Journal ArticleDOI
Crystal growth kinetics of iron fluoride trihydrate
Kerstin Forsberg,Åke C. Rasmuson +1 more
TLDR
In this article, the growth of beta-FeF3 • 3H(2)O has been investigated in mixtures of 3 mol kg(-1) hydrofluoric acid and 3mol kg(1) nitric acid at 30, 40 and 50 degrees C.About:
This article is published in Journal of Crystal Growth.The article was published on 2006-11-01. It has received 14 citations till now. The article focuses on the topics: Nitric acid & Hydrofluoric acid.read more
Citations
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Journal ArticleDOI
Facile solution synthesis of α-FeF3·3H2O nanowires and their conversion to α-Fe2O3 nanowires for photoelectrochemical application.
TL;DR: The ease and scalability of the conversion from hydrated fluoride NWs to oxide NWs suggest a potentially versatile and low-cost strategy to make NWs of other useful iron-based compounds that may enable their large-scale renewable energy applications.
Journal ArticleDOI
Predicting the Size Distribution in Crystallization of TSPP:TMPyP Binary Porphyrin Nanostructures in a Batch Desupersaturation Experiment
TL;DR: In this article, a model for the growth of binary porphyrin nanostructures was developed to simulate all the major kinetic and thermodynamic steps of crystallization including homogeneization.
Journal ArticleDOI
Anionic ordering and thermal properties of FeF3·3H2O
Mario Burbano,Mario Burbano,Mathieu Duttine,Olaf J. Borkiewicz,Alain Wattiaux,Alain Demourgues,Mathieu Salanne,Henri Groult,Damien Dambournet +8 more
TL;DR: A clear understanding is provided of the structure and thermal properties of FeF3·3H2O, a material that can potentially bridge the recycling of pickling sludge from the steel industry by preparing battery electrodes.
Journal ArticleDOI
Crystal Growth Kinetics of Piracetam Polymorphs in Ethanol and Isopropanol
TL;DR: In this paper, the crystal growth kinetics of two different polymorphs of Piracetam have been investigated in ethanol and isopropanol, and the growth rates ranged 10-7-10-8 m/s, the growth rate order was clearly higher than unity, and activation energies are in the range 39-66 kJ/mol for all the systems studied suggesting surface integration control.
Journal ArticleDOI
Recycling of waste pickle acid by precipitation of metal fluoride hydrates
Kerstin Forsberg,Åke C. Rasmuson +1 more
TL;DR: Stainless steel is pickled in mixed acid solutions (1-3 M HNO3 and 0.5-4 M HF) usually neutralized with lime, and in Sweden about 18,000 tons/yr of metal hydroxide sludge is...
References
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Journal ArticleDOI
The Growth of Crystals and the Equilibrium Structure of their Surfaces
TL;DR: In this paper, it was shown that the rate of growth of a surface containing dislocations is proportional to the square of the supersaturation for low values and to the first power for high values of the latter.
Journal ArticleDOI
Electrolyte crystal growth mechanisms
TL;DR: In this article, it was shown that the rate of integration at a kink is of the order of one thousandth of the speed of dehydration of the cation, which is due to the activation energy of diffusion, as an ion, in order to integrate, must dehydrate and make a diffusional jump.
Journal ArticleDOI
Reactivity at the mineral-water interface: dissolution and inhibition
TL;DR: In this paper, it is shown that dissolution can be explained in terms of a ligand exchange process; simplified rate laws for proton and ligand-protonated dissolution rates, being related to surface bound protons and ligands, respectively, can be derived.
Related Papers (5)
α- and β-FeF3.3H2O revisited : crystal structure and 57Fe Mössbauer spectra
D. G. Karraker,P. K. Smith +1 more