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Journal ArticleDOI

Coupling light with biocatalysis for sustainable synthesis—very recent developments and future perspectives

TLDR
This review highlights developments in the field of photobiocatalysis published in the past two years and describes novel discoveries in photobiOCatalytic cascades and in strict light-dependent enzymes.
Abstract
Using light for biocatalysis is a relatively new and expanding research field. Because of the ever-increasing number of publications, this review highlights developments in the field of photobiocatalysis published in the past two years. We introduce the topic briefly and list most of the review articles appeared so far. Afterward, we devote special attention to the most interesting and relevant key articles in the field of in vitro photobiocatalysis, and briefly, we describe novel discoveries in photobiocatalytic cascades and in strict light-dependent enzymes. Finally, we outline developments in the next decade in the conclusions and future perspectives part.

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Citations
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Journal ArticleDOI

Synthesis of Enantiopure Sulfoxides by Concurrent Photocatalytic Oxidation and Biocatalytic Reduction

TL;DR: A concurrent bioc atalytic reduction and photocatalytic oxidation process is demonstrated, using Protochlorophyllide as a new green photocatalyst for the sulfoxidation of sulfoxides.
Journal ArticleDOI

Process Intensification as Game Changer in Enzyme Catalysis

TL;DR: The aim of the review is to show the current capabilities and future potentials of PI in enzyme catalysis focused on enzymes of the class of oxidoreductases, with focus on alternative methods of energy input, innovative reactor concepts and reaction media with improved properties.
Journal ArticleDOI

Photobiocatalysis in Continuous Flow

TL;DR: This review presents recent and very recent developments in the field of photobiocatalysis in continuous flow, several different practical applications and features of state-of-the art photobioreactors are discussed and some future perspectives are presented.
Journal ArticleDOI

Optimization and Engineering of Fatty Acid Photodecarboxylase for Substrate Specificity

TL;DR: To address substrate selectivity within the medium to long chain fatty acid range, where FAP shows great promise for the synthesis of drop‐in biofuels from ubiquitous fatty acids with chain lengths from C12 to C18, 22 rationally designed mutant enzymes are screened.
References
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Journal ArticleDOI

Structure and function of DNA photolyase and cryptochrome blue-light photoreceptors.

TL;DR: This work has shown that the structure and function of the Cryptochromes and the Circadian Clock, as well as their role in the regulation of Photolyase, are fundamentally different than that of the EMTs used in previous studies.
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Photobiocatalysis: Activating Redox Enzymes by Direct or Indirect Transfer of Photoinduced Electrons

TL;DR: This Review provides an overview of recent advances in light-driven activation of redox enzymes through direct or indirect transfer of photoinduced electrons.
Journal ArticleDOI

Photoexcitation of flavoenzymes enables a stereoselective radical cyclization

TL;DR: It is found that photoexcitation of flavin-dependent “ene”-reductases changes their catalytic function, enabling these enzymes to promote an asymmetric radical cyclization, furnished a previously unknown biocatalytic reaction.