrochemical impedance spectroscopy (EIS), and scanning vibrating electrode technique (SVET).
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This article is published in Applied Surface Science.The article was published on 2018-03-30 and is currently open access. It has received 60 citations till now. The article focuses on the topics: 6111 aluminium alloy & 5005 aluminium alloy.

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Citations
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A review of incorporating Nd:YAG laser cleaning principal in automotive industry

TL;DR: In this article, the potential of incorporating pulsed Nd:YAG laser and its principals in coating removal for automotive industry with respect to these characteristics is discussed, such as being versatile, precise, controllable, lack of waste generation, and environmental friendly process.
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Electrochemical, TOF-SIMS and XPS studies on the corrosion behavior of Q-phase in NaCl solutions as a function of pH

TL;DR: In this paper, the corrosion behavior of a bulk-synthesized Q-phase (Al4Cu2Mg8Si7) in NaCl solutions at different pH has been investigated using anodic and cathodic potentiodynamic polarization, time-of-flight secondary ion mass spectroscopy (ToF-SIMS) and X-ray photoelectron spectroscopic (XPS).
Journal ArticleDOI

Investigation on the Surface Properties of 5A12 Aluminum Alloy after Nd: YAG Laser Cleaning

TL;DR: In this paper, an acousto-optic Q-switched diode-pumped Nd:YAG laser and the effects of different laser powers and different cleaning speeds on the surface roughness, microstructure, element content, microhardness, residual stress and corrosion resistance of aluminum alloy were investigated.
Journal ArticleDOI

A new monitoring method for metal rust removal states in pulsed laser derusting via acoustic emission techniques

TL;DR: In this article, acoustic emission (AE) monitoring and high-speed camera were successfully integrated for reliable investigation of laser derusting mechanism, where the removal characteristics and microscopic changes of rust layer observed and analyzed using AE signals and high speed images are utilized for further improvement of the mechanism of rust removal by pulsed laser.
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Evaluation of laser cleaning for defouling of marine biofilm contamination on aluminum alloys

TL;DR: In this paper, a nanosecond laser was used to remove marine biofilm contamination from the surface of an aluminum substrate by instantaneous thermal ablation, which can also contribute to the formation of a hierarchical micro- and nanostructured oxidized layer.
References
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Journal ArticleDOI

The analysis of electrode impedances complicated by the presence of a constant phase element

TL;DR: In this article, it was shown that the electrical double-layer at a solid electrode does not in general behave as a pure capacitance but rather as an impedance displaying a frequency-independent phase angle different from 90°.
Journal ArticleDOI

Impedance of constant phase element (CPE)-blocked diffusion in film electrodes

TL;DR: In this article, the authors construct a model of ac impedance response to blocked linear diffusion that has a sloped low frequency region in the impedance plot, which is equivalent to solving Fick's law with a boundary condition that allows us to set an arbitrary impedance response at low frequencies.
Journal ArticleDOI

Laser-assisted removal of particles on silicon wafers

TL;DR: In this paper, a dry laser cleaning tool was tested that uses an inert gas jet to remove particles lifted off by the action of a DUV excimer laser, and a model was developed to simulate the cleaning process and analyze the influence of experimental parameters on laser cleaning efficiency.
Journal ArticleDOI

The effects of short pulse laser surface cleaning on porosity formation and reduction in laser welding of aluminium alloy for automotive component manufacture

TL;DR: In this paper, the effects of short pulsed laser surface cleaning on porosity formation and reduction in laser welding of AC-170PX (AA6014) aluminium sheets with two types of joints: fillet edge and flange couch, using an AA4043 filler wire for automotive component assembly.
Journal ArticleDOI

Laser removal of oxides from a copper substrate using Q-switched Nd:YAG radiation at 1064 nm, 532 nm and 266 nm

TL;DR: In this paper, the effect of wavelength and the material removal mechanisms of a laser process for removing copper oxide from copper was studied with increasing fluence, and the laser-treated surfaces were characterised using optical microscopy, scanning electron microscopy.. SEM, and static secondary ion mass spectroscopy SSIMS.
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Frequently Asked Questions (18)
Q1. What are the contributions in "Corrosion behaviour of laser-cleaned aa7024 aluminium alloy" ?

In this study, the authors investigated the corrosion behaviour of laser-cleaned AA7024-T4 aluminium alloy using potentiodynamic polarisation, electrochemical impedance spectroscopy ( EIS ) and scanning vibrating electrode technique ( SVET ). It was suggested that the removal of the original less protective oxide layer consisting of MgO and MgAl2O4 on the as-received surfaces and the newly formed more protective oxide layer containing mainly Al2O3 and MgO by laser cleaning were responsible for the improvement of the corrosion performance. 

When the laser fluence was increased to 1 J/cm2, the oxide layer formed by the thermal oxidation became, in a large extent, crystalline and its outer part was entirely covered by a continuous layer of magnesium oxide. 

Removal of organic contaminants is based on laser beam disintegration or vaporisation of contaminants, so that no significant thermal effect on the substrate is expected. 

It was known that three mechanisms in laser removal of oxide layers from metallic substrates exist, i.e.thermal ablation, mechanical effect, and combined thermal ablation and mechanical effects. 

The higher corrosion resistance for the laser-cleaned surface at 11.3 J/cm2 than that at 7.1 J/cm2 might be the result of thicker oxide layer formed and the excessive melting which might have modified the microstructure underneath the oxide layer, in terms of refinement of second phases. 

Within this region, magnesium was also rich, which was believed to be the result of faster diffusion of Mg towards the surface than the other elements during the hot-rolling process. 

Compared with the conventional cleaning techniques, laser cleaning offers advantages including environment-friendliness, better selectivity, better controllability, better flexibility to achieve complete removal of surface contamination with minimal damage to the underlying substrate material and the process can be much faster for welding surface preparations since only localised cleaning is required. 

In recent years, laser cleaning has been considered as a pre-treatment technique for coating, welding and joining of various materials, and also a post-treatment technique to remove stains and discoloration after welding [4-7]. 

In addition, the zinc profile showed depletion on the top surface, but became relatively uniform distributing along the depth after laser cleaning. 

Laser cleaning has been considered as an alternative method to replace conventional cleaning techniques such as wet chemicals and mechanical cleaning involving air abrasives or grinding. 

It was worth stating here that the increase in the surface reflectance after laser cleaning was mainly attributed to the removal of the oxide layer that was dark in appearance s well as other contaminants. 

As MgAl2O4 presents the atomic ratio of Mg:Al:O as 1:2:4, it was most likely that all the aluminium attributed to the formation of MgAl2O4, and the excessive amount of magnesium and oxygen may be combined to form other compounds. 

Such a thermal effect is dependent on several factors, including laser beam wavelength, pulse width, laser processing parameters, thickness of oxide layers, nature of oxide layers as well as substrate materials. 

the hydrogen was also likely to be co-existent in the oxide layer as hydrogen has a higher solubility in aluminium oxide than in aluminium matrix. 

4) The SVET current maps showed that the laser-cleaned at 7.1 J/cm2 exhibited much lessanodic activity while anodic current peaks presented on the as-received alloy surface was dramatic. 

The intensities of oxygen and magnesium peaks after laser cleaning were significantly reduced, providing a further evidence of removal of the oxide layer. 

The intermediate values of resistance and capacitance of the mechanically ground surface indicated that the outer layer and oxide layer on the as-received alloy were completely removed by grinding, followed by the formation of a thin, air-formed oxide layer. 

The mechanically ground surface exhibited higher corrosion resistance than the as-received, but lower than the laser-cleaned, due to the formation of air-formed oxide layer which was more protective than the MgO+MgAl2O4 layer on the as-received surface, but less protective than the newly formed Al2O3+MgO layer by laser cleaning.